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排序方式: 共有871条查询结果,搜索用时 15 毫秒
91.
Mohammad Shahidul Islam Abdullah Saleh Alammari Assem Barakat Saeed Alshahrani Matti Haukka Abdullah Mohammed Al-Majid 《Molecules (Basel, Switzerland)》2021,26(23)
Five new C2-symmetric chiral ligands of 2,5-bis(imidazolinyl)thiophene (L1–L3) and 2,5-bis(oxazolinyl)thiophene (L4 and L5) were synthesized from thiophene-2,5-dicarboxylic acid (1) with enantiopure amino alcohols (4a–c) in excellent optical purity and chemical yield. The utility of these new chiral ligands for Friedel–Crafts asymmetric alkylation was explored. Subsequently, the optimized tridentate ligand L5 and Cu(OTf)2 catalyst (15 mol%) in toluene for 48 h promoted Friedel–Crafts asymmetric alkylation in moderate to good yields (up to 76%) and with good enantioselectivity (up to 81% ee). The bis(oxazolinyl)thiophene ligands were more potent than bis(imidazolinyl)thiophene analogues for the asymmetric induction of the Friedel–Crafts asymmetric alkylation. 相似文献
92.
In this research paper, we examine a novel method called the Natural Decomposition Method (NDM). We use the NDM to obtain exact solutions for three different types of nonlinear ordinary differential equations (NLODEs). The NDM is based on the Natural transform method (NTM) and the Adomian decomposition method (ADM). By using the new method, we successfully handle some class of nonlinear ordinary differential equations in a simple and elegant way. The proposed method gives exact solutions in the form of a rapid convergence series. Hence, the Natural Decomposition Method (NDM) is an excellent mathematical tool for solving linear and nonlinear differential equation. One can conclude that the NDM is efficient and easy to use. 相似文献
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96.
Saleh Z. M. Nasser H. Özkol E. Günöven M. Abak K. Canli S. Bek A. Turan R. 《Journal of nanoparticle research》2015,17(10):1-12
Journal of Nanoparticle Research - Plasmonic interfaces consisting of silver nanoparticles of different sizes (50–100&;nbsp;nm) have been processed by the self-assembled dewetting... 相似文献
97.
Saleh Al-Omari Nawash Alghezawi Mousa Al-Noaimi Akram Aqili Ibrahim F. Al-Hamarneh Mohammad Marashdeh 《Journal of fluorescence》2014,24(3):835-839
The shift of the Q-band of sodium zinc(II)-2,9,16,23-phthalocyanine tetracarboxylate (ZnPc(COONa)4) to about 800 nm is attributed to the influence of the electron-donating property of the carboxylate groups substituted in the β–position. ZnPc(COONa)4 which was found to have a symmetry of D 2h characterized by a splitting of the Q transition. This splitting was interpreted by the formation of dianionic symmetric ZnPc(COONa)4 resulting from the dissociation of the pyrrole protons as well as the possibility of Na+ dissolution of ZnPc(COONa)4 in the aqueous solution of NaOH. 相似文献
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99.
The motivation behind the present work is to synthesize some nonionic surfactants containing heterocyclic nucleus with intermediate fatty compounds for improving their surfactants properties. 2‐Cyano‐N‐octadecylacetamide was utilized as key intermediate for the synthesis of some new thiazole, pyrazole, oxazole, pyrimidine, 1,3‐dithiolane, thiophene, coumarin, oxazine and pyridazine derivatives. The newly synthesized compounds undergo propoxylation using propylene oxide to afford nonionic surface active agents. The antimicrobial and surface activities were evaluated and characterized through investigations of their spreading behavior in monolayer on water. 相似文献
100.
Saleh Mohammed Mokbel E. N. Kolosov I. I. Mikhalenko 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2016,90(6):1289-1292
A comparative study of oxidation of phenol, 3-chlorophenol, 4-chlorophenol, and 2,4-dichlorophenol on Pt/Ti and Ce,Pt/Ti electrocatalysts is performed via cyclic voltammetry. It is shown that the surface morphology and roughness of the anode do not change after modification with cerium. The formal kinetic orders of electrooxidation of all compounds are found to be less than one. It is shown that the β temperature coefficients of the rate of oxidation of chlorophenols grow by 10 to 50% when the Ce,Pt/Ti anode is used at a substrate concentration of 1 mM. A tenfold increase in concentration reduces the effect of cerium additive, except for 3-chlorophenol: the latter exhibits a 250% increase in the β value, compared to the Pt/Ti anode. 相似文献