全文获取类型
收费全文 | 204篇 |
免费 | 13篇 |
专业分类
化学 | 115篇 |
晶体学 | 1篇 |
力学 | 3篇 |
数学 | 24篇 |
物理学 | 74篇 |
出版年
2024年 | 4篇 |
2023年 | 2篇 |
2022年 | 2篇 |
2021年 | 4篇 |
2020年 | 4篇 |
2019年 | 3篇 |
2018年 | 9篇 |
2017年 | 3篇 |
2016年 | 11篇 |
2015年 | 9篇 |
2014年 | 8篇 |
2013年 | 15篇 |
2012年 | 20篇 |
2011年 | 14篇 |
2010年 | 16篇 |
2009年 | 7篇 |
2008年 | 4篇 |
2007年 | 7篇 |
2006年 | 10篇 |
2005年 | 12篇 |
2004年 | 6篇 |
2003年 | 5篇 |
2002年 | 1篇 |
2001年 | 3篇 |
2000年 | 2篇 |
1998年 | 1篇 |
1997年 | 1篇 |
1995年 | 3篇 |
1994年 | 1篇 |
1993年 | 3篇 |
1991年 | 1篇 |
1989年 | 1篇 |
1988年 | 1篇 |
1986年 | 2篇 |
1979年 | 1篇 |
1978年 | 2篇 |
1977年 | 1篇 |
1976年 | 4篇 |
1975年 | 6篇 |
1974年 | 6篇 |
1973年 | 2篇 |
排序方式: 共有217条查询结果,搜索用时 15 毫秒
41.
Mecke AC Sundberg J Granqvist S Echternach M 《The Journal of the Acoustical Society of America》2012,131(1):435-441
The closed quotient, i.e., the ratio between the closed phase and the period, is commonly studied in voice research. However, the term may refer to measures derived from different methods, such as inverse filtering, electroglottography or high-speed digital imaging (HSDI). This investigation compares closed quotient data measured by these three methods in two boy singers. Each singer produced sustained tones on two different pitches and a glissando. Audio, electroglottographic signal (EGG), and HSDI were recorded simultaneously. The audio signal was inverse filtered by means of the decap program; the closed phase was defined as the flat minimum portion of the flow glottogram. Glottal area was automatically measured in the high speed images by the built-in camera software, and the closed phase was defined as the flat minimum portion of the area-signal. The EGG-signal was analyzed in four different ways using the matlab open quotient interface. The closed quotient data taken from the EGG were found to be considerably higher than those obtained from inverse filtering. Also, substantial differences were found between the closed quotient derived from HSDI and those derived from inverse filtering. The findings illustrate the importance of distinguishing between these quotients. 相似文献
42.
Niko Guskos Spiros Glenis Janusz Typek Grzegorz Zolnierkiewicz Pawel Berczynski Kamil Wardal Aleksander Guskos Daniel Sibera Dariusz Moszyński Witold Lojkowski Urszula Narkiewicz 《Central European Journal of Physics》2012,10(2):470-477
Fine particles of ZnFe2O4 were synthesized by a wet chemical method in the (80 wt.% Fe2O3 + 20 wt.% ZnO) system. The morphological and structural properties of the mixed system were investigated by scanning electron microscopy, X-ray diffraction, inductively coupled plasma atomic emission, and X-ray photoelectron spectroscopy. The major phase was determined to be the ZnFe2O4 spinel with particle size of 11 nm. The magnetic properties of the material were investigated by ferromagnetic resonance (FMR) in the temperature range from liquid helium to room temperature. A very intense, asymmetric FMR signal from ZnFe2O4 nanoparticles was recorded, which has been analyzed in terms of two Callen-lineshape lines. Temperature dependence of the FMR parameters was obtained from fitting the experimental lines with two component lines. Analysis of the FMR spectra in terms of two separate components indicates the presence of strongly anisotropic magnetic interactions. 相似文献
43.
Artem Plyusnin Jingwei He Cindy Elschner Miho Nakamura Julia Kulkova Axel Spickenheuer Christina Scheffler Lippo V. J. Lassila Niko Moritz 《Molecules (Basel, Switzerland)》2021,26(5)
The use of bioresorbable fracture fixation plates made of aliphatic polyesters have good potential due to good biocompatibility, reduced risk of stress-shielding, and eliminated need for plate removal. However, polyesters are ductile, and their handling properties are limited. We suggested an alternative, PLAMA (PolyLActide functionalized with diMethAcrylate), for the use as the matrix phase for the novel concept of the in situ curable bioresorbable load-bearing composite plate to reduce the limitations of conventional polyesters. The purpose was to obtain a preliminary understanding of the chemical and physical properties and the biological safety of PLAMA from the prospective of the novel concept. Modifications with different molecular masses (PLAMA-500 and PLAMA-1000) were synthesized. The efficiency of curing was assessed by the degree of convergence (DC). The mechanical properties were obtained by tensile test and thermomechanical analysis. The bioresorbability was investigated by immersion in simulated body fluid. The biocompatibility was studied in cell morphology and viability tests. PLAMA-500 showed better DC and mechanical properties, and slower bioresorbability than PLAMA-1000. Both did not prevent proliferation and normal morphological development of cells. We concluded that PLAMA-500 has potential for the use as the matrix material for bioresorbable load-bearing composite fracture fixation plates. 相似文献
44.
Niko Naumann 《Comptes Rendus Mathematique》2003,336(4):289-292
R. Pellikaan (Arithmetic, Geometry and Coding Theory, Vol. 4, Walter de Gruyter, Berlin, 1996, pp. 175–184) introduced a two variable zeta-function Z(t,u) for a curve over a finite field which, for u=q, specializes to the usual zeta-function and he proved rationality: Z(t,u)=(1?t)?1(1?ut)?1P(t,u) with . We prove that P(t,u) is absolutely irreducible. This is motivated by a question of J. Lagarias and E. Rains about an analogous two variable zeta-function for number fields. To cite this article: N. Naumann, C. R. Acad. Sci. Paris, Ser. I 336 (2003). 相似文献
45.
This report describes composite proton electrolytes composed of nanosize activated aluminium oxide particles with different
surface acidity suspended in a poly(vinyl acetate)/glycerine matrix. The conductivity of the composite was found to increase
by going from basic to neutral to acidic aluminium oxide. Tests in laminated electrochromic devices with tungsten oxide and
nickel hydroxide films showed that the acidic electrolyte is compatible with WO3, the basic electrolyte is compatible with Ni(OH)2, and the neutral electrolyte is compatible with both of the electrodes.
Paper presented at the 4th Euroconference on Solid State Ionics, Renvyle, Galway, Ireland, Sept. 13–19, 1997 相似文献
46.
47.
Niko Ernsting 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》1994,106(5):608-609
48.
Phillips ST Piersanti G Rüth M Gubernator N van Lengerich B Bartlett PA 《Organic letters》2004,6(24):4483-4485
The synthesis of @-tide beta-strand peptidomimetics has been improved such that oligomers now can be obtained from solution- and solid-phase synthesis protocols approaching the efficiency and flexibility of peptide chemistry. These methods enable the synthesis of @-tide oligomers with a variety of amino acids and with lengths up to 13 units. [reaction: see text] 相似文献
49.
Dual Effect of Manganese Oxide Micromotors: Catalytic Degradation and Adsorptive Bubble Separation of Organic Pollutants
下载免费PDF全文
![点击此处可从《Chemistry (Weinheim an der Bergstrasse, Germany)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Owies M. Wani Muhammad Safdar Dr. Niko Kinnunen Prof. Janne Jänis 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(4):1244-1247
Manganese oxide (MnO2) based micromotors exhibiting a dual effect, that is, catalytic degradation and adsorptive bubble separation, were employed for water remediation. The dual effect of MnO2 microparticles led to a greater than 90 % of decolorization of non‐biodegradable organic dyes in just 1 h, without the need for external agitation or bubble generation. These findings suggest high potential of MnO2 micromotors for decontamination of organic pollutants from wastewaters or natural water reserves. 相似文献
50.
Greta Wistbacka Pedro Amarante Andrade Susanna Simberg Britta Hammarberg Maria Södersten Jan G. Švec Svante Granqvist 《Journal of voice》2018,32(1):126.e11-126.e22