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101.
Nattascha Kyaw Rafael Fonseca de Mesquita Etel Kameda João Crisósthomo de Queiroz Neto Marta Antunes Pereira Langone Maria Alice Zarur Coelho 《Applied biochemistry and biotechnology》2010,161(1-8):171-180
Drilling fluid has many functions, such as carry cuttings from the hole permitting their separation at the surface, cool and clean the bit, reduce friction between the drill pipe and wellbore, maintain the stability of the wellbore, and prevent the inflow of fluids from the wellbore and form a thin, low-permeable filter cake. Filter cake removal is an important step concerning both production and injection in wells, mainly concerning horizontal completion. The drilling fluids are typically comprised of starch, the most important component of the filter cake. A common approach to remove this filter cake is the use of acid solutions. However, these are non-specific reactants. A possible alternative is the use of enzymatic preparations, like amylases, that are able to hydrolyze starch. Wells usually operate in drastic conditions for enzymatic preparations, such as high temperature, high salt concentration, and high pressure. Thus, the main objective of this work was to characterize four enzymatic preparations for filter cake removal under open hole conditions. The results showed that high salt concentrations (204,000 ppm NaCl) in completion fluid decreased amylolytic activity. All enzymatic preparations were able to catalyze starch hydrolysis at all temperatures tested (30, 65, 80, and 95 °C). An increase of amylolytic activity was observed with the increase of pressure (100, 500 and 1,000 psi) for one commercial amylase. 相似文献
102.
We generalize Frobenius singular theorem due to Malgrange, for a large class of codimension one holomorphic foliations on
singular analytic subsets of ℂ
N
.
This research was partially supported by Pronex. 相似文献
103.
Petr Ya. Ekel Marden Menezes Fernando H. Schuffner Neto 《Nonlinear Analysis: Hybrid Systems》2007,1(4):527-536
This paper presents results of research into the use of the Bellman–Zadeh approach to decision making in a fuzzy environment for solving multicriteria optimization problems. Its application conforms to the principle of guaranteed result and provides constructive lines in obtaining harmonious solutions on the basis of analyzing associated maxmin problems. The use of the Bellman–Zadeh approach has served as a basis for solving a problem of multicriteria allocation of resources (or their shortages) and developing a corresponding adaptive interactive decision making system (AIDMS1). AIDMS1 includes procedures for considering linguistic variables to reflect conditions that are difficult to formalize as well as procedures for constructing and correcting vectors of importance factors for goals. The use of these procedures permits one to realize an adaptive approach to processing information of a decision maker to provide successive improvment in solution quality. The results of the paper are universally applicable and are already being used to solve power engineering problems. It is illustrated by considering problems of multicriteria power and energy shortage allocation and multicriteria power system operation. 相似文献
104.
M.A. da Nbrega J.M. S F.H.R. Bezerra J.C. Hadler Neto P.J. Iunes S. Guedes C.A. Tello Saenz P.C. Hackspacher F.P. Lima-Filho 《Radiation measurements》2005,39(6):627-633
An apatite fission track study of crystalline rocks underlying sedimentary basins in northeastern Brazil indicate that crustal blocks that occur on opposite sides of a geological fault experienced different thermal histories. Samples collected on the West block yielded corrected fission-track ages from 140 to 375 Ma, whereas samples collected on the East block yielded ages between 90 and 125 Ma. The thermal models suggest that each block experienced two cooling events separated by a heating event at different times. We concluded that the West block moved downward relative to the East block ca. 140 Ma ago, when sediments eroded from the East side were deposited on the West side. This process represents the early stage of sedimentary basin formation and the opening of the South Atlantic Ocean in the region. Downward and upward movements related to heating and cooling events of these crustal blocks at different periods until recent times are proposed. 相似文献
105.
F. Guinea A. H. Castro Neto N. M.R. Peres 《The European physical journal. Special topics》2007,148(1):117-125
We discuss the excitation spectrum, electronic susceptibilities,
and possible electronic instabilities in graphene and graphene stacks. The
corrections due interactions of Landau levels in graphene are analyzed. At
low dopings, and for
sufficiently low couplings, single layer graphene is stable against
ferromagnetism. On the other hand, a graphene bilayer, and
infinite graphite, are unstable towards ferromagnetism and
antiferromagnetism. 相似文献
106.
In order to solve linear programs with a large number of constraints, constraint generation techniques are often used. In
these algorithms, a relaxation of the formulation containing only a subset of the constraints is first solved. Then a separation
procedure is called which adds to the relaxation any inequality of the formulation that is violated by the current solution.
The process is iterated until no violated inequality can be found. In this paper, we present a separation procedure that uses
several points to generate violated constraints. The complexity of this separation procedure and of some related problems
is studied. Also, preliminary computational results about the advantages of using multiple-points separation procedures over
traditional separation procedures are given for random linear programs and survivable network design. They illustrate that,
for some specific families of linear programs, multiple-points separation can be computationally effective. 相似文献
107.
Castro EV Novoselov KS Morozov SV Peres NM dos Santos JM Nilsson J Guinea F Geim AK Neto AH 《Physical review letters》2007,99(21):216802
We demonstrate that the electronic gap of a graphene bilayer can be controlled externally by applying a gate bias. From the magnetotransport data (Shubnikov-de Haas measurements of the cyclotron mass), and using a tight-binding model, we extract the value of the gap as a function of the electronic density. We show that the gap can be changed from zero to midinfrared energies by using fields of less, approximately < 1 V/nm, below the electric breakdown of SiO2. The opening of a gap is clearly seen in the quantum Hall regime. 相似文献
108.
F.G.M. Cunha A.W.M. Pinto P.R. Oliveira J.X. da Cruz Neto 《Applied mathematics and computation》2011,218(8):4523-4532
We obtain a class of primal affine scaling algorithms which generalize some known algorithms. This class, depending on a r-parameter, is constructed through a family of metrics generated by −r power, r ? 1, of the diagonal iterate vector matrix. We prove the so-called weak convergence of the primal class for nondegenerate linearly constrained convex programming. We observe the computational performance of the class of primal affine scaling algorithms, accomplishing tests with linear programs from the NETLIB library and with some quadratic programming problems described in the Maros and Mészáros repository. 相似文献
109.
Machado AE Gomes WR Araújo DM Miglio HS Ueno LT De Paula R Cavaleiro JA Barbosa Neto NM 《Molecules (Basel, Switzerland)》2011,16(7):5807-5821
An imidazolium tetrasubstituted cationic porphyrin derivative (the free base and its Zn(II) complex) with five-membered heterocyclic groups in the meso-positions were synthesized using microwave irradiation, and the compounds obtained characterized by (1)H-NMR and mass spectrometry. We observed that under microwave irradiation the yield is similar to when the synthesis is performed under conventional heating, however, the time required to prepare the porphyrins decreases enormously. In order to investigate the electronic state of these compounds, we employed UV-Vis and fluorescence spectroscopy combined with quantum chemical calculations. The results reveal the presence, in both compounds, of a large number of electronic states involving the association between the Soret and a blue-shifted band. The Soret band in both compounds also shows a considerable solvent dependence. As for emission, these compounds present low quantum yield at room temperature and no solvent influence on the fluorescence spectra was observed. 相似文献
110.
A contracted basis set of triple zeta (TZ) valence quality for the atoms from K to Kr was constructed from fully-optimized Gaussian basis sets generated in this work. Gaussian polarization functions (d, f, and g symmetries), which were optimized at the second-order Mφller–Plesset level, were added to the TZ set. This extends earlier work on segmented contracted TZ basis set for atoms H-Ar. This set along with the BP86 non-hybrid and B3LYP hybrid functionals were used to calculate geometric parameters, dissociation energy, harmonic vibrational frequency, and electric dipole moment of a sample of molecules and, then, comparison with results obtained with other basis sets and with experimental data reported in the literature is done. CCSD(T) atomic excitation energies and bond lengths, dissociation energies, and harmonic vibrational frequencies of some diatomics were also evaluated. Using density functional theory and gauge-including atomic orbitals, 57Fe and 77Se nuclear magnetic resonance chemical shifts in Fe(C5H5)2, H2Se, (CH3)SeH, CSe2, SeCO, H2CSe, and SeF6 were calculated. Comparison with theoretical and experimental values previously published in the literature was done. It is verified that in general these results give good agreement with experimental and benchmark values. 相似文献