Sc(P204)3/烷基铝体系催化降冰片烯聚合

以钪的膦酸酯盐Sc(P204)3和烷基铝组成催化体系催化降冰片烯(NBE)聚合,考察了聚合反应条件对单体转化率、产物分子量以及微观结构的影响.当以三乙基铝为助催化剂时,[NBE]/[Sc]=50(摩尔比),[A1]/[Sc]=30(摩尔比),40℃陈化5 min,在甲苯中于60℃聚合7h,单体转化率为98％,所得聚合物可部分溶于有机溶剂;NBE以开环聚合方式为主,开环产物含量为81％ ～88％,其中顺式双键含量为48％ ～58％,分子量2.4×103～ 3.0×103,分子量分布1.9 ～2.2.当以三异丁基铝为助催化剂时,[NBE]/[Sc]=50(摩尔比),[Al]/[Sc] =5(摩尔比),50℃陈化2h,80℃下于甲苯中聚合4h,单体转化率为39％,所得白色聚合产物很难溶于有机溶剂,以开环聚合方式为主,产物中反式双键含量90％.     

含氨基聚芳醚酮/磺化聚芳醚酮砜中高温质子交换复合膜的制备与性能研究

以自制的高磺化度磺化聚芳醚酮砜(SPAEKS)和含有氨基的聚芳醚酮(Am-PAEK)为原料,通过共溶剂涂膜法制备了不同重量比例的Am-PAEK/SPAEKS复合膜.通过高温(160℃)处理使氨基和磺酸基团在复合膜内形成交联,制得交联型复合膜.复合膜的热性能、尺寸稳定性、阻醇性能有所提高,而且交联型复合膜中的Am-PAEK/SPAEKS-C-3质子传导率在120℃时达到了0.0892 S/cm,高于在相同测试条件下SPAEKS膜的0.0654 S/cm和Nafion膜的0.062 S/cm,而其甲醇渗透系数在25℃时达到0.14×10-6cm2/s,低于SPAEKS膜的0.85×10-6cm2/s和Nafion膜的2×10-6cm2/s.实验结果表明,Am-PAEK/SPAEKS交联型复合膜有望在中高温质子交换膜燃料电池中得到应用.     

Microstructure of sintered ND-Fe-Ga-B magnets with Mo and MoS2 addition

The effect of Mo and MoS₂ additions on the magnetic and microstructure properties has been investigated in Nd-Fe-Ga-B sintered magnets. Coercivity can be increased by both the additions, but the MoS₂ addition provides the larger increase per Mo atom for up to 0.6 at.% Mo. Microstructure investigation reveals a new amorphous intergranular Ga rich phase. This phase forms a thin layer in the grain boundaries and leads to a wetting behavior of the grain boundary phase, therefore increasing the coercivity. Molybdenum addition in the form of MoS₂ is found to modify the Nd₂Fe₁₄B phase, rather than form new minority phases, and the coercivity enhancement of the magnet is due to the increased anisotropy field of the hard magnetic phase.     

Multi-armed spirals and multi-pairs antispirals in spatial rock–paper–scissors games

We study the formation of multi-armed spirals and multi-pairs antispirals in spatial rock–paper–scissors games with mobile individuals. We discover a set of seed distributions of species, which is able to produce multi-armed spirals and multi-pairs antispirals with a finite number of arms and pairs based on stochastic processes. The joint spiral waves are also predicted by a theoretical model based on partial differential equations associated with specific initial conditions. The spatial entropy of patterns is introduced to differentiate the multi-armed spirals and multi-pairs antispirals. For the given mobility, the spatial entropy of multi-armed spirals is higher than that of single armed spirals. The stability of the waves is explored with respect to individual mobility. Particularly, we find that both two armed spirals and one pair antispirals transform to the single armed spirals. Furthermore, multi-armed spirals and multi-pairs antispirals are relatively stable for intermediate mobility. The joint spirals with lower numbers of arms and pairs are relatively more stable than those with higher numbers of arms and pairs. In addition, comparing to large amount of previous work, we employ the no flux boundary conditions which enables quantitative studies of pattern formation and stability in the system of stochastic interactions in the absence of excitable media.     

The structural and electronic properties of silicon nanoribbons on Ag(110): A first principles study

We have investigated the structures of silicon nanoribbons on Ag(110) using first principles calculations. The armchair silicon nanoribbons (ASiNRs) and zigzag silicon nanoribbons (ZSiNRs) with different widths are analyzed. The formation energy study shows that the ASiNRs with the width of 16 Å are the most stable structures. These ASiNRs have the structural parameters same as experimental ones. The simulated scanning tunneling microscope (STM) images of these ASiNRs also agree well with the experimental results. Thus, these ASiNRs are supposed to be the nanoribbons grown in experiment. The electronic structures shows that the ASiNRs are metallic, which is in agreement with the experiments.     

Isotope effects in water as investigated by neutron diffraction and path integral molecular dynamics

The structures of heavy and light water at 300?K were investigated by using a joint approach in which the method of neutron diffraction with oxygen isotope substitution was complemented by path integral molecular dynamics simulations. The diffraction results, which give intra-molecular O-D and O-H bond distances of 0.985(5) and 0.990(5)??, were found to be in best agreement with those obtained by using the flexible anharmonic TTM3-F water model. Both techniques show a difference of ??0.5% between the O-D and O-H intra-molecular bond lengths, and the results support a competing quantum effects model for water in which its structural and dynamical properties are governed by an offset between intra-molecular and inter-molecular quantum contributions. Further consideration of the O-O correlations is needed in order to improve agreement with experiment.     

Exponentially Many Monochromatic <Emphasis Type="Italic">n</Emphasis>-Matchings in <Emphasis Type="Italic">K</Emphasis><Subscript>3<Emphasis Type="Italic">n</Emphasis>-1</Subscript>

Erdös et al and Gerencsér et al had shown that in any 2-edge-coloring of K _3n-1, there is a n-matching containing edges with the same color(we call such matching monochromatic matching). In this paper we show that for any 2-edge-coloring of K _3n-1 there exists a monochromatic subgraph H of K _3n-1 which contains exponentially many monochromatic n-matchings.     

高效液相色谱分析鱼毒性藻类海洋卡盾藻溶血毒素

采用高效液相色谱技术(HPLC)分离和分析了海洋卡盾藻(香港株)溶血毒素的甲醇粗提物,通过对比不同流动相、检测波长、等度和梯度洗脱方式,初步建立了分析其溶血毒素的HPLC方法.结果表明,采用梯度洗脱的方法,海洋卡盾藻溶血毒素的粗提物在50 min内取得了较好地分离.色谱条件为C8硅胶柱(4.6 mm× 150 mm,5 μm),流动相为乙腈和水,梯度洗脱(0～10 min,60％→80％乙腈;10～40 min,80％ →90％乙腈;40～50 min,90％乙腈);紫外检测器检测波长为205和448nm;流速为0.8 mL/min;柱温为25℃.用兔血红细胞法对各个主要色谱峰进行溶血活性检测显示,海洋卡盾藻(香港株)的溶血毒素至少含有5种成分.光谱分析显示一种成分的紫外吸收高峰在448 nm,一种未完全分离的混合组分的紫外吸收高峰为440和446nm,另外3种成分的紫外吸收高峰为205 nm.     

分布反馈式光纤激光器线宽特性及其展宽机理研究

针对分布反馈式光纤激光器(DFB-FL)线宽特性进行了深入研究.通过理论推导和实验验证, 分析了自脉动、相 移光栅、激射窗口宽度以及外界环境扰动等因素对DFB-FL线宽的展宽作用. 进一步提出了压缩DFB-FL线宽的有效方法和途径,给出了自注入锁模方式下对DFB-FL线宽压缩的对比实验结果, 将DFB-FL的线宽从35 kHz压缩到了10 kHz.     

基于液氮低温冷刀系统的冻结组织温度场分布研究

设计了基于液氮的低温冷冻治疗系统,并进行动物组织实验研究,得到组织关键测温点的温度变化;并对冷冻过程进行数值模拟,将实验结果与模拟冷冻结果进行对比,根据二者的差异对数值模拟中采用的组织热物性参数进行修正,使模拟结果更接近于实际冷冻过程.