1,4-benzothiazine derivatives from 2-aminobenzenethiol and hydrazonoyl halides

2-Aminobenzenethiol was condensed with alkyl α-chlorophenylhydrazonoglyoxylates yielding alkyl 2-(2-aminophenylthio)-2-arylhydrazonoglyoxylates which were cyclized to the corresponding 2-arylhydrazono-2,3-dihydro-4H-1,4-benzothiazin-3-ones. Starting from α-chloro-α-arylhydrazonoacetones the corresponding 2-arylhydrazono-3-methylbenzo-1,4-benzothiazines were formed.     

EPR and ab-initio study on the solid state radiolysis of aliphatic and aromatic polyesters

Low temperature matrix EPR spectroscopy was employed to investigate the free radical intermediates in the solid state radiolysis of poly(ethylene terephthalate) (PET), poly(butylene terephthalate) (PBT), poly(ethylene naphthalate) (PEN), poly(1,4-cyclohexanedimethylene terephthalate-co-ethylene terephthalate) (PCT-co-ET) and poly(ethylene adipate) (PEA). With PEA the species identified is consistent with the formation of carbon centred radicals stemming from electron capture, C–O scissions and H abstractions, the most abundant species at room temperature being the -ester radical, –CH₂–CH–COO–. The radiolysis of PEN is characterized by the predominance of radicals arising from the aromatic section, the preferred reaction being the H atom addition at a position adjacent to the ester unit, leading to the formation of cyclohexadienyl type radicals. In the copolymer, PET and PBT, the role played by the aliphatic and aromatic sections with respect to radical forming processes is of comparable importance. The cyclohexadienyl radicals arising from these latter polymers are reckoned with the prominent H addition at the sites adjacent to the esters groups which are also statistically favoured. The reactivity distribution in the aromatic rings with respect to the formation of cyclohexadienyls was analyzed in greater detail by comparing the experimental results with DFT B3LYP M.O. calculations. The DFT method has also been employed for assessing the EPR properties of the cyclohexadienyl and ion-radicals from PEN and PET models.     

Cohomologies of locally conformally symplectic manifolds and solvmanifolds

We study the Morse–Novikov cohomology and its almost-symplectic counterpart on manifolds admitting locally conformally symplectic structures. More precisely, we introduce lcs cohomologies and we study elliptic Hodge theory, dualities, Hard Lefschetz condition. We consider solvmanifolds and Oeljeklaus–Toma manifolds. In particular, we prove that Oeljeklaus–Toma manifolds with precisely one complex place, and under an additional arithmetic condition, satisfy the Mostow property. This holds in particular for the Inoue surface of type \(S^0\).