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41.
An infrared-absorption band centered at 0.85 eV, which is below the big optical absorption at the charge-density-wave (CDW) gap energy of 1.85 eV, has been observed for semiconducting single crystalline Ba(1-x)KxBiO3. With substituting K for Ba, the spectral weight of the new band increases with x, while that of the CDW-gap excitation decreases. Since the impurity state with the K substitution is known to be nonmagnetic at low temperatures, Bi3+ the state with 6s2 electrons surrounded by the six Bi5+ ions forms a small bipolaron by losing a pair of electrons in the Rice-Sneddon model. The new band is assigned to a transition from the lower-Peierls band to a state of the bipolaronic point defect. 相似文献
42.
A rapid column-adsorption method has been developed for concentrating traces of copper, cadmium, and lead in water prior to their determinations by graphite-furnace atomic-absorption spectrometry. The adsorbent used was prepared by loading a strongly basic anion-exchanger QAE-Sephadex A-25 (50 mg) with thiacalix[4]arenetetrasulfonate (20 mol). Two-hundredfold preconcentration of the analyte elements was achieved by passing 100 mL of sample solution (pH 8.0) through a column packed with the adsorbent (6 mm i.d.×7 mm high) at a flow rate of 10 mL min–1 and by the subsequent elution with 500 L of aqueous nitric acid solution (1 mol L–1). The practical applicability of the proposed method was evaluated by analyzing certified reference seawater samples. 相似文献
43.
Morohashi N Katagiri H Iki N Yamane Y Kabuto C Hattori T Miyano S 《The Journal of organic chemistry》2003,68(6):2324-2333
All four stereoisomers of p-tert-butylsulfinylcalix[4]arene [4(rccc), 4(rcct), 4(rctt), and 4(rtct)], arising from the disposition of the four sulfinyl groups with respect to the mean plane of the four bridging sulfur atoms, have been prepared via oxidation of p-tert-butylthiacalix[4]arene (2) or its tetra-O-benzyl ethers 5 of defined conformations. Thus, treatment of 2 with 4.4 molar equiv of NaBO(3).4H(2)O gave the rtct and rctt isomers in 27% and 17% yields, respectively, while oxidation of cone 5 (5(C)) and partial cone 5 (5(PC)) proceeded stereoselectively to give, after debenzylation of the resulting tetrasulfoxides 12 and 15, the rccc and rcct isomers in 56% and 28% yields, respectively, based on 5. The sulfinylcalix[4]arenes 4 were treated with iodomethane in the presence of a base to give the corresponding tetramethyl ethers 16, the structures of which in regard to the disposition of the sulfinyl groups and the conformation of the phenol units were determined by X-ray crystallography. Also reported is the synthesis of all four conformational isomers of tetra-O-benzyl ether of 2 (5(C), 5(PC), 5(1,2-A), and 5(1,3-A)). 相似文献
44.
We proposed in this study a novel analog complementary metal oxide semiconductor (CMOS) circuit for generating a motion signal
when an object moves, which is a simple structure. The proposed unit circuit was constructed using a previously proposed edge
detection circuit and a novel proposed circuit for generating a motion signal which accepts an edge signal. The part for generating
the motion signal was constructed using six metal oxide semiconductor (MOS) transistors and one capacitor. Results obtained
by the simulation program with integrated circuit emphasis (SPICE) and the measured results of a test circuit constructed
with discrete MOS transistors and the test circuit fabricated with a 1.2 μm CMOS process showed that the proposed unit circuit
can output pulsed current (motion signal) when an object moves on the circuit. It was clarified from the SPICE results that
the two-dimensional network constructed with proposed unit circuits can output motion signals. The size of the novel unit
circuit is expected to be about 110 × 110μm2 obtained by the 1.2 μm CMOS process. It is possible to arrange 90 × 90 unit circuits on a chip which has an area of 1 × 1cm2. The aperture ratio is expected to be about 21%, which is twice as large as that of the previously proposed circuit. An integrated
circuit for image processing in real time can thus be realized by applying the two-dimensional network constructed with the
proposed circuits. 相似文献
45.
J. Khuyagbaatar S. Hofmann F. P. Heßberger D. Ackermann S. Antalic H. G. Burkhard S. Heinz B. Kindler A. F. Lisetskiy B. Lommel R. Mann K. Nishio H. J. Schött B. Sulignano 《The European Physical Journal A - Hadrons and Nuclei》2007,34(4):355-361
Isomeric states in 214Th and 213Th were identified by means of γ -rays measured in delayed coincidence with the implanted evaporation residues. These were
produced in irradiations of 164Dy with 54Cr projectiles and separated in-flight by the velocity filter SHIP. An isomeric state of I
π = 8+ with a half-life of (1.24±0.12) μs was identified in 214Th . The configuration π[1h
9/2 ⊗ 2f
7/2] was assigned to this state. An isomeric state with a half-life of (1.4±0.4) μs was observed in 213Th . Tentatively it was assigned to an I
π = 13/2+ state. 相似文献
46.
Using the RTM/NEGF method, which is a first-principles calculation tool for the quantum transport through nanostructures between electrodes, we study the effects of atomic-scale contacts on the transport properties through single molecules. Electronic states and current-voltage (I-V) characteristics are investigated in various contact conditions with and without single molecules between electrodes. We find that similar nonlinear behaviors appear in the I-V characteristics. Such nonlinear behaviors are determined not only by the HOMO-LUMO electronic states of single molecules between electrodes, but also by the atomic-scale contact conditions. We show that the transitions from tunneling to ballistic regimes affect the I-V characteristics significantly. 相似文献
47.
We investigate the vacancy effect on the electronic transport properties of the (5,5)-metallic and (5,0)-semiconducting carbon nanotubes using the time-dependent wave-packet approach based on the Kubo-Greenwood formula within the tight-binding approximation. We found that the metallic and semiconducting carbon nanotubes show different electronic transport properties for the states created by vacancies. 相似文献
48.
Wei‐Ching Liao Nobuhiko Watari Shengnian Wang Xin Hu Ronald G. Larson Ly James Lee 《Electrophoresis》2010,31(16):2813-2821
The electrophoresis of λ‐DNA is observed in a microscale converging channel where the center‐of‐masses trajectories of DNA molecules are tracked to measure instantaneous electrophoretic (EP) mobilities of DNA molecules of various stretch lengths and conformations. Contrary to the usual assumption that DNA mobility is a constant, independent of field and DNA length in free solution, we find DNA EP mobility varies along the axis in the contracting geometry. We correlate this mobility variation with the local stretch and conformational changes of the DNA, which are induced by the electric field gradient produced by the contraction. A “shish‐kebab” model of a rigid polymer segment is developed, which consists of aligned spheres acting as charge and drag centers. The EP mobility of the shish‐kebab is obtained by determining the electrohydrodynamic interactions of aligned spheres driven by the electric field. Multiple shish‐kebabs are then connected end‐to‐end to form a freely jointed chain model for a flexible DNA chain. DNA EP mobility is finally obtained as an ensemble average over the shish‐kebab orientations that are biased to match the overall stretch of the DNA chain. Using physically reasonable parameters, the model agrees well with experimental results for the dependence of EP mobility on stretch and conformation. We find that the magnitude of the EP mobility increases with DNA stretch, and that this increase is more pronounced for folded conformations. 相似文献
49.
Tadashi Nishio Rie Suzuki Yuko Tsukada Hideko Kanazawa Teruo Okano Takako Miyabe-Nishiwaki 《Journal of chromatography. A》2009,1216(44):7427-7432
A new method for the quantitative analysis of monkey serum propofol, which is widely used as an anaesthetic agent, was developed by utilizing a temperature-responsive polymer of N-isopropylacrylamide (NIPAAm) and butyl methacrylate (BMA) as the stationary phase of HPLC–fluorescence detection. This poly(NIPAAm-co-BMA) copolymer undergoes a reversible phase transition from a hydrophilic to a hydrophobic microstructure when triggered by change in the temperature. Also this chromatographic system is possible to separate the analytes by using only water as a mobile phase. A pretreatment of the serum (80 μL) was only solid-phase extraction, and the recovery rate of propofol and internal standard was more than 77%, respectively. This method covered the calibration range from 0.5 μg/mL to 10 μg/mL and allowed a reproducible quantification of the serum propofol in administrated monkey serum. The intra- and inter-assay relative standard deviations were less than 14.1%. In addition, there was good relationship of the quantification values between the developed method and the widely used reversed-phase HPLC method. Our developed method has proven to be useful for a simple analysis of propofol in clinical practice, because the avoidance of complicated mobile phase preparation was possible, and only temperature changing could regulate the retention time of the analyte. In addition, by using water instead of fossil fuel, it is the ideal analytical method according to green chemistry. 相似文献
50.