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101.
Dr. Baptiste Joalland Nuwandi M. Ariyasingha Hassan R. Younes Shiraz Nantogma Dr. Oleg G. Salnikov Dr. Nikita V. Chukanov Dr. Kirill V. Kovtunov Prof. Igor V. Koptyug Prof. Juri G. Gelovani Prof. Eduard Y. Chekmenev 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(8):2774-2781
Many MRI contrast agents formed with the parahydrogen-induced polarization (PHIP) technique exhibit biocompatible profiles. In the context of respiratory imaging with inhalable molecular contrast agents, the development of nonflammable contrast agents would nonetheless be highly beneficial for the biomedical translation of this sensitive, high-throughput and affordable hyperpolarization technique. To this end, we assess the hydrogenation kinetics, the polarization levels and the lifetimes of PHIP hyperpolarized products (acids, ethers and esters) at various degrees of fluorine substitution. The results highlight important trends as a function of molecular structure that are instrumental for the design of new, safe contrast agents for in vivo imaging applications of the PHIP technique, with an emphasis on the highly volatile group of ethers used as inhalable anesthetics. 相似文献
102.
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103.
104.
A review of normalization techniques in analytical atomic spectrometry with laser sampling: From single to multivariate correction 总被引:1,自引:0,他引:1
Nikita B. Zorov Alexander A. GorbatenkoTimur A. Labutin Andrey M. Popov 《Spectrochimica Acta Part B: Atomic Spectroscopy》2010
Despite many advantages of laser sampling in analytical atomic spectrometry, the signal intensity of these hyphenated methods suffers from the specific influences resulting from the laser ablation process of a sample. The problems that arise affect the accuracy and precision of analytical results. Different techniques of analytical signal normalization which improve figures-of-merit for atomic spectrometry with laser sampling are considered in this review. The characteristics and application of these approaches including the use of internal standards, single or several reference signals and multivariate correction of analytical signal are discussed. 相似文献
105.
106.
Orienting Effect of the Cage Addends: The Case of Nucleophilic Cyclopropanation of C2‐C70(CF3)8
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Dr. Marina G. Apenova Olesya O. Semivrazhskaya Eugenia V. Borkovskaya Nikita M. Belov Dr. Ilya N. Ioffe Dr. Vitaliy Yu. Markov Prof. Dr. Sergey I. Troyanov Dr. Natalia S. Lukonina Prof. Dr. Lev N. Sidorov Dr. Alexey A. Goryunkov 《化学:亚洲杂志》2015,10(6):1370-1378
C2‐C70(CF3)8 was found to be a very promising substrate in the Bingel and the Bingel–Hirsch reactions combining perfect regioselectivity with much higher reactivity compared to its analogs. The reactions with diethyl malonate yield a single isomer of the monoadduct C70(CF3)8[C(CO2Et)2] and a single C2‐symmetrical bisadduct C70(CF3)8[C(CO2Et)2]2. The Bingel–Hirsch variation is particularly interesting in that it additionally affords, in a similar regioselective manner, the unexpected alkylated derivatives C70(CF3)8[CH(CO2Et)2]H and C70(CF3)8[C(CO2Et)2][CH(CO2Et)2]H. The novel compounds have been isolated and structurally characterized by means of 1H and 19F NMR spectroscopy as well as single‐crystal X‐ray diffraction. The mechanistic and regiochemical aspects of the reaction are explained with the aid of DFT calculations. 相似文献
107.
Nikita Sidorov 《Journal of Number Theory》2009,129(4):741-754
Let q∈(1,2); it is known that each x∈[0,1/(q−1)] has an expansion of the form with an∈{0,1}. It was shown in [P. Erd?s, I. Joó, V. Komornik, Characterization of the unique expansions and related problems, Bull. Soc. Math. France 118 (1990) 377-390] that if , then each x∈(0,1/(q−1)) has a continuum of such expansions; however, if , then there exist infinitely many x having a unique expansion [P. Glendinning, N. Sidorov, Unique representations of real numbers in non-integer bases, Math. Res. Lett. 8 (2001) 535-543]. In the present paper we begin the study of parameters q for which there exists x having a fixed finite number m>1 of expansions in base q. In particular, we show that if q<q2=1.71…, then each x has either 1 or infinitely many expansions, i.e., there are no such q in . On the other hand, for each m>1 there exists γm>0 such that for any q∈(2−γm,2), there exists x which has exactly m expansions in base q. 相似文献
108.
Nikita A. Nekrasov 《Japanese Journal of Mathematics》2009,4(1):63-93
We discuss instanton partition functions in various spacetime dimensions. These partition functions capture some information
about the spectrum of the supersymmetric gauge theories and their low-energy dynamics. Some of these theories can be defined
microscopically only through string theory. Remarkably, they even know about the M-theory. Our conjectures include the identities
between the generalization of the MacMahon formula and the character of M-theory, compactified down to 0 + 1 dimension.
This article is based on the 5th Takagi Lectures that the author delivered at the University of Tokyo on October 4 and 5,
2008. 相似文献
109.
G3(MP2) and other model chemistry calculations indicate that stabilization energies of extensively conjugated allylic radicals H2(C=C)nCH2*, n = 1-4, increase monotonically as the number of repeating C=C units increase. In contrast, stabilization energies of the analogous propargylic radicals, H(C[triple bond]C)nCH2*, decrease beyond n = 2. Breaking up the number of contiguous conjugated C[triple bond]C units in conjugation with the odd electron enhances rather than diminishes stability. These results complement previous findings of significant differences in the stabilization of conjugated ground-state polyenes vs polyynes. 相似文献
110.
Nikita A. Karpenko 《Comptes Rendus Mathematique》2010,348(21-22):1151-1153
We prove the symplectic analogue of the isotropy theorem for orthogonal involutions. We apply (a modification of) a method due to J.-P. Tignol originally applied to prove the symplectic analogue of the hyperbolicity theorem for orthogonal involutions. 相似文献