Green and Cost Effective Synthesis of Fluorescent Carbon Quantum Dots for Dopamine Detection

Carbon quantum dots (CQDs) due to its high fluorescent output is evolving as novel sensing material and is considered as future building blocks for nano sensing devices. Hence, in this investigation we report microwave assisted preparation and multi sensing application of CQDs. The microwave derived CQDs are characterized by Dynamic Light Scattering (DLS) experiment and Fourier Infrared spectra (FTIR) to investigate the size distribution and chemical purity respectively. Fluorescent emission spectra recorded at varying pH shows varying fluorescence emission intensities. Further, emission spectra recorded at different temperatures shows that fluorescence emission of CQDs greatly depends on temperature. Therefore, we demonstrate the pH and temperature sensing characteristics of CQDs by fluorescence quenching behaviour. In addition, the interaction and sensing behaviour of CQDs for dopamine is also presented in this work with a detection limit of 0.2 mM. The steady state and time-resolved methods have been employed in fluorescence quenching methods for sensing dopamine through CQDs at room temperature. The bimolecular quenching rate constants for different concentration have been measured. The interaction between CQDs and dopamine indicates fluorescence quenching method is an elegant process for detecting dopamine through CQDs.     

Unidirectionally Emitting Quantum Cascade Microcavity Lasers with Patterned Contacts

We investigate unidirectionally emitting quantum cascade microcavity lasers with semicircle-patterned top contacts. We employ novel patterned top contacts while fabricating notched ellipse-shaped cavity lasers. We study experimentally the microcavity-structure-based quantum cascade (QC) laser material with a long infrared wavelength of ~10 μm. Then we characterize microcavity lasers with patterned contacts and compare them with nonpatterned ones and observe a lower operating injection threshold current as a consequence of this relatively straightforward technique, with the unidirectional emission feature being kept. We obtain a maximum light output peak power of 16 mW with unidirectional emission at a far-field divergence angle of ~7° at a full width of half maximum, while the patterned device shows low threshold even in the microcavity laser with a size of 150 μm. Furthermore, we also carry out a reliability test of the QC microcavity lasers with semicircle-patterned top contacts, and the testing results show no sudden failure or severe light-output-power drop during an operating time of thousand hours.     

Chern–Simons,Wess–Zumino and other cocycles from Kashiwara–Vergne and associators

Descent equations play an important role in the theory of characteristic classes and find applications in theoretical physics, e.g., in the Chern–Simons field theory and in the theory of anomalies. The second Chern class (the first Pontrjagin class) is defined as \(p= \langle F, F\rangle \) where F is the curvature 2-form and \(\langle \cdot , \cdot \rangle \) is an invariant scalar product on the corresponding Lie algebra \(\mathfrak g\). The descent for p gives rise to an element \(\omega =\omega _3+\omega _2+\omega _1+\omega _0\) of mixed degree. The 3-form part \(\omega _3\) is the Chern–Simons form. The 2-form part \(\omega _2\) is known as the Wess–Zumino action in physics. The 1-form component \(\omega _1\) is related to the canonical central extension of the loop group LG. In this paper, we give a new interpretation of the low degree components \(\omega _1\) and \(\omega _0\). Our main tool is the universal differential calculus on free Lie algebras due to Kontsevich. We establish a correspondence between solutions of the first Kashiwara–Vergne equation in Lie theory and universal solutions of the descent equation for the second Chern class p. In more detail, we define a 1-cocycle C which maps automorphisms of the free Lie algebra to one forms. A solution of the Kashiwara–Vergne equation F is mapped to \(\omega _1=C(F)\). Furthermore, the component \(\omega _0\) is related to the associator \(\Phi \) corresponding to F. It is surprising that while F and \(\Phi \) satisfy the highly nonlinear twist and pentagon equations, the elements \(\omega _1\) and \(\omega _0\) solve the linear descent equation.     

Conformal Galilei algebras,symmetric polynomials and singular vectors

We classify and explicitly describe homomorphisms of Verma modules for conformal Galilei algebras \({\mathfrak {cga}}_\ell (d,\mathbb {C})\) with \(d=1\) for any integer value \(\ell \in {\mathbb {N}}\). The homomorphisms are uniquely determined by singular vectors as solutions of certain differential operators of flag type and identified with specific polynomials arising as coefficients in the expansion of a parametric family of symmetric polynomials into power sum symmetric polynomials.     

Modularity of logarithmic parafermion vertex algebras

The parafermionic cosets \(\mathsf {C}_{k} = {\text {Com}} ( \mathsf {H} , \mathsf {L}_{k}(\mathfrak {sl}_{2}) )\) are studied for negative admissible levels k, as are certain infinite-order simple current extensions \(\mathsf {B}_{k}\) of \(\mathsf {C}_{k}\). Under the assumption that the tensor theory considerations of Huang, Lepowsky and Zhang apply to \(\mathsf {C}_{k}\), irreducible \(\mathsf {C}_{k}\)- and \(\mathsf {B}_{k}\)-modules are obtained from those of \(\mathsf {L}_{k}(\mathfrak {sl}_{2})\). Assuming the validity of a certain Verlinde-type formula likewise gives the Grothendieck fusion rules of these irreducible modules. Notably, there are only finitely many irreducible \(\mathsf {B}_{k}\)-modules. The irreducible \(\mathsf {C}_{k}\)- and \(\mathsf {B}_{k}\)-characters are computed and the latter are shown, when supplemented by pseudotraces, to carry a finite-dimensional representation of the modular group. The natural conjecture then is that the \(\mathsf {B}_{k}\) are \(C_2\)-cofinite vertex operator algebras.     

Loss of Ergodicity in the Transition from Annealed to Quenched Disorder in a Finite Kinetic Ising Model

We consider a kinetic Ising model which represents a generic agent-based model for various types of socio-economic systems. We study the case of a finite (and not necessarily large) number of agents N as well as the asymptotic case when the number of agents tends to infinity. The main ingredient are individual decision thresholds which are either fixed over time (corresponding to quenched disorder in the Ising model, leading to nonlinear deterministic dynamics which are generically non-ergodic) or which may change randomly over time (corresponding to annealed disorder, leading to ergodic dynamics). We address the question how increasing the strength of annealed disorder relative to quenched disorder drives the system from non-ergodic behavior to ergodicity. Mathematically rigorous analysis provides an explicit and detailed picture for arbitrary realizations of the quenched initial thresholds, revealing an intriguing “jumpy” transition from non-ergodicity with many absorbing sets to ergodicity. For large N we find a critical strength of annealed randomness, above which the system becomes asymptotically ergodic. Our theoretical results suggests how to drive a system from an undesired socio-economic equilibrium (e.g. high level of corruption) to a desirable one (low level of corruption).     

Quantum Diffusion and Eigenfunction Delocalization in a Random Band Matrix Model

We consider Hermitian and symmetric random band matrices H in d ≥ 1 dimensions. The matrix elements H _xy , indexed by \({x,y \in \Lambda \subset \mathbb{Z}^d}\), are independent, uniformly distributed random variables if \({\lvert{x-y}\rvert}\) is less than the band width W, and zero otherwise. We prove that the time evolution of a quantum particle subject to the Hamiltonian H is diffusive on time scales \({t\ll W^{d/3}}\). We also show that the localization length of the eigenvectors of H is larger than a factor W ^d/6 times the band width. All results are uniform in the size \({\lvert{\Lambda}\rvert}\) of the matrix.     

Cosmological Models with Variable <Emphasis Type="Italic">G</Emphasis> in <Emphasis Type="Italic">C</Emphasis>-Field Cosmology

Cosmological models with variable G in C-field cosmology for barotropic fluid distribution in FRW space-time are investigated. To get the deterministic model of the universe, we have assumed that G=R ⁿ where R is the scale factor and n the constant. To obtain the results in terms of cosmic time t, we have assumed n=−1. We find that for n=−1, Creation field (C) and spatial volume increase with time, G and ρ (matter density) decreases with time, the model represent accelerating universe. Thus inflationary scenario exists in the model. The model is also free from horizon. The results so obtained match with the astronomical observations.     

Blowup Criterion for Viscous Baratropic Flows with Vacuum States

We prove that the maximum norm of the deformation tensor of velocity gradients controls the possible breakdown of smooth(strong) solutions for the 3-dimensional (3D) barotropic compressible Navier-Stokes equations. More precisely, if a solution of the 3D barotropic compressible Navier-Stokes equations is initially regular and loses its regularity at some later time, then the loss of regularity implies the growth without bound of the deformation tensor as the critical time approaches. Our result is the same as Ponce’s criterion for 3-dimensional incompressible Euler equations (Ponce in Commun Math Phys 98:349–353, 1985). In addition, initial vacuum states are allowed in our cases.     

On Random Field Induced Ordering in the Classical <Emphasis Type="Italic">XY</Emphasis> Model

Consider the classical XY model in a weak random external field pointing along the Y axis with strength ε. We study the behavior of this model as the range of the interaction is varied. We prove that in any dimension d≥2 and for all ε sufficiently small, there is a range L=L(ε) so that whenever the inverse temperature β is larger than some β(ε), there is strong residual ordering along the X direction.