全文获取类型
收费全文 | 2066篇 |
免费 | 73篇 |
国内免费 | 37篇 |
专业分类
化学 | 1158篇 |
晶体学 | 35篇 |
力学 | 65篇 |
数学 | 375篇 |
物理学 | 543篇 |
出版年
2023年 | 16篇 |
2022年 | 20篇 |
2021年 | 37篇 |
2020年 | 37篇 |
2019年 | 34篇 |
2018年 | 26篇 |
2017年 | 27篇 |
2016年 | 53篇 |
2015年 | 36篇 |
2014年 | 53篇 |
2013年 | 112篇 |
2012年 | 145篇 |
2011年 | 154篇 |
2010年 | 92篇 |
2009年 | 67篇 |
2008年 | 112篇 |
2007年 | 94篇 |
2006年 | 105篇 |
2005年 | 81篇 |
2004年 | 79篇 |
2003年 | 66篇 |
2002年 | 56篇 |
2001年 | 46篇 |
2000年 | 53篇 |
1999年 | 48篇 |
1998年 | 22篇 |
1997年 | 36篇 |
1996年 | 20篇 |
1995年 | 33篇 |
1994年 | 28篇 |
1993年 | 38篇 |
1992年 | 46篇 |
1991年 | 34篇 |
1990年 | 31篇 |
1989年 | 27篇 |
1988年 | 15篇 |
1987年 | 15篇 |
1986年 | 18篇 |
1985年 | 26篇 |
1984年 | 22篇 |
1983年 | 6篇 |
1982年 | 13篇 |
1981年 | 13篇 |
1980年 | 8篇 |
1979年 | 17篇 |
1978年 | 12篇 |
1977年 | 7篇 |
1975年 | 5篇 |
1974年 | 11篇 |
1973年 | 7篇 |
排序方式: 共有2176条查询结果,搜索用时 15 毫秒
101.
A series of photochromic spirooxazine-containing zinc(II) diimine bis-thiolate complexes were successfully synthesized, and their photophysical and photochromic properties were studied. The X-ray crystal structure of complex 1a has also been determined. Upon excitation by UV light at 330 nm, all the ligands and complexes exhibit photochromic behavior. The thermal bleaching kinetics of the ligands and the complexes were studied in dimethylformamide at various temperatures. The photochemical quantum yields for the photochromic reactions of the ligands and complexes were also determined. 相似文献
102.
This paper presents an interior point method to determine the minimum energy conformation of alanine dipeptide. The CHARMM energy function is minimized over the internal coordinates of the atoms involved. A barrier function algorithm to determine the minimum energy conformation of peptides is proposed. Lennard-Jones 6-12 potential which is used to model the van der Waals interactions in the CHARMM energy equation is used as the barrier function for this algorithm. The results of applying the algorithm for the alanine dipeptide structure as a function of varying number of dihedral angles are reported, and they are compared with that obtained from genetic algorithm approach. In addition, the results for polyalanine structures are also reported. 相似文献
103.
Fifty different carbon–hydrogen distances have been predicted from ab initio MP2/6-311+G(d,p) calculations, which range from a short value of 1.0611 Å for HCNO to a long value of 1.1044 Å for H2CO. The values include those predicted for a series of methyl (CH3) moieties where the two different C–H distances vary by as much as 0.005 Å. These predicted values are compared to r
0(C–H) distances obtained from the isolated carbon–hydrogen stretching frequencies, as well as to r
0 or r
s
parameters obtained from microwave data. Except for the very short C–H bonds, the ab initio values from the MP2/6–311+G(d,p) calculations can be used for the carbon–hydrogen distances with error limits of ± 0.003 Å. By utilizing the spectral data from CD3CClO, it is shown that combination bands in the C–H stretching region could cause problems in the identification of the isolated C–H stretching frequency from the CD2HCClO isotopomer. The value of the ab initio predicted C–H distances for checking unusually long or short r
s
(C–H) or r
0 values is demonstrated. 相似文献
104.
Gooding KB Higgs R Hodge B Stauffer E Heinz B McKnight K Phipps K Shapiro M Winkler M Ng WL Julian RK 《Journal of the American Society for Mass Spectrometry》2004,15(6):884-892
Approximately 300,000 compounds from selected libraries were screened against a subdomain of a hepatitis C viral (HCV) RNA using a high throughput flow injection mass spectrometry (FIA-MS) method with automated data storage and analysis. Samples contained 2 microM RNA target and 10 microM of each of up to ten ligands. Preliminary studies to optimize operational parameters used the binding of aminoglycosides to the A44 subdomain of bacterial RNA. Binding (confirmed by titration) and sensitivity were maximized within the constraints of the library and throughput. The mobile phase of 5 mM ammonium acetate in 50% isopropanol maintained the noncovalent complexes and provided good detection by electrospray mass spectrometry. Additionally, this composition maximized general solubility of the various classes of compounds including the oligonucleotide and organic library molecules. Cation adduction was insignificant in this screen although some solute and target dependent acetate adduction was observed. The ion trap mass spectrometer provided sufficient mass resolution to identify complexes of RNA with known components of the library. Converted mass spectral data (netCDF) were subjected to two types of statistical evaluation based on binding. The first algorithm identified noncovalent complexes that correlated with the molecular weights of the injected compounds. The second yielded the largest peak in the noncovalent complex region of the spectrum; this spectrum may or may not correlate with expected well components. Sixty-three compounds were confirmed to bind by more stringent secondary testing. Titrations, which were carried out with selected binding compounds, yielded a range of dissociation constants. Biological activity was observed for eleven confirmed binders. 相似文献
105.
We devised a dangling cantilever optical lever setup with imaging that permits dynamical studies of superhydrophobic surfaces without the effects of gravitational acceleration for better insight into the mechanics. The setup enabled us to ascertain liquid loss and ascribe it to the interaction of liquid that just touched the superhydrophobic surface as it translated at various constant lateral speeds. At lower speeds (20-60 μm/s), the interactions were characterized by a strong initial liquid pin (at up to 0.6 nN force) and depin followed by a series of smaller force pin and depins before sufficient liquid loss led to total liquid detachment from the surface. At higher translation speeds (80-100 μm/s), the interactions were characterized by liquid pinning and depinning processes at a sustained force (around 0.7 nN) in which liquid loss was low enough to engender a much later liquid detachment (beyond 100 s). A linear reduction of the receding contact angle with time, but not with the advancing contact angle, was found up to the point of first liquid depinning. This suggested a stronger role played by the receding contact line in establishing liquid adherence to the superhydrophobic surface. The detachment process from the surface was also characterized by a liquid bridge driven to rupture by way of liquid being conveyed away from the bridge. 相似文献
106.
Swadźba-Kwaśny M Chancelier L Ng S Manyar HG Hardacre C Nockemann P 《Dalton transactions (Cambridge, England : 2003)》2012,41(1):219-227
Two stable nanofluids comprising of mixed valent copper(I,II) oxide clusters (<1 nm) suspended in 1-butyl-3-methylimidazolium acetate, [C(4)mim][OAc], and copper(II) oxide nanoparticles (<50 nm) suspended in trioctyl(dodecyl)phosphonium acetate, [P(8 8 8 12)][OAc], were synthesised in a facile one-pot reaction from solutions of copper(II) acetate hydrate in the corresponding ionic liquids. Formation of the nanostructures was studied using (13)C NMR spectroscopy and differential scanning calorimetry (DSC). From a solution of Cu(OAc)(2) in 1-ethyl-3-methylimidazolium acetate, [C(2)mim][OAc], crystals were obtained that revealed the structure of [C(2)mim][Cu(3)(OAc)(5)(OH)(2)(H(2)O)]·H(2)O, indicating the formation of copper hydroxo-clusters in the course of the reaction. Synthesised nanostructures were studied using transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). Physical properties of the prepared IL-nanofluids were examined using IR and UV-VIS spectroscopy, thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and densitometry. 相似文献
107.
Winghong Chan Suei Yee Lam-Leung Chingfai Ng Junqi Ding Shiping Xi 《Journal of polymer science. Part A, Polymer chemistry》1995,33(15):2525-2531
New diamino monomers IIa – IIg were synthesized in a two-step reaction sequence starting from p-acetamidobenzenesulfonyl chloride. Solution polymerization of these monomers in DMAC with terephthaloyl or isophthaloyl chloride resulted in the formation of a series of 14 poly(amide sulfonamide)s (PASAs) in excellent yield (> 95%). The polymers have in-trinsic viscosities of 0.32–1.11 dL g?1. Except for polymers IIIa ? p and IIId - p , all other PASAs were readily soluble in aprotic polar solvents including DMAC, DMF, and DMSO. Thermogravimetric analyses of the polymers showed moderate thermal stability with 10% weight loss being recorded in the range of 325–408°C. In addition, these polymers exhibit moderate chemical stabilities toward alkali, acidic, and chromic acid solution. © 1995 John Wiley & Sons, Inc. 相似文献
108.
109.
110.
Applied Biochemistry and Biotechnology - The model describes the anaerobiosis of 2-ethylhexanoic acid (2-EHA), which is a persistent and inhibitory organic waste. Model development was based on a... 相似文献