全文获取类型
收费全文 | 710篇 |
免费 | 25篇 |
国内免费 | 2篇 |
专业分类
化学 | 380篇 |
晶体学 | 7篇 |
力学 | 10篇 |
数学 | 86篇 |
物理学 | 254篇 |
出版年
2023年 | 2篇 |
2022年 | 20篇 |
2021年 | 11篇 |
2020年 | 11篇 |
2019年 | 15篇 |
2018年 | 20篇 |
2017年 | 13篇 |
2016年 | 32篇 |
2015年 | 15篇 |
2014年 | 29篇 |
2013年 | 53篇 |
2012年 | 50篇 |
2011年 | 46篇 |
2010年 | 26篇 |
2009年 | 32篇 |
2008年 | 36篇 |
2007年 | 35篇 |
2006年 | 29篇 |
2005年 | 35篇 |
2004年 | 17篇 |
2003年 | 16篇 |
2002年 | 19篇 |
2001年 | 26篇 |
2000年 | 21篇 |
1999年 | 12篇 |
1998年 | 12篇 |
1997年 | 9篇 |
1996年 | 14篇 |
1995年 | 3篇 |
1994年 | 17篇 |
1993年 | 7篇 |
1992年 | 7篇 |
1991年 | 7篇 |
1990年 | 5篇 |
1989年 | 4篇 |
1988年 | 2篇 |
1987年 | 1篇 |
1986年 | 4篇 |
1985年 | 2篇 |
1984年 | 4篇 |
1983年 | 2篇 |
1982年 | 3篇 |
1981年 | 1篇 |
1980年 | 2篇 |
1979年 | 2篇 |
1978年 | 2篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1974年 | 2篇 |
1955年 | 2篇 |
排序方式: 共有737条查询结果,搜索用时 15 毫秒
61.
62.
Gian Paulo G. Freschi Carolina D. Freschi José A. Gomes Neto 《Mikrochimica acta》2008,161(1-2):129-135
Different kinds of modifiers and coatings on the integrated platform of transversely heated graphite atomizer (THGA) have
been tested for the simultaneous determination of two group of elements: the first, the more volatile, formed by arsenic,
bismuth, lead, antimony and selenium; the second, the less volatile, formed by cobalt, chromium, cupper, iron and manganese
in milk by electrothermal atomic absorption spectrometry. Different Rh-modifiers were studied, such as Rh-coated platforms
(Rh), carbide plus rhodium coated platforms (W-Rh, Zr-Rh), carbide-coated platforms (W and Zr) with co-injection of RhCl3, solutions and uncoated platforms with injection of solutions of Pd(NO3)2, Mg(NO3)2, and RhCl3. Milk samples were diluted 1:10 in 1.0% HNO3 and injected into the tube. The mass of modifier deposited and co-injected in the tube and the use of end capped tubes were
also evaluated in order to improve the electrothermal behavior of analytes. Integrated platform pretreated with W plus co-injection
RhCl3 for first group and pretreated with W-Rh for second group were elected. For 20 μL injected samples the analytical curves
in the 5.0–20.0 μg L−1 concentration range have good linear correlation coefficients (r > 0.998). Relative standard deviations (n = 12) are <6% and the calculated characteristic masses are between 5 pg and 62 pg.
Correspondence: Gian Paulo G. Freschi, Faculdade de Ciências Exatas e Tecnologia, Universidade Federal da Grande Dourados,
PO Box 332, 79.804-970, Dourados-MS, Brazil; Instituto de Química, Universidade Estadual Paulista, PO Box 355, 14801-970 Araraquara-SP,
Brazil 相似文献
63.
We consider the harmonic and anharmonic chains of oscillators with self-consistent stochastic reservoirs and derive an integral
representation (à la Feynman-Kac) for the correlations, in particular, for the heat flow. For the harmonic chain, we give
a new proof that its thermal conductivity is finite in the steady state. Based on this integral representation for the correlations
and a perturbative analysis, the approach is quite general and can be extended to more intricate systems.
__________
Translated from Teoreticheskaya i Matematicheskaya Fizika, Vol. 156, No. 1, pp. 138–146, July, 2008. 相似文献
64.
65.
Alex Virgilio Renata Stabile Amais Daniela Schiavo José Anchieta Gomes Neto Joaquim de Araújo Nóbrega 《Analytical letters》2017,50(5):842-852
A procedure for the determination of As, Cd, Cr, Ni, Pb, and V in phytotherapy medicines by inductively coupled plasma–tandem mass spectrometry is reported. The use of tandem mass spectrometry with oxygen into an octopole reaction system at various gas flow rates and the combination of on-mass and mass-shift modes was evaluated. Cadmium, Cr, Ni, and Pb were determined as free atomic ions while As and V were determined as the oxides AsO+ and VO+ in the same run. Samples were prepared by microwave-assisted digestion with dilute nitric acid and hydrogen peroxide. Two plant-certified reference materials (apple leaves and tomato leaves) were used to check the accuracy. For tandem mass spectrometry with 0.5?mL min?1 O2, recoveries in the 85–113% were typically obtained and no statistical differences were observed at the 95% confidence level (t-test) in comparison with the certified values. Using these conditions, the limits of detection for the method were 0.01, 0.0002, 0.008, 0.008, 0.003, and 0.002?µg g?1 for As, Cd, Cr, Ni, Pb, and V, respectively. The procedure was used for the analysis of four phytotherapic drugs and the determined concentrations were up to 0.168?µg g?1 As, 0.03?µg g?1 Cd, 0.82?µg g?1 Cr, 1.18?µg g?1 Ni, 0.52?µg g?1 Pb, and 2.4?µg g?1 V with average precision values of 8% as the relative standard deviation. The found concentrations were compared with limits proposed in official guidelines and, in most cases, the values were below the maximum limits allowed. 相似文献
66.
Luisa Célia Melo Djenaine De Souza Pedro de Lima‐Neto Adriana Nunes Correia 《Electroanalysis》2010,22(21):2502-2510
The highly boron‐doped diamond electrode (HBDD) combined with square wave voltammetry (SWV) was used in the development of an analytical procedure for diquat determination in potato and sugar cane samples and lemon, orange, tangerine and pineapple juices. Preliminary experiments realised in a medium of 0.05 mol L?1 Na2B4O7 showed the presence of two voltammetric peaks around ?0.6 V and around ?1.0 V vs. Ag/AgCl/Cl? 3.0 mol L?1, where the first peak could be successfully used for analytical proposes due the facility in the electrode surface renovation. After the experimental and voltammetric optimisation, the calculated detection and quantification limits were 1.6×10?10 mol L?1 and 5.3×10?10 mol L?1 (0.057 µg L?1 and 0.192 µg L?1, respectively), which are lower than the maximum residue limit established for fresh food samples by the Brazilian Sanitary Vigilance Agency. The proposed methodology was used to determine diquat residues in potato and sugar cane samples and lemon, orange, tangerine and pineapple juices and the calculated recovery efficiencies indicated that the proposed procedure presents higher robustness, stability and sensitivity, good reproducibility, and is very adequate for diquat determination in complex samples. 相似文献
67.
Jorge Ananias Neto 《International Journal of Theoretical Physics》2011,50(11):3552-3559
In this paper, by using the holographic principle, a modified equipartition theorem where we assume that below a critical
temperature the energy is not equally divided on all bits, and the Unruh temperature, we derive MOND theory and a modified
Friedmann equation compatible with MOND theory. Furthermore, we rederive a modified Newton’s law of gravitation by employing
an adequate redefinition of the numbers of bits. 相似文献
68.
We calculate the magnetic and quasiparticle excitation spectra of an itinerant J(1)-J(2) model for iron-pnictide superconductors. In addition to an acoustic spin-wave branch, the magnetic spectrum has a second, optical branch, resulting from the coupled four-sublattice magnetic structure. The spin-wave velocity has also a planar directional anisotropy, due to the collinear or striped antiferromagnetism. Within the magnetically ordered phase, the quasiparticle spectrum is composed of two Dirac cones, resulting from the folding of the magnetic Brillouin zone. We discuss the relevance of our findings to the understanding of both neutron scattering and photoemission spectroscopy results for SrFe(2)As(2). 相似文献
69.
The present work offers new equations for phase evaluation in measurements. Several phase shifting equations with an arbitrary but constant phase shift between captured intensity signs are proposed. The equations are similarly derived as the so-called Carré equation. The idea is to develop a generalization of Carré equation that is not restricted to four images. Errors and random noise in the images cannot be eliminated, but the uncertainty due to their effects can be reduced by increasing the number of observations. An experimental analysis of the mistakes of the technique was made, as well as a detailed analysis of mistakes of the measurement. The advantages of the proposed equation are its precision in the measures taken, speed of processing and the immunity to noise in signs and images. 相似文献
70.
Batalioto F Martins OG Duarte AR Figueiredo Neto AM 《The European physical journal. E, Soft matter》2011,34(1):10
In this work we investigate the influence of the adsorption of ions on the impedance spectroscopy of an electrolytic cell.
We consider that the positive and negative ions present in a dielectric liquid are adsorbed in the electrode surfaces with
different adsorption energies. This difference in adsorption energies causes an additional plateaux in the limit of the low-frequency
range of the real part of the impedance Z . In the same frequency range, a second minimum in the imaginary part of Z is predicted. The theory is illustrated with measurements of the impedance of an electrolytic solution in the frequency range
from 10-2Hz to 1KHz. A comparison between the present model and others from the literature to describe the experimental results is
also made. 相似文献