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71.
72.
PtSn/C and PtSnSb/C electrocatalysts (20 wt.% metal loading) were prepared by an alcohol reduction process using H2PtCl6.6H2O, SnCl2.2H2O, and Sb(OOCCH3) as metal sources, ethylene glycol as solvent and reducing agent, and Vulcan XC72 as carbon support. The
electrocatalysts were characterized by energy dispersive X-ray analysis, X-ray diffraction, and transmission electron microscopy,
while that the performance for ethanol oxidation was investigated by cyclic voltammetry and chronoamperommetry (chrono) at
room temperature. The diffractograms of the PtSn/C and PtSnSb/C electrocatalysts showed four peaks associated to Pt face-centered
cubic structure and two peaks that were related to a SnO2 phase. For PtSb/C and PtSnSb/C electrocatalysts, no Sb (antimony) peaks corresponding to a metallic antimony or antimony
oxide phases were observed. Transmission electron microscopy images showed that the metal particles were homogeneously distributed
over the support. The PtSnSb/C (50:45:05) electrocatalyst showed an increase of performance for ethanol oxidation in relation
to PtSn/C electrocatalyst at room temperature. In the tests at 100 °C on a single cell of a direct ethanol fuel cell, the
maximum power density of PtSnSb/C (50:45:05) electrocatalyst was slightly higher than that of PtSn/C electrocatalyst. 相似文献
73.
G. Silva Neto 《Mathematische Zeitschrift》2014,277(1-2):481-497
We will prove that there are no stable complete hypersurfaces of $\mathbb {R}^4$ with zero scalar curvature, polynomial volume growth and such that $\frac{(-K)}{H^3}\ge c>0$ everywhere, for some constant $c>0$ , where K denotes the Gauss-Kronecker curvature and $H$ denotes the mean curvature of the immersion. Our second result is the Bernstein type one there is no entire graphs of $\mathbb {R}^4$ with zero scalar curvature such that $\frac{(-K)}{H^3}\ge c>0$ everywhere. At last, it will be proved that, if there exists a stable hypersurface with zero scalar curvature and $\frac{(-K)}{H^3}\ge c>0$ everywhere, that is, with volume growth larger than polynomial growth of order four, then its tubular neighborhood is not embedded for suitable radius. 相似文献
74.
Nattascha Kyaw Rafael Fonseca de Mesquita Etel Kameda João Crisósthomo de Queiroz Neto Marta Antunes Pereira Langone Maria Alice Zarur Coelho 《Applied biochemistry and biotechnology》2010,161(1-8):171-180
Drilling fluid has many functions, such as carry cuttings from the hole permitting their separation at the surface, cool and clean the bit, reduce friction between the drill pipe and wellbore, maintain the stability of the wellbore, and prevent the inflow of fluids from the wellbore and form a thin, low-permeable filter cake. Filter cake removal is an important step concerning both production and injection in wells, mainly concerning horizontal completion. The drilling fluids are typically comprised of starch, the most important component of the filter cake. A common approach to remove this filter cake is the use of acid solutions. However, these are non-specific reactants. A possible alternative is the use of enzymatic preparations, like amylases, that are able to hydrolyze starch. Wells usually operate in drastic conditions for enzymatic preparations, such as high temperature, high salt concentration, and high pressure. Thus, the main objective of this work was to characterize four enzymatic preparations for filter cake removal under open hole conditions. The results showed that high salt concentrations (204,000 ppm NaCl) in completion fluid decreased amylolytic activity. All enzymatic preparations were able to catalyze starch hydrolysis at all temperatures tested (30, 65, 80, and 95 °C). An increase of amylolytic activity was observed with the increase of pressure (100, 500 and 1,000 psi) for one commercial amylase. 相似文献
75.
We generalize Frobenius singular theorem due to Malgrange, for a large class of codimension one holomorphic foliations on
singular analytic subsets of ℂ
N
.
This research was partially supported by Pronex. 相似文献
76.
Petr Ya. Ekel Marden Menezes Fernando H. Schuffner Neto 《Nonlinear Analysis: Hybrid Systems》2007,1(4):527-536
This paper presents results of research into the use of the Bellman–Zadeh approach to decision making in a fuzzy environment for solving multicriteria optimization problems. Its application conforms to the principle of guaranteed result and provides constructive lines in obtaining harmonious solutions on the basis of analyzing associated maxmin problems. The use of the Bellman–Zadeh approach has served as a basis for solving a problem of multicriteria allocation of resources (or their shortages) and developing a corresponding adaptive interactive decision making system (AIDMS1). AIDMS1 includes procedures for considering linguistic variables to reflect conditions that are difficult to formalize as well as procedures for constructing and correcting vectors of importance factors for goals. The use of these procedures permits one to realize an adaptive approach to processing information of a decision maker to provide successive improvment in solution quality. The results of the paper are universally applicable and are already being used to solve power engineering problems. It is illustrated by considering problems of multicriteria power and energy shortage allocation and multicriteria power system operation. 相似文献
77.
M.A. da Nbrega J.M. S F.H.R. Bezerra J.C. Hadler Neto P.J. Iunes S. Guedes C.A. Tello Saenz P.C. Hackspacher F.P. Lima-Filho 《Radiation measurements》2005,39(6):627-633
An apatite fission track study of crystalline rocks underlying sedimentary basins in northeastern Brazil indicate that crustal blocks that occur on opposite sides of a geological fault experienced different thermal histories. Samples collected on the West block yielded corrected fission-track ages from 140 to 375 Ma, whereas samples collected on the East block yielded ages between 90 and 125 Ma. The thermal models suggest that each block experienced two cooling events separated by a heating event at different times. We concluded that the West block moved downward relative to the East block ca. 140 Ma ago, when sediments eroded from the East side were deposited on the West side. This process represents the early stage of sedimentary basin formation and the opening of the South Atlantic Ocean in the region. Downward and upward movements related to heating and cooling events of these crustal blocks at different periods until recent times are proposed. 相似文献
78.
F. Guinea A. H. Castro Neto N. M.R. Peres 《The European physical journal. Special topics》2007,148(1):117-125
We discuss the excitation spectrum, electronic susceptibilities,
and possible electronic instabilities in graphene and graphene stacks. The
corrections due interactions of Landau levels in graphene are analyzed. At
low dopings, and for
sufficiently low couplings, single layer graphene is stable against
ferromagnetism. On the other hand, a graphene bilayer, and
infinite graphite, are unstable towards ferromagnetism and
antiferromagnetism. 相似文献
79.
In order to solve linear programs with a large number of constraints, constraint generation techniques are often used. In
these algorithms, a relaxation of the formulation containing only a subset of the constraints is first solved. Then a separation
procedure is called which adds to the relaxation any inequality of the formulation that is violated by the current solution.
The process is iterated until no violated inequality can be found. In this paper, we present a separation procedure that uses
several points to generate violated constraints. The complexity of this separation procedure and of some related problems
is studied. Also, preliminary computational results about the advantages of using multiple-points separation procedures over
traditional separation procedures are given for random linear programs and survivable network design. They illustrate that,
for some specific families of linear programs, multiple-points separation can be computationally effective. 相似文献
80.
Castro EV Novoselov KS Morozov SV Peres NM dos Santos JM Nilsson J Guinea F Geim AK Neto AH 《Physical review letters》2007,99(21):216802
We demonstrate that the electronic gap of a graphene bilayer can be controlled externally by applying a gate bias. From the magnetotransport data (Shubnikov-de Haas measurements of the cyclotron mass), and using a tight-binding model, we extract the value of the gap as a function of the electronic density. We show that the gap can be changed from zero to midinfrared energies by using fields of less, approximately < 1 V/nm, below the electric breakdown of SiO2. The opening of a gap is clearly seen in the quantum Hall regime. 相似文献