全文获取类型
收费全文 | 653篇 |
免费 | 26篇 |
国内免费 | 4篇 |
专业分类
化学 | 424篇 |
晶体学 | 3篇 |
力学 | 10篇 |
数学 | 112篇 |
物理学 | 134篇 |
出版年
2023年 | 9篇 |
2022年 | 6篇 |
2021年 | 8篇 |
2020年 | 13篇 |
2019年 | 15篇 |
2018年 | 12篇 |
2017年 | 11篇 |
2016年 | 25篇 |
2015年 | 16篇 |
2014年 | 18篇 |
2013年 | 46篇 |
2012年 | 38篇 |
2011年 | 51篇 |
2010年 | 28篇 |
2009年 | 33篇 |
2008年 | 39篇 |
2007年 | 37篇 |
2006年 | 36篇 |
2005年 | 34篇 |
2004年 | 37篇 |
2003年 | 18篇 |
2002年 | 22篇 |
2001年 | 7篇 |
2000年 | 7篇 |
1999年 | 14篇 |
1998年 | 8篇 |
1997年 | 6篇 |
1996年 | 8篇 |
1995年 | 7篇 |
1994年 | 11篇 |
1993年 | 6篇 |
1992年 | 5篇 |
1991年 | 6篇 |
1990年 | 6篇 |
1988年 | 2篇 |
1986年 | 1篇 |
1985年 | 4篇 |
1984年 | 7篇 |
1983年 | 7篇 |
1982年 | 6篇 |
1981年 | 1篇 |
1980年 | 3篇 |
1979年 | 1篇 |
1978年 | 2篇 |
1976年 | 1篇 |
1973年 | 3篇 |
1911年 | 2篇 |
排序方式: 共有683条查询结果,搜索用时 328 毫秒
31.
32.
33.
34.
Radiolysis of Aqueous Solutions of Benzoate Ion: A Radiation Chemistry Experiment for Undergraduates
This investigation describes the chemical effects of ionizing radiation on dilute aqueous solutions of benzoate ion. We have composed an experimental procedure that allows undergraduate chemistry students to identify and to quantitatively determine the amount of the products that are produced. The student investigators determine the absorbed dose that a sample receives when exposed to a 60Co source, irradiate dilute aqueous solutions of benzoate ion, and analyze the resulting mixture of hydroxybenzoate ions using high-performance liquid chromatography. The radiolysis of dilute solutions of benzoate ion results in the formation of a mixture of ortho-, meta-, and para-hydroxybenzoate ions that are readily separated on a C18 -Bondapak column. By the use of appropriate calibration curves, the yield (G values) of each of the isomers may be determined and compared.This paper was presented at the 15th Biennial Conference on Chemical Education, Waterloo, Ontario, Canada, August 1998 by N. Zevos and at the 26th Northeast Regional Meeting of the American Chemical Society by Evon Powell. 相似文献
35.
Wojciech Czardybon Wojciech Sokol John Warkentin Nick Henry Werstiuk 《Journal of Physical Organic Chemistry》2008,21(1):41-46
Synthesis of a bicyclic 2,2‐dioxa oxadiazoline (6,7‐diaza‐1‐methoxy‐5‐methyl‐2,8‐dioxabicyclo[3.2.1]oct‐6‐ene) is reported. Its thermolysis at 27°C is about 200 times as fast as the thermolysis of a monocyclic oxadiazoline model system. Presumably, a cyclic dioxa carbonyl ylide is formed initially and the ylide then undergoes a bond scission to afford either a dioxacarbene or a dialkylcarbene or it cyclizes to an oxirane. A small fraction of a dialkylcarbene was trapped as the product of addition to dimethyl acetylenedicarboxylate (DMAD). Computations of the barriers to the loss of N2 from the oxadiazolines and to the formation of the carbenes from the carbonyl ylide resulting from thermolysis of the bicyclic oxadiazoline are compared to corresponding barriers for a similar monocyclic oxadiazoline. The rate acceleration is accounted for in terms of geometric factors. The complex products from the decomposition of the bicyclic oxadiazoline were not studied. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
36.
G. Nagels 《General Relativity and Gravitation》1985,17(6):545-557
A pregeometry of space is considered, in which the only structure imposed on individual points is a uniform probability of adjacency between any two arbitrarily chosen points. This probability is not specified (but only assumed small) and neither is the total number of points specified (but is assumed large). It is shown that the most likely distribution of points has similarities with a closed three-dimensional space of constant positive curvature, in particular, the number of points at a given distance from an arbitrary origin is proportional to sine-squared of the distance from that origin. 相似文献
37.
We present a new method to measure the polarization state of a terahertz pulse by using a modified electro-optic sampling setup. To illustrate the power of this method, we show two examples in which the knowledge of the polarization of the terahertz pulse is essential for interpreting the results: spectroscopy measurements on polystyrene foam and terahertz images of a plastic coin. Both measurements show a sample-induced rotation of the terahertz electric field vector, which is surprisingly large and is a strong function of frequency. A promising aspect of our setup is the possibility of simultaneously measuring both transversal electric field components. 相似文献
38.
Tran NE Lambrakos SG Moore PG Ashraf Imam M Dulcey CS 《The Journal of chemical physics》2004,120(21):10257-10262
A prototype case study is presented that examines the level of hydrogen content in H-SWNTs using the Surface Plasmon Resonance technique. The damping effect and the angular shift in the resonance minimum of an SWNT-gold interface due to the presence of hydrogen is analyzed using a parametric model, which is based on the concept of an effective permittivity. The new approach provides for a non-invasive analysis of the level of hydrogen content in H-SWNTs and is potentially extendable to other carbon-based hydrogen storage materials. 相似文献
39.
Markowicz PP Tiryaki H Pudavar H Prasad PN Lepeshkin NN Boyd RW 《Physical review letters》2004,92(8):083903
We have observed a dramatic enhancement of third-harmonic generation in 3D polystyrene-air photonic crystals pumped by a near infrared laser beam. As the pump wavelength is tuned, the peak of the enhancement occurs when the third-harmonic wavelength approaches the short-wavelength edge of the band gap. We show that the origin of the enhancement is phase matching provided by the periodic structure of the photonic crystals. 相似文献
40.
MntA from Lactobacillus plantarum and copA from Enterococcus hirae both encode membrane proteins that are members of the P-type family of adenosine triphosphatases (ATPases). Both transporters
act as metal importers to take up nutritionally required substrates; MntA translocates Mn(II) and CopA translocates Cu(I).
Both ATPases can also translocate secondary substrates, Cd(II) and Ag(I), respectively. Although functionally and sequentially
similar, these ATPases differ in several key residues and in their membrane topologies. The bioaccumulation properties of
these two proteins were examined by coexpressing the transporters with overexpressed metallothionein in Escherichia coli cells, a system that has previously shown high levels of substrate-specific uptake. Both strains exhibited rapid metal accumulation,
both saturated at around 50 μM metal, and both displayed temperature-sensitive uptake. However, the transporters responded differently when external conditions
were varied; MntA displayed increased sensitivity to ionic strength, while CopA was more pH sensitive and more inhibited by
chelating agents. The differences in accumulation are likely owing to structural differences in the transmembrane region of
these two ATPases. 相似文献