Synthesis of bis(1,5-disubstituted tetrazoles) via double four component Azido-Ugi reaction

A double four component Azido-Ugi reaction of isocyanide, TMSN₃, aldehyde, and 4,4′-sulfonyldianiline with two amine functional groups in MeOH at 65°C has been described. The synthesis of pharmacologically and structurally interesting compounds with two 1,5-disubstituted tetrazole rings via a reaction from available and inexpensive reagents under a convenient process and mild reaction conditions has been reported. Modifications in the structure of the reaction product could be followed by varying the aldehyde or isocyanide component. The products are new and were well described by Mass, ¹H NMR, and ¹³C NMR spectral studies.     

Hydrodynamic analysis of a heat exchanger with crosscut twisted tapes and filled with thermal oil-based SWCNT nanofluid: applying ANN for prediction of objective parameters

Journal of Thermal Analysis and Calorimetry - Present study investigates hydrodynamic analysis of heat exchanger with crosscut twisted tapes and filled with thermal oil-based SWCNT nanofluid (NF)....     

Energy and mass transport of Casson nanofluid flow over a slanted permeable inclined surface

In this problem, examination of Casson nanofluid flow over nonlinear slanted extending sheet with chemical reaction and heat generation/absorption influences are under thought. Nanofluid exhibits in this examination is established on Buongiorno model. The governing nonlinear PDE’s are reduced to nonlinear ODE’s by employing suitable transformations. The Keller-box numerical technique is considered for simulation of this research. The influence of chemical reaction and nonlinear parameter on concentration and velocity distribution is analyzed. The recovered results exhibit that the impact of inclination and Casson factor reduced liquid velocity. While energy and mass transport rates are increased against inclination factor. Numerical and graphical outcomes are additionally exhibited in tables and graphs.

     

Pore formation in phospholipid bilayers by branched-chain pyrogallol[4]arenes

Pyrogallolarenes are tetrameric macrocycles that form from 1,2,3-trihydroxybenzene and aldehydes under acidic conditions. When 2-ethylbutanal or 2-propylpentanal was so treated, the branched-chain pyrogallolarenes crystallized as nanotubes or bilayers, respectively. When the behavior of each compound was assessed by using the planar bilayer conductance method, pore formation was observed. The properties of the pores were significantly different from each other, probably reflecting different types of pore organization within the membrane.     

An efficient and provably secure three-party password-based authenticated key exchange protocol based on Chebyshev chaotic maps

Three-party password-based authenticated key exchange (3PAKE) protocols allow two clients to establish a secure session key through a server over an insecure channel. Recently, the 3PAKE protocols have been developed based on Chebyshev chaotic maps, in which the clients utilize smart cards to login into the server and employ server’s public key to ensure the identity of the server or symmetric cryptosystems to encrypt the messages. However, this paper describes an efficient chaos-based 3PAKE protocol without smart cards, which requires neither server’s public key nor symmetric cryptosystems. The security of the proposed 3PAKE protocol is proved in the random oracle model using the chaos-based decisional Diffie–Hellman assumption. In comparison with the existing chaos-based 3PAKE protocols, our protocol individually provides better performance in terms of communication, computation, and security aspects, and is supported by the formal proof in the random oracle model.     

Metallized nanotube polymer composites via supercritical fluid impregnation

Although many metal decorated nanotubes and nanowires appear in the literature, well‐dispersed metal decorated nanotube polymer composites have rarely been reported because of the excessive density mismatch between the decorated nanotubes and polymer matrix. Here, we report a novel method to prepare well‐dispersed, highly functional, metallized nanotube polymer composites (MNPCs) that possess remarkably improved electrical conductivity and mechanical toughness. The MNPCs are prepared by supercritical fluid impregnation of an organometal compound into a premade well‐dispersed single wall carbon nanotube‐polymer composite film. The infused precursor preferentially migrates towards the nanotubes to undergo spontaneous reduction and form nanometer‐scale metal particles leading to an increase in the conductivity of the MNPC films. The environmentally friendly supercritical fluid impregnation process significantly improved the toughness of the composite films, regardless of the presence of metal. Additional functionality can be imparted into the resulting MNPC by infusing other precursors such as magnetic and catalytic metal compounds. © 2011 Wiley Periodicals, Inc.* J Polym Sci Part B: Polym Phys, 2012     

Kinetic study of in situ normal and AGET atom transfer radical copolymerization of n–butyl acrylate and styrene: Effect of nanoclay loading and catalyst concentration

The effect of clay nanolayers and catalyst concentration on the kinetics of atom transfer radical copolymerization of styrene and butyl acrylate initiated by activators generated by electron transfer (AGET initiation system) or an alkyl halide (normal initiation system) was studied. Monomer conversion was studied by attenuated total reflection–Fourier transform infrared spectroscopy, and also proton nuclear magnetic resonance (¹H NMR) spectroscopy was utilized to evaluate the heterogeneity in the composition of poly(styrene‐co‐butyl acrylate) chains. A decrease in the copolymerization rate of styrene and butyl acrylate in the presence of clay platelets was observed since clay layers confine the accessibility of monomer and growing radical chains. Considering the linear first‐order kinetics of the polymerization, successful AGET and normal atom transfer radical polymerization (ATRP) in the presence of clay nanolayers were carried out. Consequently, poly(styrene‐co‐butyl acrylate) chains with narrow molecular weight distribution and low polydispersity indices (1.13–1.15) were obtained. The linearity of ln([M]₀/[M]) versus time and molecular weight distribution against conversion plots indicates that the proportion of propagating radicals is almost constant during the polymerization, which is the result of insignificant contribution of termination and transfer reactions. Controlled synthesis of poly(styrene‐co‐butyl acrylate)/clay is implemented with the diminishing catalyst concentration of copper(I) bromide/N,N,N′,N′′,N′′‐pentamethyl diethylene triamine without affecting the copolymerization rate of normal ATRP. © 2012 Wiley Periodicals, Inc. Int J Chem Kinet 44: 789–799, 2012     

Synthesis of pyrazol-quinazolinones and 2,3-dihydroquinazolin-4(1H)-ones using CoAl2O4 nanoparticles as heterogeneous catalyst

Journal of the Iranian Chemical Society - The preparation and characterization of cobalt aluminate (CoAl2O4) magnetic nanoparticles and its application as a catalyst for the synthesis of a novel...     

Minimization of Total Absolute Flow Time Deviation in Single and Multiple Machine Scheduling

In this note, single machine scheduling and minimizing absolute flow time deviation (TAFD) are considered. The relationship between this problem and the mean absolute deviation of job completion times about a common due date (MAD) is discussed. Based on the MAD problem optimal solutions of the TAFD problem are given. Furthermore, the generalization of the problem to the multiple machine case is discussed and an efficient algorithm for generating many optimal solutions of the problem, in the multi-machine case, is given.