Kinetic analysis of actinides using differential spectrophotometry

The kinetic method developed allowed us to analyse of two-component actinide mixtures without separation. The concentration changes in the system where complex dissociation reaction takes place were determined by spectrophotometry.     

Indoles

An intermediate, which proved to be a dimer of N-(-methylpyrrolino)-2-aminopyridine, was isolated during the synthesis of 2-methyl-7-azatryptamine from 2-pyridylhydrazine and- chloropropyl methyl ketone under mild conditions.See [1] for communication XXVIII.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 9, pp. 1202–1207, September, 1972     

Phenazineoxonium chloranilatomanganate and chloranilatoferrate: synthesis,structure, magnetic properties,and Mössbauer spectra

Russian Chemical Bulletin - Crystalline compounds (H3O)2(phz)3M2(C6O4Cl2)3·(CH3COCH3) n ·(H2O) n (n = 0?2, M = Mn (1), Fe (3)) were obtained in an acetone-water-tetrahydrofuran...     

Dynamics of Vortex Rossby Waves in Tropical Cyclones,Part 1: Linear Time‐Dependent Evolution on an f‐Plane

Analyses of observational data on hurricanes in the tropical atmosphere indicate the existence of spiral rainbands which propagate outward from the eye and affect the structure and intensity of the hurricane. These disturbances may be described as vortex Rossby waves. This paper describes the evolution of barotropic vortex Rossby waves in a cyclonic vortex in a two‐dimensional configuration where the variation of the Coriolis force with latitude is ignored. The waves are forced by a constant‐amplitude boundary condition at a fixed radius from the center of the vortex and propagate outward. The mean flow angular velocity profile is taken to be a quadratic function of the radial distance from the center of the vortex and there is a critical radius at which it is equal to the phase speed of the waves. For the case of waves with steady amplitude, an exact solution is derived for the steady linearized equations in terms of hypergeometric functions; this solution is valid in the outer region away from the critical radius. For the case of waves with time‐dependent amplitude, asymptotic solutions of the linearized equations, valid for late time, are obtained in the outer and inner regions. It is found that there are strong qualitative similarities between the conclusions on the evolution of the vortex waves in this configuration and those obtained in the case of Rossby waves in a rectangular configuration where the latitudinal gradient of the Coriolis parameter is taken into account. In particular, the amplitude of the steady‐state outer solution is greatly attenuated and there is a phase change of across the critical radius, and in the linear time‐dependent configuration, the outer solution approaches a steady state in the limit of infinite time, while the amplitude of the inner solution grows on a logarithmic time scale and the width of the critical layer approaches zero.     

Dynamics of Vortex Rossby Waves in Tropical Cyclones,Part 2: Nonlinear Time‐Dependent Asymptotic Analysis on a β‐Plane

Vortex Rossby waves in cyclones in the tropical atmosphere are believed to play a role in the observed eyewall replacement cycle, a phenomenon in which concentric rings of intense rainbands develop outside the wall of the cyclone eye, strengthen and then contract inward to replace the original eyewall. In this paper, we present a two‐dimensional configuration that represents the propagation of forced Rossby waves in a cyclonic vortex and use it to explore mechanisms by which critical layer interactions could contribute to the evolution of the secondary eyewall location. The equations studied include the nonlinear terms that describe wave‐mean‐flow interactions, as well as the terms arising from the latitudinal gradient of the Coriolis parameter. Asymptotic methods based on perturbation theory and weakly nonlinear analysis are used to obtain the solution as an expansion in powers of two small parameters that represent nonlinearity and the Coriolis effects. The asymptotic solutions obtained give us insight into the temporal evolution of the forced waves and their effects on the mean vortex. In particular, there is an inward displacement of the location of the critical radius with time which can be interpreted as part of the secondary eyewall cycle.     

Skeletal Wagner-Meerwein rearrangement of perhydro-3a,6;4,5-diepoxyisoindoles

An investigation of a skeletal Wagner-Meerwein rearrangement of variously substituted or quinoline-annulated 3a,6;4,5-diepoxyisoindol-1-ones is reported. Optimum reaction conditions (Ac₂O, BF₃·OEt₂, rt) were discovered for the formation of the target 4,6-epoxycyclopenta[c]pyridines in 40-80% yields. It was shown that the direction of the sigmatropic rearrangement of 3a,6;4,5-diepoxyisoindol-1-ones depended dramatically on the carboxyl group position (exo-/endo-) in the oxabicyclo[2.2.1]heptane moiety. The spatial structure of previously unknown 7,9-epoxycyclopenta[4,5]pyrido[1,2-a]quinolines derived from Wagner-Meerwein rearrangement of 2,11b-epoxyoxireno[6,7]isoindolo[2,1-a]quinolines was established based on the X-ray analysis data. The skeletal rearrangement proceeded regio- and stereospecifically in all the cases examined due to the absence of the epimerization of the carbon atoms adjacent to the carbocation centres.