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31.
32.
A new, convenient, one-pot process is presented for the synthesis of 2-oxazolines in high yields (75-94%) via boron esters of N-(2-hydroxyethyl) amides. The procedure involves thermolysis of the boron esters at 240-260 °C, in the presence of solid CaO as an acid scavenger and allows the preparation of oxazolines from hydroxyethyl amides of aliphatic and aromatic monocarboxylic acids. 相似文献
33.
Several approaches have been proposed for evaluating information in expected utility theory. Among the most popular approaches are the expected utility increase, the selling price and the buying price. While the expected utility increase and the selling price always agree in ranking information alternatives, Hazen and Sounderpandian [11] have demonstrated that the buying price may not always agree with the other two. That is, in some cases, where the expected utility increase would value information A more highly than information B, the buying price may reverse these preferences. In this paper, we discuss the conditions under which all these approaches agree in a generic decision environment where the decision maker may choose to acquire arbitrary information bundles. 相似文献
34.
35.
Niyazi Bicak Bunyamin Karagoz Dilek Emre 《Journal of polymer science. Part A, Polymer chemistry》2006,44(6):1900-1907
Copper‐mediated atom transfer radical polymerization (ATRP) is presented as a versatile tool for the graft copolymerization of 2‐ethyl hexylacrylate with poly(vinyl chloride) (PVC) in an aqueous suspension. The appreciable solubility of PVC in 2‐ethyl hexylacrylate (30%) at temperatures around 130 °C makes grafting of the monomer possible from labile chlorines of PVC in aqueous suspensions without the use of additional solvent. The first‐order kinetics (rate constant k = 4.2 × 10?6 s?1) of the mass percentage increase reveals a typical ATRP fashion of the graft copolymerization at low conversions. The use of a completely organosoluble copper(I) complex of hexylated triethylene tetramine, in combination with α‐methylcellulose as a stabilizer, makes the graft copolymerization possible in a dispersed organic phase. Nearly spherical, green particles can be obtained with moderate stirring rates (1000 rpm) in high graft yields. Although the kinetics of the reaction deviates from the first order at high conversions, reasonable graft yields (146%) can be attained within a reaction period of 24 h. In this study, the reaction conditions of the grafting have been studied, and graft products have been confirmed by common techniques such as 1H NMR, gel permeation chromatography, and differential scanning calorimetry. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 1900–1907, 2006 相似文献
36.
This paper deals with the approximate solution of multi-pantograph equation with nonhomogenous term in terms of Taylor polynomials. The technique we have used is based on a Taylor matrix method. In addition, some numerical examples are presented to show the properties of the given method and the results are discussed. 相似文献
37.
Jacek Gasiorowski Sameh Boudiba Kurt Hingerl Christoph Ulbricht Valeria Fattori Francesca Tinti Nadia Camaioni Reghu Menon Stefanie Schlager Louiza Boudida Niyazi Serdar Sariciftci Daniel Ayuk Mbi Egbe 《Journal of Polymer Science.Polymer Physics》2014,52(4):338-346
An anthracene‐containing poly(arylene‐ethynylene)‐alt‐poly(arylene‐vinylene) (PAE‐PAV) of general constitutional unit (? Ph? C?C? Anthr? C?C? Ph? CH?CH? Anthr? CH?CH)n bearing two 2‐ethylhexyloxy solubilizing side chains on each phenylene (Ph) unit has been synthesized and characterized. The basic electrochemical characterization was done, showing the existence of two non‐reversible oxidation and one reversible reduction peaks. The optical properties, the real and imaginary part of the dielectric function, were probed using spectroscopic ellipsometry (SE). The vibrational structure of the undoped/doped polymer was investigated using Fourier transformed infrared spectroscopy. A strong change in the polaronic absorption was observed during the doping, which after modeling revealed the existence of two separated transitions. The optical changes upon doping were additionally recorded using the SE technique. Similar to the results from FT‐IR spectroscopy, two new in‐the‐gap absorptions were found. Moreover, the electrical conductivity as well as the mobility of positive carriers were measured. In the undoped state, the conductivity of the polymer was found to be below the detection limit (<μS cm?1), after doping the conductivity increased to 0.69 S cm?1. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2014 , 52, 338–346 相似文献
38.
Fatma Canturk Bunyamin Karagoz Niyazi Bicak 《Journal of polymer science. Part A, Polymer chemistry》2011,49(16):3536-3542
Simple mixing of an atom transfer radical polymerization (ATRP) mixture with zinc powder was demonstrated to result in rapid decolorizing of the solution and precipitation of elemental copper, using small amounts of silica gel as seeding material. The experiments revealed that the chemical reduction of copper by wetted zinc powder (i.e., 0.325 g/mmol copper) is fast and completed within less than 5 min. UV spectra of the filtered polymer solution showed no any trace of copper. Terminal bromoalkyl groups of the polymers in the ATRP solution were determined to be unchanged by short‐term contact with zinc powder at room temperature and a nearly complete reductive dehalogenation takes place only after 24 h of interaction, as evidenced by reaction of elemental zinc with a model compound, ethyl bromoacetate. Indeed, poly(methyl methacrylate) (PMMA) sample (Mn: 7900, polydispersity index: 1.09) isolated from ATRP mixture after the copper removal a by short contact with zinc powder (i.e., 15 min) was determined “still living” as confirmed by chain extension with styrene, ethyl acrylate, and t‐butyl acrylate monomers to give block copolymers. The presence of acetic acid was demonstrated to accelerate reductive dehalogenation of PMMA end‐groups by zinc and yields nonliving polymer within 2 h. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011 相似文献
39.
Deniz Gunes Okan Sirkecioglu Niyazi Bicak 《Phosphorus, sulfur, and silicon and the related elements》2013,188(8):1685-1690
A simple and convenient one-pot procedure is described for the synthesis of thioethers via boron esters. This procedure involves in-situ generation of alkyl sulfates by reaction of trialkyl borates with concentrated sulfuric acid and subsequent reaction with thiols in the presence of pyridine. The reactions with boron esters of primary or secondary alcohols proceed cleanly at 100°C and afford aliphatic thioethers in reasonable yields (59–93%) within 24 h. Interestingly, the 1H NMR spectra of the products showed no sign of positional isomerisms. The method fails however with thiophenol and does not yield aromatic thioethers, due to electrophilic substitution at the phenyl ring. 相似文献
40.
Abstract A versatile crosslinking agent, tetraallyl piperazinium dichloride (TAP) has been prepared and demonstrated to be useful in copolymerization with water soluble monomers such as acrylic acid and acrylamide. Although the crosslinker itself does not readily homopolymerize in water, it forms transparent rigid hydrogels within a reasonable period of time when copolymerized with acrylic acid. Being nonhydrolysable, the crosslinker presented is superior to other common water soluble crosslinking agents such as methylene or ethylene bis(acrylamides). Since this crosslinker has a low toxicity, it may be used for bioapplications such as gel electrophoresis etc. 相似文献