Gas-phase reactions of lithium dimethylaminoborohydride and related species

[reaction: see text] Ab initio and density functional theory (DFT) calculations were used to examine the mechanisms of reduction and amination of chloromethane by lithium dimethylaminoborohydride (LAB) in the gas phase. For comparison, the amination of chloromethane by lithium dimethylamide and the reduction by borane, diborane, and borohydride ions were also examined. The reduction of chloromethane by LAB occurred most readily from a conformation that allowed coordination of the lithium atom to the chloride leaving group, and the most favorable amination pathway occurred by a backside attack of the nitrogen nucleophile on chloromethane.     

Shape and size control of Ag2Se nanocrystals from a single precursor [(Ph3P)3Ag2(SeC{O}Ph)2

Monodispersed Ag2Se nanocubes and faceted nanocrystals have been synthesized by hexadecylamine (HDA) induced thermolysis of [(PPh3)3Ag2(SeC{O}Ph)2] in a mixture of TOP (tri-n-octyl phosphine) and HDA in the temperature range 95-180 degrees C.     

On the stable rank of algebras of operator fields over metric spaces

Let Γ be a finitely generated, torsion-free, two-step nilpotent group. Let C^*(Γ) denote the universal C^*-algebra of Γ. We show that , where for a unital C^*-algebra A, sr(A) is the stable rank of A, and where is the space of one-dimensional representations of Γ. In process, we give a stable rank estimate for maximal full algebras of operator fields over metric spaces.     

GaAs distributed Bragg reflector lasers

An equivalent cavity approach is used to derive the oscillation condition of a distributed Bragg reflector laser. The oscillation frequencies and thresholds are determined graphically. The effect of lossy reflectors is discussed. Several advantages and potential applications of distributed Bragg reflector structures are pointed out. Experimental results on optically pumped GaAs lasers are presented.     

Reduced Brillouin backscatter in CO2 laser-target interaction

Substantially reduced Brillouin reflection has been found for CO₂ laser irradiated high density gas targets. In contrast to high reflectivity (60%) previously observed for underdense hydrogen plasma, total backscatter (stimulated plus specular) is found to peak at 30% for incident intensity 5 × 10¹² W/cm² and decrease thereafter to 18% at 10¹³ W/cm². Ponderomative effects are postulated to account for these observations.     

Determination of components in propolis by capillary electrophoresis and photodiode array detection

The capillary electrophoretic separation of components in propolis, a commonly used natural medicine, was investigated. Optimum conditions for the separation were established. Photodiode-array detection permitted the rapid identification of the components in the samples analysed. The determination of these components, including caffeic acid, dimethylcaffeic acid, isoferulic acid and quercetin, was performed on a commercial propolis sample.     

Heavy-ion optical potentials at finite temperature calculated using a complex effective interaction derived from a realistic force

Hot density distributions of heavy ions generated by a modified Thomas-Fermi calculation at finite temperature are used to calculate the optical potential using the double-folding method and a complex effective energy and density-dependent interaction deduced from a realistic NN (Reid soft-core) force in nuclear matter. The real and the imaginary part of the optical potential become more attractive when the temperature increases.     

Spherical time dependent Thomas-Fermi calculation of the dynamical evolution of hot and compressed nuclei

We have used a self-consistent time dependent Thomas-Fermi model at finite temperature to calculate the dynamical evolution of hot and compressed nuclei. It has been found that nuclei can accomodate more thermal energy than compressional energy before they break.     

Synthesis of Biomorphic ZrO2-CeO2 Nanostructures by Silkworm Silk Template

以桑蚕丝为模板制备多级生物形态结构ZrO₂-CeO₂. 整个合成过程是由桑蚕丝模板的导向作用决定的. 分析结果表明ZrO₂-CeO₂结晶良好,呈多级网络中空纤维结构,直径为16～28μm,800 oC煅烧后ZrO₂-CeO₂晶粒尺寸约为14 nm.