The modulation of auditory novelty processing by working memory load in school age children and adults: a combined behavioral and event-related potential study

Background  

We investigated the processing of task-irrelevant and unexpected novel sounds and its modulation by working-memory load in children aged 9-10 and in adults. Environmental sounds (novels) were embedded amongst frequently presented standard sounds in an auditory-visual distraction paradigm. Each sound was followed by a visual target. In two conditions, participants evaluated the position of a visual stimulus (0-back, low load) or compared the position of the current stimulus with the one two trials before (2-back, high load). Processing of novel sounds were measured with reaction times, hit rates and the auditory event-related brain potentials (ERPs) Mismatch Negativity (MMN), P3a, Reorienting Negativity (RON) and visual P3b.     

Low Band Gap Donor‐Acceptor Conjugated Polymer Nanoparticles and their NIR‐mediated Thermal Ablation of Cancer Cells

Low band gap D‐A conjugated PNs consisting of 2‐ethylhexyl cyclopentadithiophene co‐polymerized with 2,1,3‐benzothiadiazole (for nano‐PCPDTBT) or 2,1,3‐benzoselenadiazole (for nano‐PCPDTBSe) have been developed. The PNs are stable in aqueous media and showed no significant toxicity up to 1 mg · mL^?1. Upon exposure to 808 nm light, the PNs generated temperatures above 50 °C. Photothermal ablation studies of the PNs with RKO and HCT116 colorectal cancer cells were performed. At concentrations above 100 µg · mL^?1 for nano‐PCPDTBSe, cell viability was less than 20%, while at concentrations above 62 µg · mL^?1 for nano‐PCPDTBT, cell viability was less than 10%. The results of this work demonstrate that low band gap D‐A conjugated polymers 1) can be formed into nanoparticles that are stable in aqueous media; 2) are non‐toxic until stimulated by IR light and 3) have a high photothermal efficiency.

     

Random Block Copolymers via Segment Interchange Olefin Metathesis

Polycarbonate/polyethylene random block copolymers (RBCs) have been produced using olefin metathesis catalysis in a process termed segment interchange metathesis. An olefin metathesis catalyst tolerant of polar functionality was added to reagent polycarbonate and polyethylene polymers which contained internal unsaturated carbon–carbon bonds. Subsequent metathesis occurred, segmenting the reagent polymers, resulting in RBCs. The block copolymers self-assembled into microphase structures which persisted into the melt state as determined by small angle X-ray scattering (SAXS).

     

Flow boiling heat transfer and pressure drop of R-134a in a mini tube: an experimental investigation

This paper presents the results of an experimental study carried out with R-134a during flow boiling in a horizontal tube of 2.6 mm ID. The experimental tests included (i) heat fluxes in the range from 10 to 100 kW/m², (ii) the refrigerant mass velocities set to the discrete values in the range of 240-930 kg/(m² s) and (iii) saturation temperature of 12 and 22 °C. The study analyzed the heat transfer, through the local heat transfer coefficient along of flow, and pressure drop, under the variation of these different parameters. It was possible to observe the significant influence of heat flux in the heat transfer coefficient and mass velocity in the pressure drop, besides the effects of saturation temperature. In the low quality region, it was possible to observe a significant influence of heat flux on the heat transfer coefficient. In the high vapor quality region, for high mass velocities, this influence tended to vanish, and the coefficient decreased. The influence of mass velocity in the heat transfer coefficient was detected in most tests for a threshold value of vapor quality, which was higher as the heat flux increased. For higher heat flux the heat transfer coefficient was nearly independent of mass velocity. The frictional pressure drop increased with the increase in vapor quality and mass velocity. Predictive models for heat transfer coefficient in mini channels were evaluated and the calculated coefficient agreed well with measured data within a range 35% for saturation temperature of 22 °C. These results extend the ranges of heat fluxes and mass velocities beyond values available in literature, and add a substantial contribution to the comprehension of boiling heat transfer phenomena inside mini channels.     

Highly ordered metal oxide nanopatterns prepared by template-assisted chemical solution deposition

TiO₂, Al₂O₃, and ZrO₂ patterns composed of ordered nano motifs of various morphologies (i.e. perforations (craters), rings, canyons, wires, dots, or channels) with typical lateral dimensions of less than 40 nm and thickness below 15 nm are presented. Simple chemical solution deposition (CSD) of molecular inorganic precursors and commercial block copolymers was used to create patterns on several substrate surfaces (bare, hydrophobized or gold covered silicon wafers and ITO). Self-assembly during evaporation and subsequent stabilization at 500 °C leads to the various nanostructures. Compared to other techniques for surface nano patterning, the present method has the advantage of being cheap, reproducible and easy to scale up and does not require specialized equipment. The type, dimension, and organization of these motifs were assessed by AFM, FE-SEM, spectroscopic ellipsometry, and GI-SAXS and are shown to depend on the conditions of preparation. Usage as model surfaces for modelling of wetting properties and as nanoelectrode arrays were investigated.     

The periodic risk model with investment

We consider a periodic risk model with the possibility of investing into a risky asset, given by a geometrical Brownian motion. The aim is to maximize the adjustment coefficient of the risk process. It is shown that the optimal investment strategy only depends on the averaged data of the model and is constant over time. Thus maximizing the adjustment coefficient is a very weak optimization criterion.     

Mother and Child Emotions during Mathematics Homework

Mathematics is often thought of as a purely intellectual and unemotional activity. Recently, researchers have begun to question the validity of this approach, arguing that emotions and cognition are intertwined. The emotions expressed during mathematics work may be linked to mathematics achievement. We used behavioral measures to identify the emotions expressed by U.S. mothers and their 11-year-old children while solving pre-algebra tasks in the home. The most notable positive emotions displayed by mothers and children included positive interest, affection, joy, and pride, whereas the most notable negative emotions expressed included tension, frustration, and distress. Reflecting the social aspects of doing homework together, mothers' and children's emotions were highly correlated. Independent of pre-existing differences in knowledge, children's emotions were associated with their performance on a mathematics post-test: tension was linked to poorer performance while positive interest, humor, and pride were linked to better performance. We found no evidence of gender differences in the emotions while working the tasks, although boys responded with more tension following an incorrect solution than did girls.     

Can international environmental cooperation be bought: Comment

Fuentes-Albero and Rubio (2010) analytically examine the effects of the countries’ heterogeneity on the international environmental cooperation. They consider two types of countries having different abatement costs in one case and different environmental damages in another case. Furthermore it is analyzed whether a self-financed transfer system can diminish these heterogeneity effects. The paper shows for both scenarios of asymmetry and no transfers that the maximum level of cooperation consists of three countries of the same type. For the case of heterogeneity in environmental damages, Fuentes-Albero and Rubio conclude that an agreement between one type 1 and one type 2 country is also self-enforcing given that the differences in the damages are not very large. In this comment, the derivation of the last mentioned result is shown to be incorrect by proving that this coalition is not self-enforcing.