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91.
The authors prove that in the space of nonsingular transformations of a Lebesgue probability space the type III1 ergodic transformations form a denseG
set with respect to the coarse topology. They also prove that for any locally compact second countable abelian groupH, and any ergodic type III transformationT, it is generic in the space ofH-valued cocycles for the integer action given byT that the skew product ofT with the cocycle is orbit equivalent toT. Similar results are given for ergodic measure-preserving transformations as well.Research supported in part by: Nat. Sci. and Eng. Res. Council #A7163 and # U0080 F.C.A.C. Quebec, NSF Grants # MCS-8102399 and # DMS-8418431. 相似文献
92.
A.C. and d.c. electrical conductivities, thermoelectric power and dielectric constant of copper vanadate (CuV2O6) have been measured in the temperature range 300–1000 K in order to discuss the electrical conduction in the compound. The extrinsic conduction, which takes place below 500 K, has been explained by small polaron hopping mechanism while intrinsic conduction, which takes place above 500 K, has been explained by large polaron band mechanism in view of the values of activation energy and charge carrier mobility in the temperature ranges 300–500 K and 500–1000 K. 相似文献
93.
94.
Beryllium can be precipitated from homogeneous solution as a dense and easily filterable precipitate by the hydrolysis of urea, in the presence of sulphate. The method has been applied to the gravimetric determination of beryllium as oxide. The nature of the precipitate thus obtained has been examined by thermogravimetric, infrared, photomicrographic and X-ray methods. 相似文献
95.
Y. Shi L. Sun J. E. S. Venart R. C. Prasad 《Journal of Thermal Analysis and Calorimetry》2006,86(3):585-590
The transient hot-wire technique is widely used for absolute measurements
of the thermal conductivity and thermal diffusivity of fluids. It is well
established that fluid radiation effects significantly influence these measurements,
especially those for the thermal diffusivity. Corrections for radiation effects
are based on the models developed and deviations of the measured data from
the ideal line source model. In this paper, the effect of fluid radiation
on the measurements of the thermal conductivity of n-pentane
is presented. For comparison, the influence of thermal radiation effect on
measurement of transparent fluids, such as argon is also shown. The difference
between the influence of natural convection and thermal radiation is also
demonstrated. 相似文献
96.
Selenocystine ([Sec]2) and aryl-substituted selenocysteine (Sec) derivatives are synthesized, starting from commercially available amino acid l-serine. These compounds are characterized by a number of analytical techniques such as NMR (1H, 13C and 77Se) and TOF mass spectroscopy. This study reveals that the introduction of amino/imino substituents capable of interacting with selenium may stabilize the Sec derivatives. This study further suggests that the oxidation-elimination reactions in Sec derivatives could be used for the generation of biologically active selenols having internally stabilizing substituents. 相似文献
97.
The use of 1,2-naphthoquinone-2-semicarbazone-4-sulphonic acid and 1,2-naphtho-quinone-2-thiosemicarbazone-4-sulphoic acid as indicators in the titrimetric estimation of phosphate, molybdate, tungstate and sulphate with lead has been examined. The precision, accuracy and applicability of the methods have been evaluated. 相似文献
98.
[reaction: see text] Gamma,delta-unsaturated beta-diketones have been prepared by the acylation of ketones with N-acylbenzotriazoles of various aliphatic and aromatic alpha,beta-unsaturated carboxylic acids. 相似文献
99.
M. Durga Prasad 《Theoretical chemistry accounts》1994,88(5):383-388
Summary Finite order expressions are derived for expectation values and transition matrix elements within the framework of the coupled cluster method. 相似文献
100.
Two bis(bipyridine) polymeric metal nitrate complexes
with 4,4’-bipyridine of simple formula like [M(bipy)2](NO3)2⋅xH2O (where M=Co, Ni and Cu; x=4, 2 and 0, respectively) have been prepared and
characterized. Their thermal decomposition has been undertaken using simultaneous
TG-DTG-DTA and DSC in nitrogen atmosphere and non-isothermal TG in air atmosphere.
Isothermal TG has been performed at decomposition temperature range of the
complexes to evaluate the kinetics of decomposition by applying model-fitting
as well as isoconversional method. Possible mechanistic pathways have also
been proposed for the thermolysis. Ignition delay measurements have been carried
out to investigate the response of these complexes under the condition of
rapid heating. 相似文献