全文获取类型
收费全文 | 497篇 |
免费 | 3篇 |
专业分类
化学 | 311篇 |
晶体学 | 3篇 |
力学 | 66篇 |
数学 | 16篇 |
物理学 | 104篇 |
出版年
2022年 | 5篇 |
2020年 | 9篇 |
2019年 | 5篇 |
2018年 | 13篇 |
2017年 | 15篇 |
2016年 | 12篇 |
2015年 | 11篇 |
2014年 | 17篇 |
2013年 | 15篇 |
2012年 | 21篇 |
2011年 | 16篇 |
2010年 | 20篇 |
2009年 | 18篇 |
2008年 | 18篇 |
2007年 | 21篇 |
2006年 | 15篇 |
2005年 | 19篇 |
2004年 | 20篇 |
2003年 | 14篇 |
2002年 | 15篇 |
2001年 | 14篇 |
2000年 | 6篇 |
1999年 | 6篇 |
1998年 | 5篇 |
1997年 | 5篇 |
1995年 | 5篇 |
1994年 | 5篇 |
1992年 | 7篇 |
1991年 | 8篇 |
1990年 | 6篇 |
1989年 | 6篇 |
1987年 | 8篇 |
1986年 | 4篇 |
1985年 | 4篇 |
1984年 | 4篇 |
1983年 | 4篇 |
1982年 | 5篇 |
1981年 | 6篇 |
1979年 | 5篇 |
1978年 | 6篇 |
1977年 | 6篇 |
1976年 | 7篇 |
1975年 | 5篇 |
1974年 | 7篇 |
1973年 | 8篇 |
1972年 | 5篇 |
1970年 | 6篇 |
1969年 | 3篇 |
1968年 | 3篇 |
1967年 | 6篇 |
排序方式: 共有500条查询结果,搜索用时 15 毫秒
431.
Roman S. Pavelyev Sergey G. Gnevashev Rusalia M. Vafina Oleg I. Gnezdilov Alexey B. Dobrynin Svetlana A. Lisovskaya Liliya E. Nikitina Evgenii N. Klimovitskii 《Mendeleev Communications》2012,22(3):127-128
Both exo- and endo-isomers of 4-phenyl-3,5,8-trioxabicyclo[5.1.0]octane were reacted with thiophenol to afford individual diastereomers of hydroxy sulfides which were further processed in search for new antimycotic substances. 相似文献
432.
Kataeva O. N. Mamedova V. L. Nikitina K. A. Metlushka K. E. Ivshin K. A. Krupskaya Yu. V. Kataev V. E. Sinyashin O. G. Alfonsov V. A. 《Russian Chemical Bulletin》2017,66(2):362-367
Russian Chemical Bulletin - One-dimensional coordination polymer was obtained by cation exchange reaction of triethylammonium salt of methyl ent-16α-H-phosphonyloxybeyeran-19-oate with CuCl2.... 相似文献
433.
434.
E. V. Nikitina N. A. Kazakovtseva M. A. Maikov V. B. Malkov E. A. Karfidov A. Yu. Chuikin 《Russian Journal of Electrochemistry》2018,54(9):697-701
The interaction of the monel alloy and its corrosion resistance in a melt of alkali metal carbonates in an oxidizing atmosphere was studied. The selectivity of alloy dissolution and modification of the electrode surface after storage at a constant anode potential were analyzed. The generation and development of local corrosion defects (pit corrosion, intercrystallite corrosion, corrosion cracking) on monel alloy (70% nickel, 28% copper), copper, and nickel electrodes in the molten eutectic of lithium, sodium, and potassium carbonates at a working temperature of 773 K were studied. The anode polarization was accompanied by a change in the state of the electrode surface. 相似文献
435.
K. E. Metlushka D. N. Sadkova K. A. Nikitina L. N. Shaimardanova O. N. Kataeva V. A. Alfonsov 《Russian Journal of General Chemistry》2016,86(3):515-521
Phosphoric acid derivatives containing chiral Betti base fragment were synthesized by reacting racemic and enantiopure N-Boc-protected 1-(α-aminobenzyl)-2-naphthols with diethyl chlorophosphate followed by deprotection. 相似文献
436.
Nikolay E. Polyakov Tatyana V. Leshina Alexey V. Tkachev Irina A. Nikitina Natalia A. Pankrushina 《Journal of photochemistry and photobiology. A, Chemistry》2008,197(2-3):290-294
The NMR technique has been applied to characterize the phototransformation products of the natural alkaloid lappaconitine. It was demonstrated that the photolysis of lappaconitine 1 results in cleavage of the ester bond with elimination of N-acetylanthranilic acid. The final reaction product was found to be an immonium salt 4 of N-acetylanthranilic acid and enamine 3. An equilibrium between the imine cation and the enamine 3 was detected. 相似文献
437.
E. E. Ergozhin G. K. Kabulova A. I. Nikitina N. A. Bektenov 《Russian Journal of Applied Chemistry》2008,81(8):1356-1359
Sorption of chromium(III) ions by cation exchangers based on oil residue and ED-20 epoxy resin was studied in comparison with that of KU-2 × 8 industrial cation exchanger. 相似文献
438.
Svetlana G. D'yachkova Nina K. Gusarova Elena A. Nikitina Andrei V. Afonin Eleonora N. Deryagina Natal'ya V. Russavskaya 《Phosphorus, sulfur, and silicon and the related elements》2013,188(7):1355-1360
(Organylthio)chloroacetylenes react with aliphatic 1,2-dithiols in dimethyl sulfoxide at 20–25°C in the presence of a two-fold molar excess of alkali to form 2-[(alkylthio)methyliden]-1,3-dithiolanes in up to 66% yield. 相似文献
439.
K. Kh. Khakimbolatova E. E. Ergozhin T. K. Chalov T. V. Kovrigina A. I. Nikitina 《Russian Journal of Applied Chemistry》2010,83(6):941-944
The platinum(IV) and palladium(II) sorption properties under static conditions were examined for new polyfunctional anion
exchangers based on resorcinol diglycidyl ether, monoethanolamine vinyl ether, allyl bromide, and various amines. 相似文献
440.