全文获取类型
收费全文 | 1845篇 |
免费 | 73篇 |
国内免费 | 11篇 |
专业分类
化学 | 1196篇 |
晶体学 | 8篇 |
力学 | 84篇 |
数学 | 308篇 |
物理学 | 333篇 |
出版年
2023年 | 13篇 |
2022年 | 33篇 |
2021年 | 48篇 |
2020年 | 35篇 |
2019年 | 36篇 |
2018年 | 26篇 |
2017年 | 20篇 |
2016年 | 73篇 |
2015年 | 55篇 |
2014年 | 82篇 |
2013年 | 107篇 |
2012年 | 130篇 |
2011年 | 147篇 |
2010年 | 86篇 |
2009年 | 67篇 |
2008年 | 121篇 |
2007年 | 112篇 |
2006年 | 110篇 |
2005年 | 114篇 |
2004年 | 91篇 |
2003年 | 79篇 |
2002年 | 49篇 |
2001年 | 23篇 |
2000年 | 17篇 |
1999年 | 17篇 |
1998年 | 14篇 |
1997年 | 18篇 |
1996年 | 26篇 |
1995年 | 16篇 |
1994年 | 20篇 |
1993年 | 11篇 |
1992年 | 9篇 |
1991年 | 9篇 |
1990年 | 12篇 |
1989年 | 11篇 |
1988年 | 6篇 |
1987年 | 5篇 |
1985年 | 6篇 |
1984年 | 9篇 |
1983年 | 9篇 |
1982年 | 7篇 |
1981年 | 4篇 |
1980年 | 3篇 |
1978年 | 6篇 |
1977年 | 6篇 |
1976年 | 3篇 |
1975年 | 5篇 |
1974年 | 3篇 |
1973年 | 5篇 |
1919年 | 2篇 |
排序方式: 共有1929条查询结果,搜索用时 15 毫秒
11.
L. Sajo-Bohus M. C. Scott E. D. Greaves L. J. Somervaille S. Green T. Avila F. Loaiza L. Foglietta 《Journal of Radioanalytical and Nuclear Chemistry》2004,259(2):251-255
Gamma-ray induced X-ray emission (GIXE) technique for elemental lead in-vivo tibial measurement using a large volume hyper
pure germanium detector is presented with the most convenient source-sample-detector geometry. The system operates advantageously
when several parameters are considered for a lower dead time operation. The detection limit (DL) is better that 3.5 μg/g of
Ca. Results of in-vivo average tibial lead concentration for some of the monitored groups are: control 7 μg of lead per g
of Ca; gasoline filling attendants 6 μg/g of Ca; custom office workers near the DL; industrial workers range from DL up to
84±3 μg/g of Ca, suggesting that lead accumulation in the bone does not represent a major health risk
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
12.
We discuss possible experiments which can exploit recently-developed techniques to accumulate, store, and manipulate low-energy positrons to measure the parameters associated with positron annihilation radiation from media of astrophysical interest. Media discussed include collections of dust grains, partially ionized gases, He, H2, and other molecular gases and gas mixtures, including polycyclic aromatic hydrocarbon (PAH) molecules relevant to the interstellar medium. 相似文献
13.
This paper outlines the results of a study undertaken to investigate the nature of Community Operational Research (COR). The objective was to contact the people involved in COR through a series of personal interviews and a questionnaire survey, in order to clarify many of the issues that have emerged within the profession relating to the practice of OR within the community and voluntary sector. A total of 20 individuals were successfully contacted, and they have been responsible for at least two-thirds of the projects in the COR area. 相似文献
14.
S. De Nicola A. E. Kaplan S. Martellucci P. Mormile G. Pierattini J. Quartieri 《Applied physics. B, Lasers and optics》1989,49(5):441-444
We have observed a hysteretic (bistable) reflection of a Gaussian laser beam at the interface between glass and a liquid solution of polystyrene microspheres as nonlinear medium with both branches of the hysteretic curve being stable, in contrast to the results of previous experiments. 相似文献
15.
16.
We prove partial regularity results for local minimisers of
相似文献
17.
Isomer-selective infrared photodissociation (IRPD) spectra are obtained for the first time for protonated polyfunctional aromatic molecules isolated in the gas phase. IRPD spectra of the oxonium and fluoronium isomers of protonated para-fluorophenol (C6H6FO+) were separately obtained by monitoring resonant photo-induced H2O and HF loss, respectively. Analysis of the F-H, O-H, and C-H stretch wave numbers provides valuable spectroscopic information on the chemical properties of these reactive intermediates, in particular on the substitution effects of functional groups. 相似文献
18.
Mazzaglia A Angelini N Lombardo D Micali N Patané S Villari V Scolaro LM 《The journal of physical chemistry. B》2005,109(15):7258-7265
The interaction between the anionic 5,10,15,20-tetrakis(4-sulfonatophenyl)-21H,23H-porphyrin (TPPS) and cationic vesicles formed by heptakis(2-omega-amino-O-oligo(ethylene oxide)-6-hexylthio)-beta-cyclodextrin (SC6CDNH2) has been investigated in detail through a combination of elastic light scattering (ELS), quasi-elastic light scattering (QELS), zeta potential measurements, and time-resolved fluorescence anisotropy. ELS experiments provided the first structural characterization of these cationic vesicles both in the absence and in the presence of TPPS porphyrin, modeling the system as a spherical particle described by a single thin shell form factor. The structure of mixed hetero-aggregates is modulated by charge and size of the two components as function of different porphyrin/cyclodextrin (CD) molar ratios. At the limiting molar ratio studied, the absolute value of zeta potential (/zeta/ = 12.5 mV) seems to be a reference value for the formation of stable colloidal CD vesicular aggregates at thermodynamic equilibrium. New insights on the structure of these heterotopic colloids have been obtained by analysis of rotational correlation times at different molar ratios exploiting time-resolved fluorescence anisotropy experiments. At high porphyrin loads, the anisotropy decays behave as monoexponentials and the rotational correlation times (1-2 ns) together with the r(0) values close to zero suggest the presence of small amounts of TPPS embedded in a hydrophobic environment either in monomeric or in aggregated form. At the lower porphyrin/CD molar ratios, the anisotropy decays exhibit a double-exponential behavior showing a predominant component with a slow rotational correlation time (20-25 ns) and limiting anisotropy values of approximately 0.15. This component has been assigned to molecules that are more stabilized onto the CD vesicles, that is, porphyrins embedded into the oligo-ethylene "wall" of the CD vesicles. Scanning near-field optical microscopy of the samples evaporated on glass surfaces gave further insights on the morphology and optical properties of these systems, confirming the embedding of TPPS on the vesicles and evidencing the role of the solvent. 相似文献
19.
King NC Dickinson C Zhou W Bruce DW 《Dalton transactions (Cambridge, England : 2003)》2005,(6):1027-1032
Mesoporous silicates are prepared by templating on the hexagonal (H1) mesophase of surfactant bipyridine complexes of ruthenium(II) using a true liquid-crystal templating approach. On calcination, the surfactant template is removed except for the central metal ion that is oxidised, forming nanoparticles of RuO2 that deposit within the pores. RuO2 is a known oxidation catalyst and, despite its anhydrous nature in these silicates, is found to be very active in catalyzing the oxidation of water by acidic CeIV. 相似文献
20.
Volpi N 《Electrophoresis》2003,24(17):3097-3103
A rapid, highly sensitive and reproducible high-performance capillary electrophoresis (HPCE) method (electrokinetic chromatography with sodium dodecyl sulfate) is described for the determination of the lipopolysaccharide (LPS) and detoxified LPS (D-LPS), produced by both alkaline treatment in anhydrous conditions and mild acid hydrolysis, from Escherichia coli 055:B5 bacteria. LPS and D-LPS are separated and readily determined within 25 min on an uncoated fused-silica capillary using normal polarity at 20 kV and detection at 200 nm. A linear relationship (correlation coefficient greater than about 0.97) was found for the LPS and the two D-LPS species over a wide range of concentrations, from approximately 120 to 360 ng, with a detection sensitivity less than about 100 ng. Furthermore, HPCE was able to separate several molecular species mainly due to the presence of populations with O-specific polysaccharides of distinct and increasing mean chain lengths. This approach could be of great importance for the quantitative determination of LPS and D-LPS during the purification and preparation processes, also considering the importance of D-LPS in the preparation of human vaccines, and for the qualitative evaluation of the heterogeneity of LPS and the O-polysaccharide components. 相似文献
|