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51.
Maher I. Nessim Magda M. Osman Dina A. Ismail 《Journal of Dispersion Science and Technology》2018,39(7):1047-1055
Three cationic gemini surface active compounds of the type (1r,4r)-1,4-dialkyl-1,4-dimethy-l-piperazine-1,4-diium bromide (Ia, Ib, and Ic), were synthesized. They were characterized using elemental analysis and 1H-NMR spectra. Their surface-active properties were measured in aqueous solutions with different concentrations at different temperatures (25, 40, and 55°C). Various surface measurements of these gemini surfactants, (compared to the conventional one, 1-Dodecyl-1-methylpiperidinium bromide (a)) were estimated, specifically critical micelle concentration (CMC), effectiveness (πCMC), efficiency (PC20) as well as maximum surface excess (Γmax) and minimum surface area (Amin). The measurements of the gemini compounds gave low CMC, high efficiency in reducing the surface tension, and intense adsorption at air/water interface. These surfactants have lower Krafft points and thus better solubility. Thermodynamic data, free energy, entropy, and enthalpy changes (ΔG°, ΔS°, and ΔH°) for micellization at the air/water interface and also for adsorption in the bulk of surface-active solutions were calculated. 相似文献
52.
John Erik Fornæss Nessim Sibony Erlend Fornæss Wold 《Mathematische Zeitschrift》2011,269(1-2):495-520
In this paper, we construct various examples of holomorphic laminations, with leaves of dimension d, and we study some of their dynamical properties. In particular we study existence and uniqueness of positive closed currents. We construct minimal laminations with infinitely many mutually singular closed currents and no non-closed harmonic current. We also consider embeddings to projective space. 相似文献