Excitation and decay of low-lying nuclear states in a dense plasma produced by a subpicosecond laser pulse

The excitation of low-lying nuclear levels in a hot, dense plasma, produced by a subpicosecond pulse with intensity exceeding 10¹⁶ W/cm², is investigated theoretically and experimentally. The basic channels of electronic (inelastic scattering and inverse internal electron convergence) and photon (photoexcitation) excitations of such states as well as the influence of the broadening of a nuclear level on the excitation efficiency and the presence of hot electronic component are examined. The experimental data from measurements of the decay kinetics of the low-lying nuclear level 6.238 keV of the stable isotope ¹⁸¹Ta, which were obtained on two experimental laser systems, are presented.     

Features of the phase behavior of gamma-irradiated polytetrafluoroethylene powder

By using the technique of thermomechanical spectroscopy, an amorphous and three crystalline (high melting, intermediate, and low melting) blocks of the topological structures of polytetrafluoroethylene (PTFE) powder were characterized and their behavior under γ-radiation up to 2420 kGy was explored. The powder has an anisotropic topological structure. Starting from a dose of 4 kGy, the structure is radically changed with the long-range orientation of chains in the intermediate and high melting crystalline blocks of PTFE being replaced by a short range orientation of cluster association structures. The temperatures of glass transition and melting point continuously decreased with an increased dose of irradiation. The influence of γ-radiation on the powder and sheet of PTFE are essentially the same, the formation of amorphous character.     

稳态实验考察经模拟道路老化的全配方稀燃Nox捕集催化剂上的Nox还原

Fully formulated lean NOx trap(LNT)catalysts of the type Pt/Rh/BaO/Al2O3 were prepared with and without incorporation of CeO2-ZrO2 in the washcoat,and their NOx reduction behavior was evaluated in steady-state,continuous flow experiments.In the fresh state, the CeO2-ZrO2 addition was found to exert little effect on NOx reduction activity using H2,CO,and NH3 as the reductants.However,after simulated road aging,NOx reduction activity was significantly impaired for the CeO2-ZrO2-free catalyst,whereas the perfo...     

How the Asymmetric Nature of IP Traffic Influences the Cost of the Underlying Optical Layer

In this article the influence of the asymmetric nature of (IP) traffic on the cost of the underlying optical transport network is investigated over a time frame of six years using a realistic traffic forecast for a European fiber-optic network. The currently deployed transport networks contain bidirectional optical line systems and are thus inherently symmetric, although the traffic that has to be conveyed over those networks is asymmetric. This article shows that a cost reduction of up to 38% can be obtained if the bidirectional line systems are replaced by unidirectional ones.     

Orbital contributions to relativistic corrections of the NMR nuclear magnetic shielding tensor originated in scalar field-dependent operators

In this work relativistic corrections to the magnetic shielding constant (σM), which arise from scalar field-dependent operators (both linear and bilinear), are calculated and decomposed into contributions from molecular orbitals (MOs). Numerical results for the magnetic shielding constant of the heavy nucleus X in closed shell atomic ions X^? and HX compounds (X = F, Cl, Br, I) are presented. The relative importance of inner-shell and valence electrons in the definition of each one of these terms is thus assessed and its relation with their sensitivity to changes in a chemical environment is discussed.     

Quantum coherent control of the vibrational dynamics of a polyatomic molecule using adaptive feedback control of a femtosecond laser

We simulate adaptive feedback control to coherently shape a femtosecond infrared laser pulse by means of a 4f-spatial light modulator in order to selectively excite the rovibrational modes of a polyatomic molecule. We preferentially populate an arbitrarily chosen upper rovibrational level by only employing these tailored temporally shaped pulses. A second laser would then allow for mode selective chemistry to interact selectively with the excited population. Alternatively the excited molecules enhanced reactivity could be exploited for selective chemistry.     

S-matrix approach to the equation of state of dilute nuclear matter

Based on the general analysis of the grand canonical partition function in the S-matrix framework, a method is presented to calculate the equation of state of dilute warm nuclear matter. The result is a model-independent virial series for the pressure and density that systematically includes contributions from all the ground and excited states of all the stable nuclear species and their scattering channels. The multiplicity distribution of these species to keep the matter in statistical equilibrium is found out and then the pressure, incompressibility and the symmetry energy of the system are evaluated. The calculated symmetry energy coefficients are found to be in fair agreement with the recent experimental data.