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61.
Paola Antoniotti Stefano Borocci Nicoletta Bronzolino Felice Grandinetti 《Chemphyschem》2004,5(9):1345-1351
The structure and stability of various HCN2+ isomeric structures have been investigated at the complete active space SCF (CASSCF) and multireference-configuration interaction [MR-Cl-SD(Q)] levels of theory with the 6-31G(d) and 6-311G(d,p) basis sets. The investigated species include the singlet (S) and triplet (T) open-chain H-N-C-N+ ions 1S, 1S', and 1T, the open-chain H-C-N-N+ ions 2S, 2S', and 2T, the HC-N2+ cyclic structures 3S and 3T, and the HN-CN+ cyclic structures 4S and 4T. All these species have been identified as true energy minima on the CASSCF(8,7)/6-31G(d) potential energy surface, and their optimised geometries, refined at the CASSCF(8,8)/6-31G(d) level of theory, have been used to perform single point calculations at the [MR-Cl-SD(Q]/6-311G(d,p) computational level. The most stable structure was the H-N-C-N+ ion 1T, whose absolute enthalpy of formation at 298.15 K has been estimated as 333.9 +/- 2 kcalmol(-1) using the Gaussian-3 (G3) procedure. The two species closest in energy to 1T are the triplet H-C-N-N+ ion 2T and the singlet diazirinyl cation 3S, whose G3 enthalpies of formation at 298.15 K are 343.5 +/- 2 and 340.6 +/- 2 kcalmol(-1), respectively. Finally, we have discussed the implications of our calculations for the detailed structure of the HCN2+ ions formed in the reaction between N3+ and HCN, experimentally observed by flowing after-glow-selected ion flow/drift tube mass spectrometry and possibly occurring in Titan's atmosphere. 相似文献
62.
Federica Rizzi Rachele Castaldo Tiziana Latronico Pierluigi Lasala Gennaro Gentile Marino Lavorgna Marinella Striccoli Angela Agostiano Roberto Comparelli Nicoletta Depalo Maria Lucia Curri Elisabetta Fanizza 《Molecules (Basel, Switzerland)》2021,26(14)
Mesoporous silica nanostructures (MSNs) attract high interest due to their unique and tunable physical chemical features, including high specific surface area and large pore volume, that hold a great potential in a variety of fields, i.e., adsorption, catalysis, and biomedicine. An essential feature for biomedical application of MSNs is limiting MSN size in the sub-micrometer regime to control uptake and cell viability. However, careful size tuning in such a regime remains still challenging. We aim to tackling this issue by developing two synthetic procedures for MSN size modulation, performed in homogenous aqueous/ethanol solution or two-phase aqueous/ethyl acetate system. Both approaches make use of tetraethyl orthosilicate as precursor, in the presence of cetyltrimethylammonium bromide, as structure-directing agent, and NaOH, as base-catalyst. NaOH catalyzed syntheses usually require high temperature (>80 °C) and large reaction medium volume to trigger MSN formation and limit aggregation. Here, a successful modulation of MSNs size from 40 up to 150 nm is demonstrated to be achieved by purposely balancing synthesis conditions, being able, in addition, to keep reaction temperature not higher than 50 °C (30 °C and 50 °C, respectively) and reaction mixture volume low. Through a comprehensive and in-depth systematic morphological and structural investigation, the mechanism and kinetics that sustain the control of MSNs size in such low dimensional regime are defined, highlighting that modulation of size and pores of the structures are mainly mediated by base concentration, reaction time and temperature and ageing, for the homogenous phase approach, and by temperature for the two-phase synthesis. Finally, an in vitro study is performed on bEnd.3 cells to investigate on the cytotoxicity of the MNSs. 相似文献
63.
Nematic liquid crystal droplets dispersed in a thermoplastic matrix with a built-in d.c. electric field exhibit a quasi-linear response to an electric field. In this work we show a device characterized by a large light modulation. The device can store fields up to several V μm-1 and operates well from d.c. to several kHz. In addition, we found that the experimental results are in agreement with a simple theoretical model for light scattering by a dispersion of liquid crystal droplets. This device allows us to overcome possible drawbacks, due to a reduced light modulation, in applications where polarity detection is required. 相似文献
64.
Jean M. J. Tronchet Guido Zosimo-landolfo Nicoletta Bizzozero Daniel Cabrini Ford Habashi Evelyne Jean 《Journal of carbohydrate chemistry》2013,32(1):169-186
Abstract Reduction of sugar aldoximes gave in good yield the corresponding terminal deoxy hydroxyamino sugars. These compounds were found to be reasonably stable (they could be kept for some weeks at 4° C). On standing in the air, these compounds in solution were spontaneously oxidized to the corresponding nitroxide free radicals whose ESR spectra gave useful structural information. 相似文献
65.
Jean M. J. Tronchet Nicoletta Bizzozero Michel Geoffroy 《Journal of carbohydrate chemistry》2013,32(5):813-817
Abstract Deoxy-N-hydroxyaminosugars constitute a novel family of sugars. The interest in them is mainly due to their close structural similarity to natural sugars, coupled, with their easy oxidation to nitroxide free radicals, enabling their study by ESR spectroscopy.1 From the point of view of their chemical reactivity, the hydroxyamino group is an ambident nucleophile possessing complex orbital and topographical factors, which direct its reactivity to either of its heteroatoms. 相似文献
66.
Evidence for PSII donor-side damage and photoinhibition induced by cadmium treatment on rice (Oryza sativa L.) 总被引:2,自引:0,他引:2
Pagliano C Raviolo M Dalla Vecchia F Gabbrielli R Gonnelli C Rascio N Barbato R La Rocca N 《Journal of photochemistry and photobiology. B, Biology》2006,84(1):70-78
The effects of cadmium (from 7.5 to 75 microM) on chloroplasts of rice were studied at the structural and biochemical level. Loss of pigments, reduction of thylakoids and decrease in oxygen evolution and Fv/Fm ratio occur in leaves following cadmium treatment. However, the amount of photosystem II reaction center proteins and that of its light harvesting complex is not affected, indicating that cadmium does not adversely influence the structural organization of this photosystem. In thylakoids isolated from cadmium-treated plants a loss in the capability to reduce 2,6-dichlorophenolindophenol is observed, which is partially restored if diphenylcarbazide is used as an electron donor, indicating that cadmium affects water splitting activity. In thylakoids isolated from control plants and treated with cadmium, diphenylcarbazide preserves most of the photosystem II activity lost after incubation with cadmium; most of the S(2) multiline electron paramagnetic resonance signal from the manganese cluster is lost, whereas the TyrD(+) and other signals are retained. Light-induced photosystem II damage, in vitro, is promoted by Cd-treatment as deduced from the mobility shift of the D1 protein observed by immunoblot. 相似文献
67.
Depalo N Comparelli R Striccoli M Curri ML Fini P Giotta L Agostiano A 《The journal of physical chemistry. B》2006,110(35):17388-17399
Different types of cyclodextrins (CDs) have been tested as mediators for the water phase transfer of organic-capped CdS nanocrystals (NCs), and alphaCD has been demonstrated to be the most effective system. The formation of a complex based on alphaCDs and colloidal NCs has been considered to be responsible for the phase transfer process and extensively investigated by optical, structural, and calorimetric measurements, as a function of the experimental parameters (pH and NC and CD concentration). A mechanism for the complexation phenomena has been suggested. The fabrication of 2/3 D supramolecular architectures has been proposed according to two different strategies. First, a layer-by-layer procedure has been used to obtain multilayered structures where polyelectrolyte layers have been intercalated with negatively charged alphaCD-CdS NC complexes by exploiting electrostatic interaction between polyelectrolyte and cyclodextrin OH groups. Second, a monolayer of CdS NCs has been deposited onto a self-assembled monolayer of sulfated CDs, thus combining the use of an electrostatic-force-based approach and host-guest chemistry. The important role played by host-guest interactions has then been revealed. 相似文献
68.
Abbate S Barlati S Colombi M Fornili SL Francescato P Gangemi F Lebon F Longhi G Manitto P Recca T Speranza G Zoppi N 《Physical chemistry chemical physics : PCCP》2006,8(40):4668-4677
Circular dichroism (CD), and NMR spectra have been recorded and molecular dynamics (MD) simulations have been performed in water and water-trifluoroethanol (TFE) mixed solvent for a synthetic biologically active 13-amino-acid fragment of human fibronectin and two related peptides. The CD results are interpreted on the basis of statistical analyses of MD trajectories and of ensuing calculations of CD spectra based on Schellman's matrix method. It is observed that the peptide conformation is quite variable in water and loses its mobility with the addition of TFE. (1)H-NOE data were found to be consistent with the most abundant calculated conformation. 相似文献
69.
Fanizza E Altomare M Di Mauro AE Del Sole T Corricelli M Depalo N Comparelli R Agostiano A Striccoli M Curri ML 《Langmuir : the ACS journal of surfaces and colloids》2012,28(14):5964-5974
The fabrication of uniform and patterned nanocrystal (NC) assemblies has been investigated by exploiting the possibility of carefully tailoring colloidal NC surface chemistry and the ability of polyelectrolyte (PE) to functionalize substrates through an electrostatic layer-by-layer (LbL) strategy. Appropriate deposition conditions, substrate functionalization, and post-preparative treatments were selected to tailor the substrate surface chemistry to effectively direct the homogeneous electrostatic-induced assembly of NCs. Water-dispersible luminescent NCs, namely, (CdSe)ZnS and CdS, were differently functionalized by (1) ligand-exchange reaction, (2) growth of a hydrophilic silica shell, and (3) formation of a hydrophilic inclusion complex, thus providing functional NCs stable in a defined pH range. The electrostatically charged functional NCs represent a comprehensive selection of examples of surface-functionalized NCs, which enables the systematic investigation of experimental parameters in NC assembly processes carried out by combining LbL procedures with microcontact printing and also exploiting NC emission, relevant for potential applications, as a prompt and effective probe for evaluating assembly quality. Thus, an ample showcase of combinations has been investigated, and the spectroscopic and morphological features of the resulting NC-based structures have been discussed. 相似文献
70.
Giovanni De Filpo Marialuigia MacChione Fiore P. Nicoletta Daniela Cupelli Roberta Cassano Giuseppe Chidichimo 《Liquid crystals》2013,40(8):1025-1029
In this work we present a new technique for obtaining large diffraction gratings (some cm) by means of a simple filling of cells having a planar treatment of their inner surfaces. A homogeneous mixture, composed of a cholesteric liquid crystal and a nematic liquid crystal monomer, was used. During the filling process, the flow induces a phase separation between the cholesteric liquid crystal and the liquid crystal monomer and, at the same time, the latter is oriented planar to the surfaces of the cell. Phase separation produces alternate arrays constituted by the cholesteric liquid crystal and the nematic liquid crystal monomer. Successive UV polymerization of these films yields a permanent grating. We have investigated the transmitted and first order diffracted beam efficiency for films obtained at different temperatures. The morphology of the films was studied by using an optical microscope equipped with crossed polarizers and by electron microscopy in order to control the shape of the arrays and the alignment of the oriented polymer. 相似文献