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961.
A directed photoelectron beam is obtained when photoelectrons from a sharp metal tip irradiated by femtosecond laser pulses are passed through a quartz nanocapillary. Such a nanolocalized photoelectron train makes it possible to conduct experiments with simultaneous femtosecond time and nanometer spatial resolutions. 相似文献
962.
Bourennane M Eibl M Gaertner S Kiesel N Kurtsiefer C Weinfurter H 《Physical review letters》2006,96(10):100502
We experimentally demonstrate the entanglement persistency when losing photons in three- and four-photon polarization-entangled states. The entanglement properties of the mixed states obtained from multiphoton spontaneous parametric down-conversion are studied via witness and positive partial transpose approaches. Together with a quantification of the bipartite entanglement such analysis enables intuitive understanding of novel multiparty quantum communication protocols. 相似文献
963.
Reif B Xue Y Agarwal V Pavlova MS Hologne M Diehl A Ryabov YE Skrynnikov NR 《Journal of the American Chemical Society》2006,128(38):12354-12355
Rapid advances in solid-state MAS NMR made it possible to probe protein dynamics on a per-residue basis, similar to solution experiments. In this work we compare methyl 2H relaxation rates measured in the solid and liquid samples of alpha-spectrin SH3 domain. The solution data are treated using a model-free approach to separate the contributions from the overall molecular tumbling and fast internal motion. The latter part forms the basis for comparison with the solid-state data. Although the accuracy of solid-state measurements is limited by deuterium spin diffusion, the results suggest a significant similarity between methyl dynamics in the two samples. This is a potentially important observation, preparing the ground for combined analysis of the dynamics data by solid- and solution-state NMR. 相似文献
964.
Nikolai A. Larkin Márcio Hiran Simões 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》2016,67(4):98
An initial boundary value problem for the 3D Kawahara equation posed on a channel-type domain was considered. The existence and uniqueness results for global regular solutions as well as exponential decay of small solutions in the H2-norm were established. 相似文献
965.
We analyzed how the approach developed for the microindentation of non-uniform elastic solids can be adapted to analyze the atomic force microscopy (AFM) probing of ultrathin (1-100 nm thick) polymer films on a solid substrate, as well as polymer films with a multilayered structure. We suggested that recent Johnson's modification of the contact mechanics model that included a viscoelastic contribution could also be utilized to analyze rate-dependent loading data for polymer surfaces. The graded model proposed for microindentation experiments was modified allowing to account not only for variable elastic moduli within different layers but also for the gradient of properties between layers within a transition zone. Two examples of a recent application of this model for molecularly thick hyperbranched polymer monolayers (<3 nm thick) and tri-layered polymer films (20-40 nm thick) tethered to a solid substrate were presented and discussed. In both cases, complex shapes of both loading curves and elastic modulus depth profiles obtained from experimental AFM data were successfully fitted by the graded model with realistic structural parameters. 相似文献
966.
Shenderovich IG Tolstoy PM Golubev NS Smirnov SN Denisov GS Limbach HH 《Journal of the American Chemical Society》2003,125(38):11710-11720
The low-temperature (1)H, (19)F, and (15)N NMR spectra of mixtures of collidine-(15)N (2,4,6-trimethylpyridine-(15)N, Col) with HF have been measured using CDF(3)/CDF(2)Cl as a solvent in the temperature range 94-170 K. Below 140 K, the slow proton and hydrogen bond exchange regime is reached where four hydrogen-bonded complexes between collidine and HF with the compositions 1:1, 2:3, 1:2, and 1:3 could be observed and assigned. For these complexes, chemical shifts and scalar coupling constants across the (19)F(1)H(19)F and (19)F(1)H(15)N hydrogen bridges have been measured which allowed us to determine the chemical composition of the complexes. The simplest complex, collidine hydrofluoride ColHF, is characterized at low temperatures by a structure intermediate between a molecular and a zwitterionic complex. Its NMR parameters depend strongly on temperature and the polarity of the solvent. The 2:3 complex [ColHFHCol](+)[FHF](-) is a contact ion pair. Collidinium hydrogen difluoride [ColH](+)[FHF](-) is an ionic salt exhibiting a strong hydrogen bond between collidinium and the [FHF](-) anion. In this complex, the anion [FHF](-) is subject to a fast reorientation rendering both fluorine atoms equivalent in the NMR time scale with an activation energy of about 5 kcal mol(-)(1) for the reorientation. Finally, collidinium dihydrogen trifluoride [ColH](+)[F(HF)(2)](-) is an ionic pair exhibiting one FHN and two FHF hydrogen bonds. Together with the [F(HF)(n)()](-) clusters studied previously (Shenderovich et al., Phys. Chem. Chem. Phys. 2002, 4, 5488), the new complexes represent an interesting model system where the evolution of scalar couplings between the heavy atoms and between the proton and the heavy atoms of hydrogen bonds can be studied. As in the related FHF case, we observe also for the FHN case a sign change of the coupling constant (1)J(FH) when the F.H distance is increased and the proton shifted to nitrogen. When the sign change occurs, that is, (1)J(FH) = 0, the heavy atom coupling constant (2)J(FN) remains very large, of the order of 95 Hz. Using the valence bond order model and hydrogen bond correlations, we describe the dependence of the hydrogen bond coupling constants, of hydrogen bond chemical shifts, and of some H/D isotope effects on the latter as a function of the hydrogen bond geometries. 相似文献
967.
S. V. Chekalin V. S. Letokhov V. S. Likhachev V. G. Movshev 《Applied physics. B, Lasers and optics》1984,33(1):57-61
A laser photodesorption microscope has been applied to obtain 4×103-fold images of rhodamine crystals on a tip with a diameter of 66m. Peculiarities of the formation of these images have been studied with different values of electric field strength on the tip and laser pulse intensities. 相似文献
968.
Ring currents can exert a large effect upon the chemical shielding of NMR resonances. The analytical expression developed by Waugh and Fessenden (Waugh, J. S.; Fessenden, R. W. J. Am. Chem. Soc. 1957, 79, 846) and Johnson and Bovey (Johnson, C. E.; Bovey, F. A. J. Chem. Phys. 1957, 29, 1012) only quantifies the contribution of ring currents to the isotropic component of the shielding tensor. In the work described here an additional analytical expression is developed so that the contribution of ring currents to the full shielding tensor can be calculated, allowing an estimate of the influence of ring currents upon the chemical shielding anisotropy (CSA, Deltasigma). To test that this pair of analytical expressions can provide a reasonable estimate of the contribution of ring currents to the full shielding tensor a series of density functional calculations (DFT) were carried out. A shielding tensor in a model compound was calculated in two distinct ways. For the first series, DFT shielding calculations of the model compound were carried out in the presence of a benzene ring. For the second series a ring current contribution to the shielding tensor was calculated via the new expressions, and this was added to the result of a DFT shielding calculation which used in place of benzene the nonaromatic analogue 1,3 cyclohexadiene. The two series of results proved to be in excellent agreement. The pair of analytical expressions are used to calculate ring current contributions to the CSA (Deltasigma) of 1H(N) backbone amide resonances in a structure of the second type 2 module from the protein fibronectin. Significant CSA variations are predicted in particular for the 1H(N) of G42 which is most likely involved in a N-H...tpi aromatic hydrogen bond. 相似文献
969.
Cooke F Kopelev N Schofield H Boyce G Dunne S 《Journal of chemical information and computer sciences》2002,42(5):1016-1027
Due to the high costs of purchasing, supporting and training users of desktop chemical information systems, it is important to understand users' behavior in order that deficiencies in their search efficiency and effectiveness can be identified and addressed. CrossFire generates comprehensive log files that can be examined to determine the nature of search activity. At GSK (GlaxoSmithKline) a Log File Parser, CrossParse, has been developed in Visual Basic that enables analysis by individual user name, groups of users or the whole user population. Log files can be analyzed for occasions when specific structural features are built, specific types of search are done and how the results are manipulated. CrossParse produces output that can be saved and analyzed within Microsoft Excel. It also allows determination of numbers of active concurrent users on the CrossFire system. CrossParse has been used at GSK (ex-SmithKline Beecham sites) to examine the search behavior of medicinal and synthetic chemists. Additionally, it has been used by MIMAS (Manchester Information and Associated Services) to compare the search behavior of trained and untrained users in the higher education community and to identify any areas where improvements to training can be made. Use of CrossParse in both organizations has allowed identification of areas where users may have difficulties using CrossFire. This will provide valuable feedback to MDL Inc., the authors of the CrossFire application, and guide them in enhancing CrossFire. 相似文献
970.
Sergiu P. Palii Nikolai I. Raevskii Dmitrii V. Zagorevskii Konstantin M. Indrichan Yurii A. Borisov Nikolai V. Gerbeleu Yurii S. Nekrasov D. V. Zagorevskii Yu. S. Nekrasov O- S. Timofeev A. I. Gren' 《Journal of mass spectrometry : JMS》1991,26(9):742-745
Structures of [ZnNCR]+ and [Zn(NCR)2]+ ions (R = H, Me), which are abundant in the mass spectra of many types of coordination compounds, were studied by the MNDO method. In all cases the most stable isomers correspond to the zinc ion coordinated with the nitrogen(s) of the nitrile ligand. For [Zn(NCR)2]+, the N-Zn-N angles are ~108°. 相似文献