两种钌配合物皮秒发光动力学过程研究

采用稳态发光光谱、瞬态发光动力学测量等手段,对两种钉配合物[Ru(bpy)3](ClO4)2和[Ru(bpy)2 HPIP](ClO4)2的发光性质进行了研究.稳态发光光谱表明[Ru(bpy)2 HPIP](ClO4)2发光明显偏弱;皮秒瞬态发光动力学测量显示[Ru(bpy)2 HPIP](ClO4)2的激发态弛豫过程...     

基于液氮低温冷刀系统的冻结组织温度场分布研究

设计了基于液氮的低温冷冻治疗系统,并进行动物组织实验研究,得到组织关键测温点的温度变化;并对冷冻过程进行数值模拟,将实验结果与模拟冷冻结果进行对比,根据二者的差异对数值模拟中采用的组织热物性参数进行修正,使模拟结果更接近于实际冷冻过程.     

分布反馈式光纤激光器线宽特性及其展宽机理研究

针对分布反馈式光纤激光器(DFB-FL)线宽特性进行了深入研究.通过理论推导和实验验证, 分析了自脉动、相 移光栅、激射窗口宽度以及外界环境扰动等因素对DFB-FL线宽的展宽作用. 进一步提出了压缩DFB-FL线宽的有效方法和途径,给出了自注入锁模方式下对DFB-FL线宽压缩的对比实验结果, 将DFB-FL的线宽从35 kHz压缩到了10 kHz.     

Open-circuit voltage analysis of p-i-n type amorphous silicon solar cells deposited at low temperature

This paper identifies the contributions of p-a-SiC:H layers and i-a-Si:H layers to the open circuit voltage of p-i-n type a-Si:H solar cells deposited at a low temperature of 125 C.We find that poor quality p-a-SiC:H films under regular conditions lead to a restriction of open circuit voltage although the band gap of the i-layer varies widely.A significant improvement in open circuit voltage has been obtained by using high quality p-a-SiC:H films optimized at the "low-power regime" under low silane flow rates and high hydrogen dilution conditions.     

Photoemission intensity oscillations in the valence bands of C70 film

We have measured and analyzed the photoemission spectra (PES) of a C₇₀ film in the photon energy region from 13.4 eV to 98.4 eV. The photoelectron intensities of two C 2p π-derived features (denoted by A and B) oscillate regularly in the whole energy region with some fine structures below ∼30 eV. To obtain the detailed information of the oscillations, we have developed a sophisticated but practical procedure for intensity calculation. The procedure consists of two core concepts. The first is ascribing the PES features to their corresponding molecular orbitals with the help of density functional calculations. The second is a background subtraction algorithm. With this procedure, we obtained the oscillating behavior for individual features (A and B), which is by and large consistent with the predictions based on the spherical symmetric approximation although C₇₀ has the ellipsoidal shape. Owing to the solid state effect, the oscillating amplitudes of the A/B intensity ratios are smaller than those of gas phase C₇₀, but an orbital shift reported recently was not observed on our sample. The oscillating curve of a deeper feature, which consists of both σ and π states, are also reported.     

Dynamical behaviour of Liu system with time delayed feedback

This paper investigates the dynamical behaviour of the Liu system with time delayed feedback. Two typical situations are considered and the effect of time-delay parameter on the dynamics of the system is discussed. It is shown that the Liu system with time delayed feedback may exhibit interesting and extremely rich dynamical behaviour. The evolution of the dynamics is shown to be complex with varying time-delay parameter. Moreover, the strange attractor like ‘wormhole＇ is detected via numerical simulations.     

基于频散补偿和分数阶微分的多模式兰姆波分离

由于兰姆波的多模和频散特性,实际检测时在同一激发频率下存在多种模式的混合信号,而各模式信号有不同的频散特性,使得在时频混叠的情况下兰姆波的检测变得十分复杂.本文在频散补偿的基础上,通过时延函数建模,依靠不同模式频散趋势的差异性,将时频混叠信号的分离问题转化为部分模式混叠信号的分离问题.基于分数阶微分的理论,用信号幅值谱分数阶微分极大值和对应频率分别与微分阶次拟合多项式实现特征参数的提取并依靠特征参数重建幅值谱.结合相位谱重构时域信号以实现部分混叠信号中频散补偿后的模式的分离.最后恢复频散获得分离后的兰姆波信号.仿真和实验结果表明,本文方法不仅可以实现时频混叠多模式兰姆波信号的分离,更能保证分离精度,有助于复杂多模式频散信号的分离与处理的进一步研究.     

Photonic instantaneous microwave frequency measurement based on two different phase modulation to intensity modulation conversions

A novel photonic technique for instantaneous frequency measurement of microwave signal based on phase modulation to intensity modulation conversion is proposed and demonstrated. In the proposed system, an optical carrier is modulated by a microwave signal with its frequency to be measured through a phase modulator. The phase-modulated optical signal is then converted to intensity-modulated signals in two independent paths using a dispersive media and a frequency discriminator respectively. Since the dependence of the received microwave power on the input microwave frequency in the two paths differs, the microwave power ratio between the two paths can be used to uniquely determine the microwave frequency. The major advantages of the approach lie in that only one laser source and the bias-free phase modulator is employed in the system, which improves the stability of the system. Experimental demonstrations of the frequency measurement based on the proposed approach are presented.     

极端紫外波段碱卤化物光阴极材料量子效率计算

为了满足极端紫外波段微通道位敏阳极光子计数探测器研究的需要,研究了碱卤化物光阴极材料的量子效率.由于光阴极材料的光电发射电流主要是由次级电子形成的,给出碱卤化物光阴极材料次级电子发射的理论模型,推导出次级电子产出的计算公式,针对光子能量30—250 eV范围内,计算并分析了光阴极材料厚度和光入射角对次级电子产出的影响.分析结果显示,光阴极材料厚度大于100 nm并且掠入射角大于临界角,是获得高次级电子产出的最佳条件.最后,应用推导的公式分析20种碱卤化物在能量30—250 eV范围内次级电子产出的光谱响应 关键词： 极端紫外 碱卤化物 光阴极 次级电子     

Optical properties of GdTaO4:Eu thick films prepared from a PVP-containing solution

Transparent GdTaO₄:Eu³⁺ thick films were prepared from the inorganic salt and 2-methoxyethanol solution containing polyvinylpyrrolidone (PVP) via sol-gel technique. The critical thickness of the film, i.e. the maximum thickness achievable without crack formation via non-repetitive deposition, was 0.8 μm. The effect of PVP on the morphology, crystallization behavior and optical property of the GdTaO₄:Eu³⁺ thick film was investigated. The results indicated that PVP could play an important role in the formation of transparent GdTaO₄:Eu³⁺ thick films, suppressing the stress evolution, adjusting the sol viscosity, ameliorating the crystallinity, and strengthening the covalency of Eu-O bonds. The GdTaO₄:Eu³⁺ thick films prepared with PVP exhibited a superior photoluminescence and X-ray exited luminescence, which implies that it will have promising applications in high-spatial-resolution X-ray imaging and flat panel display devices.