Coherent and incoherent processes in resonant photoemission

3 threshold. At threshold, the emission feature changes character and after a rather narrow transition region it appears at constant emission energy instead. Clear signatures of interference between the direct photoemission and autoionization channels are identified. Received: 6 March 1997     

Thiophene‐cored 2,2‐bis(methylol)propionic acid dendrimers for optical‐power‐limiting applications

The synthesis and characterization of dendron‐coated 2,5‐bis(phenylethynyl)thiophene chromophores are described. The dendrimers were grown divergently on the arylthiophene core with the versatile anhydride of 2,2‐bis(methylol)propionic acid. The arylthiophene core was synthesized with Sonogashira coupling reactions. Structurally well‐defined dendrimers up to the fourth generation were grown, as confirmed by size exclusion chromatography, NMR, and matrix‐assisted laser desorption/ionization time‐of‐flight analysis. The different dendritic substitution did not influence the absorption spectra of the compounds in or near the visible region. Solutions of arylthiophenes had good transparency at wavelengths greater than 400 nm. The dendritic thiophenes exhibited an optical‐power limit at the laser wavelength of 532 nm. However, the magnitude of the optical‐power limit of these compounds was slightly lower than that of a nondendritic arylthiophene with n‐pentyl substituents. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 1177–1187, 2005     

Microchip electrophoresis for specific gene detection of the pathogenic bacteria V. cholerae by circle-to-circle amplification.

We have developed a new method for a fast and precise analysis of circle-to-circle amplification (C2CA) product for specific gene detection by microchip electrophoresis. In this method, we have added a new enzymatic step to the C2CA reaction, which could be carried out isothermally at 37 degrees C. Compared to the original single-stranded DNA, the double-stranded DNA that is produced by this enzymatic reaction is more reliable for analysis by microchip electrophoresis. C2CA product was detected within 55 s with high reproducibility by this method which was successfully applied to the detection of 10-ng genomic DNA of the pathogenic bacteria Vibrio. cholerae within 110 s. Purification was found to be an indispensable step for the analysis of the C2CA product of genomic DNA samples.     

High-spin states in the isotones 89Zr, 91Mo and 93Ru populated in α-particle-induced reactions

The reactions (α, 3nγ) and (α, α′nγ) on ⁸⁸Sr, ⁹⁰Zr and ⁹²Mo were used to populate excited states in ⁸⁹Zr, ⁹¹Mo and ⁹³Ru. The de-excitation of these states was studied by in-beam γ-ray spectroscopy. The short-lived radioactivity of the ⁹²Mo target was measured in order to study the decay of ⁹³Ru. Many new levels were observed, particularly in ⁹¹Mo. They are interpreted as due to the coupling of a $\text{g}{}_{\mathrm{<mtext>9</mtext><mtext>2</mtext>}}$ neutron hole with known excited states in ⁹⁰Zr, ⁹²Mo and ⁹⁴Ru.     

Hyperfine structure in the 6p5d configuration and isotope shifts in transitions between the 6s5d and the 6p5d configurations in Ba I

High-resolution laser fluorescence spectroscopy, using a single-mode dye laser acting on a collimated atomic beam, has been performed to determine the hyperfine-structure (hfs) constants in six states of the 6p 5d configuration of¹³⁵Ba and¹³⁷Ba. Isotope shifts (IS) for eleven transitions between the 6s 5d and the 6p 5d configurations have also been measured. From an analysis of the energy levels, intermediate angular wavefunctions have been deduced. The wavefunctions are used to evaluate experimental hyperfine parameters from the experimental hfs constants. The parameters are, for the magnetic-dipole interaction compared with theoretical values, and for the electricquadrupole interaction used to estimate the nuclear quadrupole moments for the odd isotopes. The IS in the measured transitions are analysed using a King-plot, with the first resonance line in Ba II as the reference. Specific mass and field shifts are evaluated for the measured transitions. The field shifts have been used to determine the change in mean-square radius between the natural abundant Ba-isotopes.     

Single-pion production in antiproton-proton interactions

Single-pion production in $\text{p}\text{p}$ interactions at 9.1 GeV/c is analysed and cross sections are given. The p_lab dependence of the isospin amplitudes is determined by a fit to the world data. The data are also compared with the predictions of a reggeized Deck model. The results and the $\text{N}\text{π}\text{N}$ amplitudes are compared with the results at other energies and with the corresponding NπN amplitudes.     

General features of the pp interaction at 12 GeV/c

Simple inclusive cross sections for $\text{p}\text{p}$ interactions at 12 GeV/c are given. The data cover prong cross sections, V⁰ production and resonances. Separation has been made into annihilation and non-annihilation modes. Some implications of the data are discussed. It is pointed out that the ratios of cross sections for $\text{?}{}^0\text{π}{}^{\mathrm{?}}$ production are independent of incident antiproton momentum in $\text{p}\text{p}$ annihilation processes, and that data at the highest available pp energies (ISR) tend to the same value.