Neutral and ionic dissociation patterns in hexacoordinate silicon chelates: a model nucleophilic substitution at pentacoordinate silicon

A model nucleophilic-displacement reaction coordinate at pentacoordinate silicon is demonstrated by neutral and ionic dissociation equilibria through a stable hexacoordinate complex.     

Über die quartären Basen von Berberis vulgaris

Ohne Zusammenfassung     

Actions of Solvable Algebraic Groups on Central Simple Algebras

Let k be an algebraically closed base field of arbitrary characteristic. In this paper, we study actions of a connected solvable linear algebraic group G on a central simple algebra Q. The main result is the following: Q can be split G-equivariantly by a finite-dimensional splitting field, provided that G acts “algebraically,” i.e., provided that Q contains a G-stable order on which the action is rational. As an application, it is shown that rational torus actions on prime PI-algebras are induced by actions on commutative domains. Presented by Paul Smith.     

Diophantische Approximationen komplexer Zahlen

Ohne Zusammenfassung     

Über die Kettenbruchentwicklung komplexer Zahlen und Anwendungen auf diophantische Approximationen

Ohne Zusammenfassung     

Lifting problems and transgression for non-abelian gerbes

We discuss lifting and reduction problems for bundles and gerbes in the context of a Lie 2-group. We obtain a geometrical formulation (and a new proof) for the exactness of Breen’s long exact sequence in non-abelian cohomology. We use our geometrical formulation in order to define a transgression map in non-abelian cohomology. This transgression map relates the degree one non-abelian cohomology of a smooth manifold (represented by non-abelian gerbes) with the degree zero non-abelian cohomology of the free loop space (represented by principal bundles). We prove several properties for this transgression map. For instance, it reduces–in case of a Lie 2-group with a single object–to the ordinary transgression in ordinary cohomology. We describe applications of our results to string manifolds: first, we obtain a new comparison theorem for different notions of string structures. Second, our transgression map establishes a direct relation between string structures and spin structures on the loop space.