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91.
We construct a configurational entropy measure in functional space. We apply it to several nonlinear scalar field models featuring solutions with spatially-localized energy, including solitons and bounces in one spatial dimension, and critical bubbles in three spatial dimensions, typical of first-order phase transitions. Such field models are of widespread interest in many areas of physics, from high energy and cosmology to condensed matter. Using a variational approach, we show that the higher the energy of a trial function that approximates the actual solution, the higher its relative configurational entropy, defined as the absolute difference between the configurational entropy of the actual solution and of the trial function. Furthermore, we show that when different trial functions have degenerate energies, the configurational entropy can be used to select the best fit to the actual solution. The configurational entropy relates the dynamical and informational content of physical models with localized energy configurations. 相似文献
92.
We develop a cluster expansion for the probability of full connectivity of high density random networks in confined geometries. In contrast to percolation phenomena at lower densities, boundary effects, which have previously been largely neglected, are not only relevant but dominant. We derive general analytical formulas that show a persistence of universality in a different form to percolation theory, and provide numerical confirmation. We also demonstrate the simplicity of our approach in three simple but instructive examples and discuss the practical benefits of its application to different models. 相似文献
93.
Maria Philippou Yiolanda Damianou Xenia Miscouridou Georgios C. Georgiou 《Meccanica》2017,52(9):2081-2099
We solve analytically the cessation flows of a Newtonian fluid in circular and plane Couette geometries assuming that wall slip occurs provided that the wall shear stress exceeds a critical threshold, the slip yield stress. In steady-state, slip occurs only beyond a critical value of the angular velocity of the rotating inner cylinder in circular Couette flow or of the speed of the moving upper plate in plane Couette flow. Hence, in cessation, the classical no-slip solution holds if the corresponding wall speed is below the critical value. Otherwise, slip occurs only initially along both walls. Beyond a first critical time, slip along the fixed wall ceases, and beyond a second critical time slip ceases also along the initially moving wall. Beyond this second critical time no slip is observed and the decay of the velocity is faster. The velocity decays exponentially in all regimes and the decay is reduced with slip. The effects of slip and the slip yield stress are discussed. 相似文献
94.
Olga Kokkinaki Savas Georgiou 《Applied Physics A: Materials Science & Processing》2008,92(4):1013-1017
Matrix-Assisted-Pulsed-Laser-Evaporation (MAPLE) has emerged as a very promising technique for the deposition of polymers
and biopolymers in intact and functional form. However, our understanding of the mechanism of the procedure is still limited.
Here, we examine laser-induced (248 nm) desorption from condensed CHCl3 solid, which has been employed as a potential matrix in MAPLE. We find that the absorption of the condensed halocarbon increases
significantly with successive laser pulses, as a result of the formation and accumulation of strongly absorbing products.
This results in a significant increase of the ejection efficiency in the irradiation with successive laser pulses. Thus, in
studies employing multi-pulse irradiation protocols, the attained laser-induced temperatures are considerably higher than
what is estimated on the basis of the absorption coefficient of CHCl3. Thus, contrary to previous suggestions, ablation of CHCl3 frozen solid at 248 nm may be due to explosive boiling. A number of additional implications are also discussed. 相似文献
95.
Nikitas Georgiou Antigoni Cheilari Danai Karta Eleni Chontzopoulou Janez Plavec Demeter Tzeli Stamatia Vassiliou Thomas Mavromoustakos 《Molecules (Basel, Switzerland)》2022,27(14)
The structure assignment and conformational analysis of the thiosemicarbazones, DKI21 and DKI24, were performed through homonuclear and heteronuclear 2D Nuclear Magnetic Resonance (NMR) spectroscopy (2D-COSY, 2D-NOESY, 2D-ROESY, 2D-HSQC, and 2D-HMBC) and quantum mechanics (QM) calculations, using Functional Density Theory (DFT). In addition, utilizing a combination of 2D-NOESY and 2D-ROESY spectra an exo structure was established for both of the analogs. This experimental results were confirmed by theoretical mechanistic studies, as the lowest minima conformations derived through DFT calculations were compatible with the spatial correlations observed in the 2D-NOESY and 2D-ROESY spectra. Finally, molecular binding experiments were performed to detect the potential targets for DKI21 and DKI24, derived from SwissAdme. In silico molecular binding experiments showed favorable binding energy values for the most of the enzymes studied. The ADMET calculations, using the preADMET and pKCSm software, showed that the two molecules appear as possible drug leads. 相似文献
96.
Vasileios A Dimitriou Andreas C Georgiou Nikolas Tsantas 《The Journal of the Operational Research Society》2015,66(6):993-1006
The present paper employs the Multivariate Homogeneous Markov System (MHMS) in the context of Markov manpower planning modelling. The system is regulated by an embedded multivariate Markov process that allows us to distinguish employees’ mobility patterns that take place either within or among the existing divisions (departments) of an organization. The motivation behind this step arises from the generalization of univariate Markov manpower planning models in which the organization is considered a single (probably hierarchical) group and from the fact that departmental mobility is actually common in most realistic establishments. The first part of the paper presents the functional relations of the MHMS governing intra/inter-departmental transitions. Using these functional forms, we proceed by studying the system’s equilibrium behaviour. This asymptotic analysis reveals the inherent tendencies of the system to reach the limiting structures of specific forms and properties under conditions imposed in the long run. 相似文献
97.
98.
99.
The microwave spectrum of 4-pyridine carbaldehyde has been investigated in the region 8 to 40 GHz. Rotational transitions have been observed and assigned for the ground state and two excited states of the torsion mode. Analysis yields precise rotational constants (A = 5519.04 ± 0.08, B = 1559.17 ± 0.03, C = 1216.11 ± 0.02 MHz) which prove the molecule to be planar. Centrifugal distortion constants have also been obtained. Analysis of the observed 14N quadrupole fine structure yields the following quadrupole coupling constants (in MHz): χaa = ?4.67 ± 0.09; χbb = 1.19 ± 0.26; χcc = 3.48 ± 0.26. The electric field gradient about the nitrogen nucleus is thus similar to that of pyridine. 相似文献
100.
We consider the time-dependent shear flow of an Oldroyd-B fluid with slip along the fixed wall. Slip is allowed by means
of a generic slip equation predicting that the shear stress is a non-monotonic function of the velocity at the wall. The complete
one-dimensional stability analysis to one-dimensional disturbances is carried out and the corresponding neutral stability
diagrams are constructed. Asymptotic results for large values of the elasticity number and finite element calculations are
also presented. The instability regimes are within or coincide with the negative-slope regime of the slip equation. The numerical
calculations agree with the linear stability results when the size of the initial perturbation is small. Large perturbations
may destabilize a linearly stable steady state, leading to a periodic solution. The period and the amplitude of the periodic
solutions increase with elasticity.
Received: 19 June 1997 Accepted: 22 September 1997 相似文献