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271.
The novel 1,4-benzodiazepino[4,5-d][1,4]benzoxazepine ring system has been constructed via preformed benzoxazepine intermediates. Several derivatives have been prepared as potential anxiolytic agents.  相似文献   
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273.
Measurements of the appearance potential for the production of CF3+ in the photoionization of CF3Br are in sharp disagreement, contributing to controversy in the heat of formation of CF3+. We reexamine our previous work and add additional experiments, obtaining AP(CF3+/CF3Br) = 11.64 +/- 0.04 eV as the average of four measurements made under widely different conditions. This is higher by 0.08 eV than the value we reported previously. Our new value for Delta(f)H0 degrees (CF3+) is now 88.0 +/- 0.9 kcal mol(-1). We compare our method with other techniques.  相似文献   
274.
Quantum chemical calculations as well as crystallographic analyses show that the Ni(n) rings in the tiara Ni thiolates, [NiS2]n and [Ni(SR)2]n (n = 3-6), have highly symmetric polygonal structures. We find that such structural features primarily arise from the effective delocalization of the d-orbital electrons across the Ni(n) rings leading to bond length equalization and thereby aromaticity. We introduce the d-orbital aromaticity for the first time to explain the experimentally observed polygonal structures of these cyclic metal rings bridged by thiol linkages.  相似文献   
275.
The advent of Sonet and DWDM mesh-restorable networks which contain explicit reservations of spare capacity for restoration presents a new problem in topological network design. On the one hand, the routing of working flows wants a sparse tree-like graph for minimization of the classic fixed charge plus routing (FCR) costs. On the other hand, restorability requires a closed (bi-connected) and preferably high-degree topology for efficient sharing of spare capacity allocations (SCA) for restoration over non-simultaneous failure scenarios. These diametrically opposed considerations underlie the determination of an optimum physical facilities graph for a broadband network provider. Standalone instances of each constituent problem are NP-hard. The full problem of simultaneously optimizing mesh-restorable topology, routing, and sparing is therefore very difficult computationally. Following a comprehensive survey of prior work on topological design problems, we provide a {1–0} MIP formulation for the complete mesh-restorable design problem and also propose a novel three-stage heuristic. The heuristic is based on the hypothesis that the union set of edges obtained from separate FCR and SCA sub-problems constitutes an effective topology space within which to solve a restricted instance of the full problem. Where fully optimal reference solutions are obtainable the heuristic shows less than 8% gaps but runs in minutes as opposed to days. In other test cases the reference problem cannot be solved to optimality and we can only report that heuristic results obtained in minutes are not improved upon by CPLEX running the full problem for 6 to 18 hours. The computational behavior we observe gives insight for further work based on an appreciation of the problem as embodying unexpectedly difficult feasibility apects, as well as optimality aspects.  相似文献   
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277.
We present the generation and interaction dynamics of dispersion managed soliton in a dissipative cubic-quintic nonlinear optical fiber coupled with frequency-selective feedback. Analytically, perturbative variational method is used to obtain evolution equations for different soliton parameters that are subsequently solved to study the propagation characteristics of the dispersion managed dissipative solitons (DMDS). The DMDSs show breather like characteristics and are found to be robust against certain level of initial noise. Both the standard Gaussian and more generic super-Gaussian pulse profile are shown to yield stable DMDS. Interaction of two DMDSs of same phase may lead to a bound state. By varying the temporal separation and phase difference between the DMDSs the bound state can be switched between low to high speed regime.  相似文献   
278.
In this article, the closed form expressions for the transverse vibrations of a homogenous isotropic, thermally conducting, Kelvin–Voigt type viscothermoelastic thin beam, based on Euler– Bernoulli theory have been derived. The effects of relaxation times, thermomechanical coupling, surface conditions, and beam dimensions on energy dissipation induced by thermoelastic damping in MEMS (micro-electromechanical systems) resonators are investigated for beams under clamped and simply supported conditions. Analytical expressions for deflection, temperature change, frequency shifts, and thermoelastic damping in the beam have been derived. Some numerical results with the help of MATLAB programming software in case of Silicon Nitride have also been presented. The computer-simulated results in respect of damping factor and frequency shift have been presented graphically.  相似文献   
279.
Hexagonal (space group P63cm) form of YInO3 has been investigated under high pressure using synchrotron-based angle-dispersive X-ray diffraction and Raman scattering methods. Our experimental investigations suggest that it undergoes the phase transition to a new phase in the pressure range 12–15?GPa, while the ambient hexagonal phase is found to coexist with the new phase up to 29?GPa. DFT based calculations within the LDA approach on the hexagonal phase of YInO3 showed that the unit cell volume matches well with the experimentally obtained volume at ambient pressure. As the pressure increases, theoretically obtained values of unit cell volume of the hexagonal phase were found to be significantly lower than that of experimentally obtained values. This discrepancy has been corrected using LDA?+?UIn(4d) (Hubbard interaction parameter between Indium 4d electrons) method. We have proposed the high pressure phase of YInO3 to be orthorhombic with space group Pnma.  相似文献   
280.
A rapid extraction and cleanup method using selective fabric phase sorptive extraction combined with gas chromatography and mass spectrometry has been developed and validated for the determination of broad polarity spectrum emerging pollutants, ethyl paraben, butyl paraben, diethyl phthalate, dibutyl phthalate, lidocaine, prilocaine, triclosan, and bisphenol A in various aqueous samples. Some important parameters of fabric phase sorptive extraction such as extraction time, matrix pH, stirring speed, type and volume of desorption solvent were investigated and optimized. Calibration curves were obtained in the concentration range 0.05–500 ng/mL. Under the optimum conditions, the limits of detection were in the range 0.009 –0.021 ng/mL. This method was validated by analyzing the compounds in spiked aqueous samples at different levels with recoveries of 93 to 99% and relative standard deviations of <6%. The developed method was applied for the determination of the emerging contaminants in tap water, municipal water, ground water, sewage water, and sludge water samples. The results demonstrate that fabric phase sorptive extraction has great potential in the preconcentration of trace analytes in complex matrix.  相似文献   
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