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31.
Xavier Gerbaux Armand Hadni M. Tazawa 《International Journal of Infrared and Millimeter Waves》1997,18(9):1611-1635
The different technical approaches are considered mostly to compare the accuracy attainable in microwaves to Far IR where
new resonant tchniques have been developped. It is possible to use the fringes of the observed spectra to get directly the
London penetration length. However in the present state of the Art there is more accuracy to use a two-fluid model with at
least one Mid-IR oscillator, and a strategy is possible to fit separately the different parameters. The different results
are reviewed and compared to the microwaves data. There is a good accordance, except perhaps for the power law-giving the
concentration of quasiparticles in the superconductive phase. For a thin film of YBCO devoid of grain-boundaries (no twins),
a θ4 law is found instead of a θ1.5 law for an ordinary film. It should be highly valuable that both microwaves and Far-IR data should be taken on the same sample.
presented at the 22nd International Conference on Infrared and Millimeter Waves, July 20–25, 1997, Wintergreen, Virginia 22958
USA. 相似文献
32.
33.
Fijalkowski KJ Genova RV Filinchuk Y Budzianowski A Derzsi M Jaroń T Leszczyński PJ Grochala W 《Dalton transactions (Cambridge, England : 2003)》2011,40(17):4407-4413
We describe the successful synthesis of the first mixed-cation (pseudoternary) amidoborane, Na[Li(NH(2)BH(3))(2)], with theoretical hydrogen capacity of 11.1 wt%. Na[Li(NH(2)BH(3))(2)] crystallizes triclinic (P1) with a = 5.0197(4) ?, b = 7.1203(7) ?, c = 8.9198(9) ?, α = 103.003(6)°, β = 102.200(5)°, γ = 103.575(5)°, and V = 289.98(5) ?(3) (Z = 2), as additionally confirmed by Density Functional Theory calculations. Its crystal structure is topologically different from those of its orthorhombic LiNH(2)BH(3) and NaNH(2)BH(3) constituents, with distinctly different coordination spheres of Li (3 N atoms and 1 hydride anion) and Na (6 hydride anions). Na[Li(NH(2)BH(3))(2)], which may be viewed as a product of a Lewis acid (LiNH(2)BH(3))/Lewis base (NaNH(2)BH(3)) reaction, is an important candidate for a novel lightweight hydrogen storage material. The title material decomposes at low temperature (with onset at 75 °C, 6.0% mass loss up to 110 °C, and an additional 3.0% up to 200 °C) while evolving hydrogen contaminated with ammonia. 相似文献
34.
Casadevall i Solvas X Geier FM Leroi AM Bundy JG Edel JB DeMello AJ 《Chemical communications (Cambridge, England)》2011,47(35):9801-9803
We present a passive microfluidic strategy for sorting adult C. elegans nematodes on the basis of age and size. The separation mechanism takes advantage of phenotypic differences between 'adult' and 'juvenile' organisms and their behaviour in microfluidic architectures. In brief, the microfluidic device allows worms to sort themselves in a passive manner. 相似文献
35.
36.
Katarzyna Betlejewska-Kielak Elbieta Bednarek Armand Budzianowski Katarzyna Michalska Jan K. Maurin 《Molecules (Basel, Switzerland)》2021,26(13)
Racemic ketoprofen (KP) and β-cyclodextrin (β-CD) powder samples from co-precipitation (1), evaporation (2), and heating-under-reflux (3) were analysed using X-ray techniques and nuclear magnetic resonance (NMR) spectroscopy. On the basis of NMR studies carried out in an aqueous solution, it was found that in the samples obtained by methods 1 and 2, there were large excesses of β-CD in relation to KP, 10 and 75 times, respectively, while the sample obtained by method 3 contained equimolar amounts of β-CD and KP. NMR results indicated that KP/β-CD inclusion complexes were formed and the estimated binding constants were approximately 2400 M−1, showing that KP is quite strongly associated with β-CD. On the other hand, the X-ray single-crystal technique in the solid state revealed that the (S)-KP/β-CD inclusion complex with a stoichiometry of 2:2 was obtained as a result of heating-under-reflux, for which the crystal and molecular structure were examined. Among the methods used for the preparation of the KP/β-CD complex, only method 3 is suitable. 相似文献
37.
Paul Armand 《Computational Optimization and Applications》2003,26(1):5-34
We describe an infeasible interior point algorithm for convex minimization problems. The method uses quasi-Newton techniques for approximating the second derivatives and providing superlinear convergence. We propose a new feasibility control of the iterates by introducing shift variables and by penalizing them in the barrier problem. We prove global convergence under standard conditions on the problem data, without any assumption on the behavior of the algorithm. 相似文献
38.
Armand Siegel 《Foundations of Physics》1970,1(1):57-68
The quantum formalism ofdistinguishable, yetequivalent particles (with symmetric or antisymmetric wave functions) is here worked out. The result is an entirely explicit formulation of the way in which classical mechanics emerges from quantum mechanics for such particles. Distinguishability is achieved at the cost of dynamical precision; the two are, in fact, complementary.Research sponsored in part by the Air Force Office of Scientific Research, Office of Aerospace Research, United States Air Force, under AFOSR Grant No. 557–67. 相似文献
39.
The reactivity of bis(trimethylsilyl)peroxide with a variety of nucleophilic, electrophilic, oxidizing, and reducing agents has been investigated. 相似文献
40.