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141.
Mehrdad Nikravech Kamal Baba Bernard Leneindre Frédéric Rousseau 《Chemical Papers》2012,66(5):502-510
Processing the aerosol of metal salts in non-equilibrium plasma represents a promising technique that combines the advantages
of spray pyrolysis with the high reactivity of plasmas at nearlaboratory temperature in order to produce mixed-oxides and
perovskite materials. The aim of this paper is to describe the principles of this new technique and to present the various
applications and latest developments. This technique’s capacity to deposit various mixed metal oxides with precise stoichiometry
is demonstrated. It is shown that oxidant plasma species play a key role in the chemical transformation of starting materials
into oxides at laboratory temperature, while the configuration of the reactor determines the morphology and texture of the
deposited layers. Two different reactor configurations are presented. The porous layers of La
x
Sr1−x
MnO3 as the cathode for fuel cells were synthesised in a wave shock reactor configuration, while nanostructured ZnO-Al layers
to form a transparent conductive cathode for photovoltaic cells were deposited in the spray plasma reactor of the latest generation
for this technique. The experimental results emphasise the role of plasma species in the rate of chemical reactions and in
the chemical composition of the deposited layers. 相似文献
142.
143.
L. Z. Meneghini C. A. Junqueira F. R. Salazar M. Brandalise P. E. Fröehlich A. M. Bergold 《Journal of Analytical Chemistry》2013,68(9):772-780
A set of experimental designs was applied to develop and validate a spectrophotometric method using derivative transformation coupled with zero-crossing methodology for the quantification of darifenacin hydrobromide in extended-release tablet form. In the presence of the matricial interference, a central composite (face-centered) design was necessary to reach the best condition without interference in the quantification. The optimal system was confirmed using the function named Derringer’s desirability to assess high precision and low quantification limit. The best condition pointed was the first order to derivative transformation, Δλ = 4, scale factor 150, scanning speed 280 nm/s and anulation point in 239.4 nm as wavelength. From these parameters it was possible to perform the method validation resulting in R 2 = 0.999, concentration ranging from 0.10 to 2.50 μg/mL, recovery 98.65% and mean precision 97.67% (RSD = 0.0136). Additionally, robustness was assessed by a Plackett-Burman design, and no significant variability was obtained. The spectrophotometric method was compared with high-performance liquid chromatography method, resulting in no significant difference between the methods. 相似文献
144.
Dr. Yusaku Nomura Dr. Frédéric Thuaud Dr. Daisuke Sekine Prof. Dr. Akihiro Ito Satoko Maeda Dr. Hiroyuki Koshino Dr. Daisuke Hashizume Dr. Atsuya Muranaka Dr. Thomas Cruchter Prof. Dr. Masanobu Uchiyama Prof. Dr. Satoshi Ichikawa Prof. Dr. Akira Matsuda Prof. Dr. Minoru Yoshida Prof. Dr. Go Hirai Prof. Dr. Mikiko Sodeoka 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(35):8387-8392
A synthetic methodology to access all possible stereoisomers of spectomycin A1 (SMA1) and A2 (SMA2) has been established through late-stage diversification. The key reaction for the construction of all four diastereomers is an intramolecular cyclization based on the umpolung of π-allyl palladium species with bis(pinacolato)diborane (B2(pin)2). Silyl group assisted direct benzylic oxidation of each isomer enabled construction of the fragile β-hydroxytetralone skeleton to provide the SMAs. The relative and absolute stereochemistry of SMA2 was also determined, and the absolute stereochemistry of SMA1 was extrapolated based on the optical rotation of SMA2. The axial chirality of SMAs is discussed based on circular dichroism spectra and DFT calculations, and it is concluded that the M isomer is predominant in solution. Biochemical assessment of all isomers in vitro revealed that the C9 hydroxyl group and dimeric structure were both important for protein SUMOylation-inhibitory activity. 相似文献
145.
Sebastian Aland Stephan Schwarz Jochen Fröhlich Axel Voigt 《The European physical journal. Special topics》2013,220(1):185-194
In simulations of liquid metals, various model approximations, each of which justified by experimental results lead to a simplified two-phase flow problem. This paper discusses numerical justifications for these approaches and provides quantitative results for a single rising bubble as a benchmark. Representing a bubble as a rigid object is shown to be valid for low Eötvös numbers in contaminated systems. Qualitative differences can be observed for larger Eötvös numbers. Further simulations are undertaken with different ratios of inner and outer viscosity. The benchmark problem considered may also be interesting for more general applications. 相似文献
146.
Robert T. Paine William F. McNamara Jerzy Fr. Janik Eileen N. Duesler 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1-2):241-244
Abstract Aspects of the reactivity of metallophosphanes are presented along with the synthesis and structure determinations for new aluminophosphanes. 相似文献
147.
Paul Kautny Dorian Bader Dr. Berthold Stöger Prof. Dr. Georg A. Reider Prof. Dr. Johannes Fröhlich Dr. Daniel Lumpi 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(52):18887-18898
To shed light on intramolecular charge‐transfer phenomena in 1,2,3‐triazole‐linked materials, a series of 1,2,3‐triazole‐linked push–pull chromophores were prepared and studied experimentally and computationally. Investigated modifications include variation of donor and/or acceptor strength and linker moiety as well as regioisomers. Photophysical characterization of intramolecular charge‐transfer features revealed ambipolar behavior of the triazole linker, depending on the substitution position. Furthermore, non‐centrosymmetric materials were subjected to second‐harmonic generation measurements, which revealed the high nonlinear optical activity of this class of materials. 相似文献
148.
Manon Catherin Olatz Uranga-Barandiaran Arnaud Brosseau Dr. Rémi Métivier Dr. Gabriel Canard Dr. Anthony D'Aléo Dr. David Casanova Prof. Frédéric Castet Dr. Elena Zaborova Prof. Frédéric Fages 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(17):3818-3828
We describe the synthesis of a series of covalently linked dimers of quadrupolar curcuminoid-BF2 dyes and the detailed investigation of their solvent-dependent spectroscopic and photophysical properties. In solvents of low polarity, intramolecular folding induces the formation of aggregated chromophores, the UV/Vis absorption spectra of which display the optical signature characteristic of weakly-coupled H-aggregates. The extent of folding and, in turn, of ground-state aggregation is strongly dependent on the nature of the flexible linker. Steady-state and time-resolved fluorescence emission spectroscopies show that the Frenkel exciton relaxes into a fluorescent symmetrical excimer state with a long lifetime. Furthermore, our in-depth studies show that a weakly emitting excimer lies on the pathway toward a photocyclomer. Two-dimensional 1H NMR spectroscopy and density functional theory (DFT) allowed the structure of the photoproduct to be established. To our knowledge, this represents the first example of a [2π+2π] photodimerization of the curcuminoid chromophore. 相似文献
149.
Frühwirth-Schnatter Sylvia Ingrassia Salvatore Mayo-Iscar Agustín 《Advances in Data Analysis and Classification》2019,13(1):1-5
Advances in Data Analysis and Classification - 相似文献
150.
Dr. Siddhartha De Dr. Alexandrine Flambard Dr. Delphine Garnier Patrick Herson Dr. Frank H. Köhler Dr. Abhishake Mondal Dr. Karine Costuas Dr. Béatrice Gillon Prof. Rodrigue Lescouëzec Dr. Boris Le Guennic Dr. Frédéric Gendron 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(52):12120-12136
The local magnetic structure in the [FeIII(Tp)(CN)3]− building block was investigated by combining paramagnetic Nuclear Magnetic Resonance (pNMR) spectroscopy and polarized neutron diffraction (PND) with first-principle calculations. The use of the pNMR and PND experimental techniques revealed the extension of spin-density from the metal to the ligands, as well as the different spin mechanisms that take place in the cyanido ligands: Spin-polarization on the carbon atoms and spin-delocalization on the nitrogen atoms. The results of our combined density functional theory (DFT) and multireference calculations were found in good agreement with the PND results and the experimental NMR chemical shifts. Moreover, the ab-initio calculations allowed us to connect the experimental spin-density map characterized by PND and the suggested distribution of the spin-density on the ligands observed by NMR spectroscopy. Interestingly, significant differences were observed between the pseudo-contact contributions of the chemical shifts obtained by theoretical calculations and the values derived from NMR spectroscopy using a simple point-dipole model. These discrepancies underline the limitation of the point-dipole model and the need for more elaborate approaches to break down the experimental pNMR chemical shifts into contact and pseudo-contact contributions. 相似文献