SHS等离子喷涂制备FeAl2O4-Al2O3-Fe纳米复合涂层的研究

利用SHS等离子喷涂技术,将经过机械团聚法制备的Fe2O3-Al复合粉体送入等离子焰流,沉积出厚度约为400 μm的复合涂层.利用XRD,SEM 和TEM等检测手段对涂层的成分和组织进行了分析,测定了涂层的显微硬度、断裂韧性以及耐磨性.结果表明涂层为具有纳米结构的FeAl2O4-Al2O3-Fe纳米复合组织;涂层的显微硬度为HV100g870;断裂韧性是普通Al2O3涂层的2倍;无润滑磨损的耐磨性是普通Al2O3涂层的2.5倍.     

Effect of bromine substituent on optical properties of aryl compounds

Substituents significantly affect optical properties of organic compounds. In this study, a series of organic compounds were synthesized. Ultraviolet‐visible and cyclic voltammetry spectra were determined. The relationships between the number of π electron in an aryl ring and the redshift (and molecular orbital energy levels) were studied. To investigate mechanisms of the bromine substituent effects, theoretical calculations were carried out. Ultraviolet‐visible spectra of bromine‐containing compounds exhibit obvious redshifts (0.04‐0.17 eV) of the maximal absorption wavelengths and enhanced absorbance (11%‐57%) compared with corresponding reference compounds. The lowest unoccupied and highest occupied molecular orbital energy levels of compounds containing bromine substituents are 0.05 to 0.60 and 0.02 to 0.40 eV lower than that of corresponding reference compounds. On the whole, the redshifts and the reduced molecular orbital energy levels caused by bromine substituent decrease with the increase in the number of π electron in an aryl ring. The effects would be attributed to strong p‐π conjugation between p electron in the bromine substituent and π electrons in aryl rings. Therefore, this paper suggests a useful way for tuning optical absorption and molecular orbital energy levels of aryl compounds.     

圆扫描变像管人卫激光测距技术研究

在本文中,我们设计并研制了用于毫米级精度人卫激光测距的圆扫描时间分析系统。研制的圆扫描变像管理论时间分辨率可优于3ps,可用于双色测距;偏转灵敏度高达10cm/kV,偏转空间分辨率优于24lp/mm;利用双MCP内增强,增益～1×10⁶,并有门控功能以进一步提高信噪比和动态范围。扫描控制电路能提供300MHz、10W的正弦信号,其频率、幅度、相位稳定度均可满足要求。调试过程中较好地解决了阻抗变换、空间干扰和相位正交等关键问题。在仅2W的RF功率驱动下,即可实现稳定的φ24mm的圆扫描,系统实测时间分辨率达4.8ps。在实验室实测测距精度达亚毫米级。动态实验及模拟测距表明,该时间分析系统可满足第四代人卫激光测距系统的需要。     

First-principles studies of the vibrational properties of amorphous carbon nitrides

Raman spectra of amorphous carbon nitride films (a-C:N) resemble those of typical amorphous carbon (a-C), and no specific features in the spectra are shown due to N doping. The present work provides a correlation between the microstructure and vibrational properties of a-C:N films from first principles. The six periodic model structures of 64 atoms with various mass densities and nitrogen contents are generated by the liquid-quench method using Car-Parinello molecular dynamics. By using Raman coupling tensors calculated with the finite electric field method, Raman spectra are obtained. The calculated results show that the vibrations of C=N could directly contribute to the Raman spectrum. The similarity of the Raman line shapes of N-doped and N-free amorphous carbons is due to the overlapping of C=N and C=C vibration bands. In addition, the origin of characteristic Raman peaks is also given.     

超衍射成像中 双螺旋点扩展函数的三维定位精度

开关效应和单分子定位的结合可以实现样品的超衍射分辨成像, 双螺旋点扩展函数将单分子定位纳米分辨从二维扩展到了三维.本文对双螺旋点扩展函数的三维定位精度展开了探讨.首先, 基于费希尔信息量, 计算了双螺旋点扩展函数的无偏估计, 得出其理论定位精度, 并分析了光子数、背景噪声以及有效像元尺寸大小对其定位精度的影响; 其次, 基于单分子定位实验过程中对于数据分析通常采用的高斯拟合质心定位算法, 通过误差传递函数定律求得双螺旋点扩展函数的轴向定位精度.计算机模拟结果表明, 在光子数大于1000的条件下, 高斯拟合质心定位精度和费希尔信息量理论定位精度符合较好. 本文的讨论不仅为双螺旋点扩展函数的三维定位精度提供了理论依据, 同时也可为实验提供理论指导. 关键词： 双螺旋点扩展函数 费希尔信息量 定位精度 高斯拟合     

群论在对称结构电磁散射问题中的应用

用T矩阵方法计算电磁散射问题时, 如果散射体的几何结构满足点群对称性, 即在群变换作用下保持不变, 可以利用群论找出散射体的几何对称性和T矩阵元的对称性之间的关系, 通过预知部分矩阵元的精确值以及 它们之间的关系来达到数值求解过程 中节约运行时间的目的. 关键词： 群论 对称结构 电磁散射 对称算子     

A Quantum Watermarking Protocol Based on Bell Dual Basis

This paper presents a Bell-dual-basis-based quantum watermarking protocol composed of three major algorithms: watermark embedding and extracting and the intercepting test. The first two are completed by using the entanglement swapping property of Bell dual basis and the test is accomplished through IBF protocol to guarantee its bottom security. The watermarking protocol is mainly designed for the protection of digital copyright in the existence of classical information. This design finds that the quality of digital contents is not damaged with its zero-watermark attributes when embedding watermarks.     

Scanning tunneling spectroscopy of Ag films: the effect of periodic versus quasiperiodic modulation

By using scanning tunneling spectroscopy to probe a silver thin film that contains both periodic and quasiperiodic modulation, and by using Fourier analysis, we unravel the influences of individual Fourier components of the scattering potential (periodic versus quasiperiodic) on the electronic structure of a one-dimensional quasiperiodically modulated thin Ag film. Along the periodically modulated direction, a Bragg reflection-induced energy gap is observed in k space. On the other hand, the exotic E vs k spectrum with many minigaps was observed along the quasiperiodic direction.