Adsorption of uranium ions by crosslinked polyester resin functionalized with acrylic acid from aqueous solutions

In this paper, the crosslinked polyester resin containing acrylic acid functional groups was used for the adsorption of uranium ions from aqueous solutions. For this purpose, the crosslinked polyester resin of unsaturated polyester in styrene monomer (Polipol 353, Poliya) and acrylic acid as weight percentage at 80 and 20%, respectively was synthesized by using methyl ethyl ketone peroxide (MEK_p, Butanox M60, Azo Nobel)-cobalt octoate initiator system. The adsorption of uranium ions on the sample (0.05 g copolymer and 5 mL of U(VI) solution were mixed) of the crosslinked polyester resin functionalized with acrylic acid was carried out in a batch reactor. The effects of adsorption parameters of the contact time, temperature, pH of solution and initial uranium(VI) concentration for U(VI) adsorption on the crosslinked polyester resin functionalized with acrylic acid were investigated. The adsorption data obtained from experimental results depending on the initial U(VI) concentration were analyzed by the Freundlich, Langmuir and Dubinin–Radushkevich (D–R) adsorption isotherms. The adsorption capacity and free energy change were determined by using D–R isotherm. The obtained experimental adsorption data depending on temperature were evaluated to calculate the thermodynamic parameters of enthalpy (ΔH°), entropy (ΔS°) and free energy change (ΔG°) for the U(VI) adsorption on the crosslinked polyester resin functionalized with acrylic acid from aqueous solutions. The obtained adsorption data depending on contact time were analyzed by using adsorption models such as the modified Freundlich, Elovich, pseudo-first order and pseudo-second-order kinetic models.     

Synthesis,antimicrobial and antiproliferative activities of new self-assembly benzimidazole-bridged aren ruthenium rectangles in human breast cancer cells

Journal of Inclusion Phenomena and Macrocyclic Chemistry - Some novel benzimidazole-bridged aren ruthenium rectangle compounds of the general structure...     

Ferrocene Containing Polyimides as a Route to Low-κ Dielectric Materials

Polyimides incorporating the ferrocene unit were prepared by in situ curing of poly (amic acid) macromolecules with ferrocene, for the molecular-level design of low dielectric constant (low-κ) materials. The effects of ferrocene on dielectric properties of polyimide are investigated in detail in this study. Ferrocene containing polyimides exhibit a number of desirable properties including low-water absorption and admirable thermal stability. Systematic studies demonstrate that proper insertion of ferrocene into a polyimide backbone can give rise to a reduction in the material's dielectric constant. All composites were subjected to DSC measurements for the purpose of examining Tg from all composition. Scanning electron microscopy (SEM), X-ray diffraction (XRD) and the other conventional techniques were used for structural characterization.     

On pseudo symmetric monomial curves

We study monomial curves, toric ideals and monomial algebras associated to 4-generated pseudo symmetric numerical semigroups. Namely, we determine indispensable binomials of these toric ideals, give a characterization for these monomial algebras to have strongly indispensable minimal graded free resolutions. We also characterize when the tangent cones of these monomial curves at the origin are Cohen–Macaulay.     

On the Time-Dependent Delta-Shock Model Governed by the Generalized PóLya Process

One of the widely discussed in the literature and relevant in practice shock models is the delta-shock model that is described by the constant time of a system’s recovery after a shock. However, in practice, as time progresses and due to deterioration of a system, this recovery time is gradually increasing. This important phenomenon was not discussed in the literature so far. Therefore, in this paper, we are considering a time-dependent delta-shock model, i.e., the recovery time becomes an increasing function of time. Moreover, we assume that shocks occur according to the generalized Pólya process that contains the homogeneous Poisson process, the non-homogeneous Poisson process and the Pólya process as particular cases. For the defined survival model, we derive the corresponding survival function and the mean lifetime and study the related optimal replacement policy along with some relevant stochastic properties.

     

The crystallization kinetics of the Bi2O3-added MgO–Al2O3–SiO2–TiO2 glass ceramics system produced from industrial waste

Journal of Thermal Analysis and Calorimetry - Carbon nanotubes (CNTs) with different content of carboxylated groups on their surface (depending on the duration of their treatment with nitric acid)...     

Centri-voltammetric determination of glutathione

Centri-voltammetry is a method for concentrating an analyte on an electrode with the aid of a centrifuge. It can be performed in the presence or the absence of a solid carrier/support. This is followed by a voltammetric (analytical) scan. Specifically, we describe here an application of the technique to the determination of glutathione (GSH). Silica gel is used as the carrier precipitate to which gold nanoparticles were added in order to improve accumulation as a result of their strong affinity for thiols. Voltammetry was performed with a carbon paste electrode modified with multi-wall carbon nanotubes. The response to GSH is linear in the 25 and 800 μM concentration range (the correlation coefficient being 0.9915) and the relative standard deviation is 3.40 % (at 250 μM of GSH and n?=?6). The procedure was successfully applied to the determination of GSH in wine and in synthetic plasma using the standard addition method. The recoveries are 100.8 % and 100.0 %, respectively.

Elimination of Fast Chaotic Degrees of Freedom: On the Accuracy of the Born Approximation

We apply standard projection operator techniques known from nonequilibrium statistical mechanics to eliminate fast chaotic degrees of freedom in a low-dimensional dynamical system. Through the usual perturbative approach we end up in second order with a stochastic system where the fast chaotic degrees of freedom are modelled by Gaussian white noise. The accuracy of the perturbation expansion is analysed in detail by the discussion of an exactly solvable model.     

Determination of mercury in table salt samples by on-line medium exchange anodic stripping voltammetry

A new method for the determination of traces of total mercury by using a gold film electrode in salt samples was developed. Table salts are known to contain mercury at ultra-trace level as well as a high quantity of chloride ions that cause severe disturbance during the stripping step when gold is used as the electrode material in voltammetric measurements. The interference of high chloride content in the determination of mercury was eliminated by reducing its concentration down to 3 x 10(-3) mol L(-1) level which is optimum for the determination by using on-line medium exchange procedure immediately after the deposition step. The deposition potential applied to the electrode was maintained at 0.2 V (vs. Ag/AgCl double junction electrode) while the cell content was sucked by a pump and replaced with fresh electrolyte simultaneously. The analyte loss resulted from the air contact of the electrode was prevented by this means. The mercury ions present in the salt samples were collected at +0.2 V for 60 s, the electrolyte was replaced by 0.1 mol L(-1) HClO4 and the potential was scanned, attaining a detection limit of 0.17 microg L(-1), with R.S.D. of 1.2% (S/N=3). The recovery of the method was 94.6%. The performance and accuracy of the method was compared with that of atomic fluorescence spectrometry (AFS). Consequently, this developed method can offer a wide range of application in saline samples.