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961.
Selective Capture of Carbon Dioxide under Humid Conditions by Hydrophobic Chabazite‐Type Zeolitic Imidazolate Frameworks
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Nhung T. T. Nguyen Dr. Hiroyasu Furukawa Dr. Felipe Gándara Dr. Hoang T. Nguyen Kyle E. Cordova Prof. Omar M. Yaghi 《Angewandte Chemie (International ed. in English)》2014,53(40):10645-10648
Hydrophobic zeolitic imidazolate frameworks (ZIFs) with the chabazite ( CHA ) topology are synthesized by incorporating two distinct imidazolate links. Zn(2‐mIm)0.86(bbIm)1.14 (ZIF‐300), Zn(2‐mIm)0.94(cbIm)1.06 (ZIF‐301), and Zn(2‐mIm)0.67(mbIm)1.33 (ZIF‐302), where 2‐mIm=2‐methylimidazolate, bbIm=5(6)‐bromobenzimidazolate, cbIm=5(6)‐chlorobenzimidazolate, and mbIm=5(6)‐methylbenzimidazolate, were prepared by reacting zinc nitrate tetrahydrate and 2‐mIm with the respective bIm link in a mixture of N,N‐dimethylformamide (DMF) and water. Their structures were determined by single‐crystal X‐ray diffraction and their permanent porosity shown. All of these structures are hydrophobic as confirmed by water adsorption isotherms. All three ZIFs are equally effective at the dynamic separation of CO2 from N2 under both dry and humid conditions without any loss of performance over three cycles and can be regenerated simply by using a N2 flow at ambient temperature. 相似文献
962.
Molecular simulation has been increasingly used in the analysis and modeling of gas adsorption on open surfaces and in porous materials because greater insight could be gained from such a study. In case of homogeneous surfaces or pore walls the adsorption behavior is often complicated by the order–disorder transition. It is shown in our previous publications (Ustinov and Do, Langmuir 28:9543–9553, 2012a; Ustinov and Do, Adsorption 19:291–304, 2013) that once an ordered molecular layer has been formed on the surface, the lattice constant depends on the simulation box size, which requires adjusting the box dimensions parallel to the surface for each value of loading. It was shown that this can be accomplished with the Gibbs–Duhem equation, which results in decreasing lattice constant with an increase of the amount adsorbed. The same feature is expected to be valid for gas adsorption in narrow pores, but this has not been analyzed in the literature. This study aims at an extension of our approach to adsorption in slit graphitic pores using kinetic Monte Carlo method (Ustinov and Do, J Colloid Interface Sci 366:216–223, 2012b). The emphasis rests on the thermodynamic analysis of the two-dimensional (2D) ordering transition and state of the ordered phase; if the ordered phase exists in narrow slit pores, simulation with constant volume box always leads to erroneous results, for example, seemingly incompressible adsorbed phase. We proposed a new approach that allows for modeling thermodynamically consistent adsorption isotherms, which can be used as a basis for further refinement of the pore size distribution analysis of nanoporous materials. 相似文献
963.
Bui?Van Thanh Do?N?Dai Tran?D?ThangEmail author Nguyen?Q?Binh Luu?D?Ngoc?Anh Isiaka?A?Ogunwande 《Chemistry Central journal》2014,8(1):54
Background
Vietnam is a country blessed with many medicinal plants widely used as food and for medicinal purposes, and they contain a host of active substances that contribute to health. However, the analysis of chemical constituents of these plant species has not been subject of literature discussion.Results
In this study, the chemical compositions of essential oils of four Hedychium species, obtained by hydrodistillation, were determined by means of gas chromatography-flame ionization detector (GC-FID) and gas chromatography–mass spectrometry (GC-MS) techniques. Individually, α-pinene (52.5%) and β-pinene (31.8%) were present in the leaf oil of Hedychium stenopetalum Lodd., while linalool (45.2%), (E)-nerolidol (8.7%) and α-pinene (5.0%) were identified in the root. The leaf of Hedychium coronarium J. König was characterized by α-pinene (20.0%), linalool (15.8%), 1,8-cineole (10.7%), α-pinene (10.1%) and α-terpineol (8.6%); while α-pinene (23.6%), α-humulene (17.1%) and β-caryophyllene (13.0%) were identified in the root. Hedychium flavum Roxb., gave oil whose major compounds were α-pinene (22.5%), α-humulene (15.7%) and β-caryophyllene (10.4%) in the leaf; α-humulene (18.9%), β-caryophyllene (11.8%) and α-pinene (11.2%) in the stem, as well as α-pinene (21.8%), linalool (17.5%) and 1,8-cineole (13.5%) in the root. The main constituents of Hedychium ellipticum Buch.-Ham. ex Smith were (E)-nerolidol (15.9%), α-pinene (11.8%) and bornyl acetate (9.2%) in the leaf with 1,8-cineole (40.8%), α-pinene (18.3%) and α-pinene (11.0%) occurring in the root.Conclusions
Ubiquitous monoterpenes and sesquiterpenes were identified as characteristic markers for Hedychium species. This work is of great importance for the evaluation of Hedychium essential oils grown in Vietnam.964.
This account discusses representative case studies for various applications of quantum chemical calculations in synthetic organic chemistry. These include confirmation of target structures, methodology development, and catalyst design. These examples demonstrate how predictions from quantum chemical calculations can be utilized to streamline synthetic efforts. 相似文献
965.
An opioid receptor like (ORL1) receptor is one of a family of G-protein-coupled receptors (GPCR); it represents a new pharmaceutical target with extensive therapeutic potential for the regulation of important biological functions such as nociception, mood disorders, drug abuse, learning or cardiovascular control. Although the crystal structure of the inactive form of the ORL1 receptor has been determined, little is known about its activation. By using X-ray structures of the β2-adrenegic receptor in its inactive (2RH1) and active (3P0G) states as templates, inactive and active homology models of the ORL1 receptor were constructed. Structurally diverse sets of strongly binding antagonists and agonists were docked with both ORL1 receptor forms. The major receptor-ligand interactions responsible for antagonist and agonist binding were identified. Although both sets of ligands, agonists and antagonists, bind to the same region of the receptor, they occupy partially different binding pockets. Agonists bind to the inactive receptor in a slightly different manner than antagonists. This difference is more pronounced in binding to the active ORL1 receptor model and points to the amino acids at the extracellular end of TM6, suggesting that this region is important for receptor-activation. 相似文献
966.
967.
Obesity is recognized as a chronic low-grade inflammatory state due to adipose tissue expansion being accompanied by an increase in the production of proinflammatory adipokines. Our group is the first to report that B-cell-activating factor (BAFF) is produced from adipocytes and functions as a proinflammatory adipokine. Here, we investigated how loss of BAFF influenced diet-induced obesity in mice by challenging BAFF−/− mice with a high-fat diet for 10 weeks. The results demonstrated that weight gain in BAFF−/− mice was >30% than in control mice, with a specific increase in the fat mass of the subcutaneous region rather than the abdominal region. Expression of lipogenic genes was examined by quantitative real-time PCR, and increased lipogenesis was observed in the subcutaneous adipose tissue (SAT), whereas lipogenesis in the epididymal adipose tissue (EAT) was reduced. A significant decrease in EAT mass resulted in the downregulation of inflammatory gene expression in EAT, and more importantly, overall levels of inflammatory cytokines in the circulation were reduced in obese BAFF−/− mice. We also observed that the macrophages recruited in the enlarged SAT were predominantly M2 macrophages. 3T3-L1 adipocytes were cultured with adipose tissue conditioned media (ATCM), demonstrating that EAT ATCM from BAFF−/− mice contains antilipogenic and anti-inflammatory properties. Taken together, BAFF−/− improved systemic inflammation by redistributing adipose tissue into subcutaneous regions. Understanding the mechanisms by which BAFF regulates obesity in a tissue-specific manner would provide therapeutic opportunities to target obesity-related chronic diseases. 相似文献
968.
Separation of p‐Divinylbenzene by Selective Room‐Temperature Adsorption Inside Mg‐CUK‐1 Prepared by Aqueous Microwave Synthesis
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Beau Saccoccia Alisha M. Bohnsack Nolan W. Waggoner Kyung Ho Cho Ji Sun Lee Dr. Do‐Young Hong Dr. Vincent M. Lynch Dr. Jong‐San Chang Prof. Simon M. Humphrey 《Angewandte Chemie (International ed. in English)》2015,54(18):5394-5398
A new MgII‐based version of the porous coordination polymer CUK‐1 with one‐dimensional pore structure was prepared by microwave synthesis in water. Mg‐CUK‐1 is moisture‐stable, thermally stable up to 500 °C, and shows unusual reversible soft‐crystal behavior: dehydrated single crystals of the material selectively adsorb a range of organic molecules at ambient temperature and pressure. Both polar and apolar aromatic compounds, including pyridine, benzene, p‐xylene, and p‐divinylbenzene (p‐DVB), are all readily adsorbed, while other isomers from complex mixtures of xylenes or DVBs are selectively excluded. The solvent‐loaded structures have been studied by single‐crystal X‐ray diffraction. Time‐dependent liquid sorption experiments using commercially available DVB demonstrate a high and rapid selective adsorption of p‐DVB and exclusion of m‐DVB and ethylvinylbenzene isomers. 相似文献
969.
970.
Photo-differential scanning calorimetric (Photo-DSC) technique was used to study the gelation of P-3038 (epoxy acrylate (EA) 75% and tripropyleneglycoldiacrylate (TPGDA) 25%) in the presence of various thioxanthone-based initiators, namely, thioxanthone (TX), 5-thia-naphtacene-12-one (TX-NP), 2-(carboxymethoxy) thioxanthone (TX-OCH2COOH), 2-thioxanthone-thioacetic acid (TX-SCH2COOH), and 2-mercaptothioxanthone (TX-SH). Photopolymerization reactions were performed under identical conditions of temperature, initiator concentration, and UV light intensity. Photo-DSC technique allowed us to monitor the gelation, without disturbing the system mechanically, and to test the universality of the gelation as a function of some kinetic parameters like initiator concentration. During gelation, it was observed that all conversion curves present a good sigmoidal behavior by predicting to employ percolation model. Observations around the glass transition point, t g shows that the gel fraction exponents β obeyed the percolation picture. On the other hand, t g was found to be much higher for the crosslinked networks obtained with TX-OCH2COOH and TX-SCH2COOH initiators than those with the other initiators. 相似文献