全文获取类型
收费全文 | 242665篇 |
免费 | 2413篇 |
国内免费 | 871篇 |
专业分类
化学 | 130193篇 |
晶体学 | 3688篇 |
力学 | 9889篇 |
综合类 | 2篇 |
数学 | 27044篇 |
物理学 | 75133篇 |
出版年
2020年 | 1769篇 |
2019年 | 2036篇 |
2018年 | 2469篇 |
2017年 | 2401篇 |
2016年 | 3816篇 |
2015年 | 2589篇 |
2014年 | 3889篇 |
2013年 | 11145篇 |
2012年 | 8066篇 |
2011年 | 9987篇 |
2010年 | 6565篇 |
2009年 | 6459篇 |
2008年 | 8970篇 |
2007年 | 9123篇 |
2006年 | 8367篇 |
2005年 | 7827篇 |
2004年 | 6979篇 |
2003年 | 6199篇 |
2002年 | 6135篇 |
2001年 | 7197篇 |
2000年 | 5359篇 |
1999年 | 4215篇 |
1998年 | 3547篇 |
1997年 | 3575篇 |
1996年 | 3287篇 |
1995年 | 3128篇 |
1994年 | 2944篇 |
1993年 | 2999篇 |
1992年 | 3292篇 |
1991年 | 3327篇 |
1990年 | 3143篇 |
1989年 | 3098篇 |
1988年 | 3159篇 |
1987年 | 3029篇 |
1986年 | 2923篇 |
1985年 | 3985篇 |
1984年 | 4145篇 |
1983年 | 3399篇 |
1982年 | 3749篇 |
1981年 | 3645篇 |
1980年 | 3517篇 |
1979年 | 3551篇 |
1978年 | 3777篇 |
1977年 | 3606篇 |
1976年 | 3814篇 |
1975年 | 3387篇 |
1974年 | 3516篇 |
1973年 | 3819篇 |
1972年 | 2327篇 |
1971年 | 1786篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
131.
K. S. Trofimova V. G. Dronov N. S. Shaglaeva R. G. Sultangareev 《Russian Journal of Applied Chemistry》2008,81(4):730-731
Possibilities of utilization of by-products formed in manufacture of epichlorohydrin are considered. A promising way to utilize wastes from production of epichlorohydrin by synthesis of 2,3-dichloropropene from 1,2,3-trichloropropane is suggested. 相似文献
132.
M. R. McEwen J. P. Sephton P. H. G. Sharpe D. R. Shipley 《Radiation Physics and Chemistry》2003,68(6):1017-1022
A phantom composed of alanine dosimeter material has been constructed and depth–dose measurements made in a 10 MeV electron beam. The results have demonstrated the feasibility of using relative depth–dose measurements to determine stopping power ratios in materials of dosimetric interest. Experimental stopping power ratios for alanine dosimeter material and water agreed with the data of ICRU Report 37 within the uncertainty of the experiment (±1.2% at a 95% confidence level). 相似文献
133.
The mechanism of transition of a Bose gas to the superfluid state via thermal fluctuations under the condition of external cooling at a temperature above the transition point is considered. The probability of formation of such critical fluctuations (instantons) is calculated; it is found that this probability increases as the system approaches the transition temperature. It is shown that the evolution of an individual instanton is impossible without the formation of vortices in its superfluid part. 相似文献
134.
The results of investigations of the rheological characteristics and electrical resistance of the suspensions of carbon black in vaseline oil under the effects of shear and vibration were presented. The investigations are carried out on an original unit that allowed one to simultaneously subject the suspensions to shear deformation and orthogonal vibration. The electrical resistance was also measured in an ac pulsed low-voltage mode. Possible mechanisms of the suspension conductivity were considered depending on the regime of dynamic action. 相似文献
135.
136.
Hybrid numerical—experimental approach for investigation of dynamics of microcantilever relay system
V. Ostasevicius S. Tamulevicius A. Palevicius M. Ragulskis R. Palevicius V. Grigaliunas 《Optics and Lasers in Engineering》2005,43(1):199
The time average holography measurements of the vibrating microelectromechanical switch (MEMS) were performed in this study. Experimental measurement results exhibit good agreement with computer generated holographic interferogram analysis. The validation of experimental investigations versus numerical analysis provides the necessary background to analyze the dynamical characteristics of micromechanical systems in virtual numerical environments. Direct application of fringe counting techniques for reconstruction of motion from time average holograms cannot be straightforward if the analyzed micromechanical systems contain motion limiters. Modifications of a classical time average holographic technique enable qualitative analysis of MEMS and can be applied for investigation of dynamical properties of much broader classes of MEMS systems. 相似文献
137.
We consider the problem of determining the stress distributionin a finite rectangular elastic layer containing a Griffithcrack which is opened by internal shear stress acting alongthe length of the crack. The mode III crack is assumed to belocated in the middle plane of the rectangular layer. The followingtwo problems are considered: (A) the central crack is perpendicularto the two fixed lateral surfaces and parallel to the othertwo stress-free surfaces; (B) all the lateral surfaces of therectangular layer are clamped and the central crack is parallelto the two lateral surfaces. By using Fourier transformations,we reduce the solution of each problem to the solution of dualintegral equations with sine kernels and a weight function whichare solved exactly. Finally, we derive closed-form expressionsfor the stress intensity factor at the tip of the crack andthe numerical values for the stress intensity factor at theedges of the cracks are presented in the form of tables. 相似文献
138.
T. T. Vasil'eva V. A. Kochetkova V. I. Dostovalova B. V. Nelyubin R. Kh. Freidlina 《Russian Chemical Bulletin》1989,38(11):2346-2349
The radical telomerization of 3,3,3-trifluoropropene with bromoform and methylens bromide has been studied. The nature of the products with bromoform depends substantially on the method of initiation. In the presence of Fe(CO)5 + DMF, telomers of CHBr2(CH52CHCF3)nBr are formed, while with initiation with benzoyl peroxide other compounds are also formed that contain two, three, or four bromine atoms per molecule. To elucidate the formation of these products a reaction scheme is proposed that involves rearrangement of CHBr2CH2CH(CF3)CH3CHCF3 radicals to CBr2CH2CH(CF3)CH2CH2CF3 radicals.Deceased.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2558–2562, November, 1989. 相似文献
139.
Electrohydrodynamic instability in homeotropically oriented nematic samples of 4'-n-octyl-4-cyano-biphenyl and 4'n-alkyloxy-4-cyanobiphenyl, (n = 8.9) have been studied in an a.c. electric field. The domain patterns during the instability in these compounds in a very low frequency a.c. field are very similar to those in a d.c. field. The domain patterns observed at higher frequencies have been identified as 'maltese crosses' or 'crossed isogyres'. The electro-convective 'isotropic' flows near the electrode play an important role in the observed instability. 相似文献
140.
W M Niessen M A de Kraa E R Verheij P J Bergers G F La Vos U R Tjaden J van der Greef 《Rapid communications in mass spectrometry : RCM》1989,3(1):1-4
On-line sample pretreatment by means of the phase-system switching approach is an interesting technique for the analysis of aqueous samples, e.g., plasma, by means of supercritical-fluid chromatography. In order to analyse plasma samples the following analytical procedure is used. The plasma sample is injected on to a short precolumn, which is washed with water and subsequently dried with nitrogen. Next, the solutes are desorbed with the supercritical mobile phase, analysed with packed-column supercritical-fluid chromatography and detected with either a UV detector or a mass spectrometer, equipped with a moving-belt interface. The herbicide diuron is selected as a test compound to study the feasibility of this approach. Using a selective detector the procedure is sufficiently sensitive to detect diuron in plasma, but not appropriate to detect the diuron metabolites in a post-mortem plasma sample. These have been identified with liquid chromatography/mass spectrometry. The detection limit of diuron in plasma using the procedure described is about 30 ng/mL. 相似文献