Forecasting the thermal conductivity of a nanofluid using artificial neural networks

Journal of Thermal Analysis and Calorimetry - In this study, the influence of incorporating MWCNT on the thermal conductivity of paraffin was evaluated numerically. Input variables including mass...     

Study of mechanism and kinetic modeling of CO hydrogenation reaction over the impregnated Co-Ni/Al2O3 catalyst

An investigation of the kinetic and mechanism of CO hydrogenation reaction was performed on impregnated Co-Ni/Al₂O₃. Determination of kinetic parameters from the experiments was carried out in a micro fixed-bed reactor. Kinetic evaluations were performed under various operational conditions of T = 473–673 K, p = 1–14 bar, H₂/CO = 1–3, and GHSV = 4,500 hr⁻¹. Kinetic models and rate equations for CO consumption were obtained by using two main-type rate equations of Langmuir-Hinshelwood-Hougen-Watson (LHHW) and Eley-Rideal (ER). Estimation of various kinetic parameters was performed using a nonlinear regression method. According to the obtained experimental results and using statistical criteria, one kinetic expression based on the LHHW mechanism (-r_CO = k_p.b_CO.P_CO. b_H2. P_H2/[1+ b_CO.P_CO + b_H2.P_H2]²) was chosen as the best-fitted model. For this fitted model, the activation energy was found to be 109.2 kJ/mol. Characterization of the catalyst was also performed using X-ray diffraction (XRD), BET, scanning electron microscopy (SEM), and energy-dispersive x-ray spectrometer (EDS) techniques.     

First principle study of hydrogen storage on the graphene-like aluminum nitride nanosheet

Employing density functional calculations including an empirical dispersion term, we investigated the hydrogenation of an aluminum nitride nanosheet (h-AlN) with atomic and molecular hydrogen. It was found that atomic H prefers to be adsorbed on an N atom rather than Al, releasing energy of 21.1 kcal/mol. The HOMO/LUMO energy gap of the sheet is dramatically reduced from 107.9 to 44.5 kcal/mol, upon the adsorption of one hydrogen atom. The adsorption of atomic H on the h-AlN presents properties which are promising for nanoelectronic applications. The molecular H₂ was found to be adsorbed collinearly on an N atom and dissociated to two H atoms on Al–N bond. Calculated barrier and adsorption energies for this dissociation process are about +18.9 and ?1.9 kcal/mol. We predict that each nitrogen atom in an AlN sheet can adsorb two hydrogen molecules on opposite sides of the sheet, and thus the gravimetric density for hydrogen storage on AlN sheet is evaluated to be about 8.9 wt%.     

Molecular mechanochemistry: low force switch slows enzymatic cleavage of human type I collagen monomer

In vertebrate animals, fibrillar collagen accumulates, organizes, and persists in structures which resist mechanical force. This antidissipative behavior is possibly due to a mechanochemical force-switch which converts collagen from enzyme-susceptible to enzyme-resistant. Degradation experiments on native tissue and reconstituted fibrils suggest that collagen/enzyme kinetics favor the retention of loaded collagen. We used a massively parallel, single molecule, mechanochemical reaction assay to demonstrate that the effect is derivative of molecular mechanics. Tensile loads higher than 3 pN dramatically reduced (10×) the enzymatic degradation rate of recombinant human type I collagen monomers by Clostridium histolyticum compared to unloaded controls. Because bacterial collagenase accesses collagen at multiple sites and is an aggressive cleaver of the collagen triple helical domain, the results suggest that collagen molecular architecture is generally more stable when mechanically strained in tension. Thus the tensile mechanical state of collagen monomers is likely to be correlated to their longevity in tissues. Further, strain-actuated molecular stability of collagen may constitute the fundamental basis of a smart structural mechanism which enhances the ability of animals to place, retain, and load-optimize material in the path of mechanical forces.     

Choosing the optimal intervention method to reduce human-related machine failures

This paper presents a novel method to quantify the effects of human-related factors on the risk of failure in manufacturing industries. When failures can be caused by operators, the decision maker must intervene to mitigate operator-related risk. There are numerous intervention methods possible; we develop a revenue model that provides the decision-maker with a systematic tool to perform a cost-benefit analysis, balancing the advantage of risk reduction, against the direct cost of the intervention method.     

Effects of operator learning on production output: a Markov chain approach

We develop a Markov chain approach to forecast the production output of a human-machine system, while encompassing the effects of operator learning. This approach captures two possible effects of learning: increased production rate and reduced downtime due to human error. In the proposed Markov chain, three scenarios are possible for the machine at each time interval: survival, failure, and repair. To calculate the state transition probabilities, we use a proportional hazards model to calculate the hazard rate, in terms of operator-related factors and machine working age. Given the operator learning curves and their effect on reducing human error over time, the proposed approach is considered to be a non-homogeneous Markov chain. Its result is the expected machine uptime. This quantity, along with production forecasting at various operator skill levels, provides us with the expected production output.     

Double-diffusivity heat generation effects on bioconvection process embedded in a vertical porous surface with variable fluid properties

Journal of Thermal Analysis and Calorimetry - The present paper concerns the bioconvective flow, mass and heat transfer including motile microorganisms on a vertical surface saturated with porous...     

Comparative study of mixed convection heat transfer of water–Cu nanofluid in an enclosure having multiple rotating circular cylinders with different configurations and considering harmonic cylinders rotation

Journal of Thermal Analysis and Calorimetry - In the present study, heat transfer in a lid-driven square cavity in the existence of four rotating cylinders having harmonic motion was investigated...