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231.
A.K. Grover S.K. Dhar E.V. Sampathkumaran L.C. Gupta S.K. Malik 《Solid State Communications》1979,30(3):141-144
Susceptibility of Co2TAl (T Ti, Zr and Hf) and 59Co and 27Al Knight shifts have been measured down to the magnetic ordering temperature of these itinerant ferromagnets. The effective hyperfine fields per Bohr magneton at Co and Al nuclear sites have been derived and for Co these are in very good agreement with the spin echo results in ferromagnetic state of these alloys. The effective fields at Al site are small which is the reason that no spin echo signal due to Al could be observed. The sign of the field at Al site is accounted for in terms of an RKKY model of conduction electron polarization with appropriate preasymptotic correction. 相似文献
232.
A sub-solidus phase evolution study was done in CeO2-Sc2O3 and CeO2-Lu2O3 systems under slow-cooled conditions from 1400 °C. Long-range order probing of X-ray diffraction technique is utilized in conjunction with the ability of Raman spectroscopy to detect the changes in local co-ordination. Lu2O3 showed solubility of 30 mol% in CeO2, thus forming an anion deficient fluorite-type (F-type) solid solution, whereas Sc2O3 did not show any discernible solubility. A biphasic region (F+C) was unequivocally detected by Raman spectroscopy in Ce1−xLuxO2−x/2 (0.4?x?0.9) and in Ce1−xScxO2−x/2 (0.1?x?0.9) systems. Raman spectroscopy was valuable in studying these systems since oxygen vacancies are created on doping RE2O3 into ceria and Raman spectroscopy is very much sensitive to oxygen polarizability and local coordination. Back scattered images collected on representative compositions support the above-mentioned results. 相似文献
233.
Khatoon Sayyada Singh Neha Srivastava Neena Rawat Ajay K. S. Mehrotra Shanta 《平面色谱法杂志一现代薄层色谱法》2008,21(3):167-171
JPC – Journal of Planar Chromatography – Modern TLC - Terminalia species are widely used as important timber-yielding plants and are rich source of tannins and dyes. The stem bark of... 相似文献
234.
D. P. Singh R. Kumar M. Kamboj V. Grover K. Jain 《Russian Journal of Coordination Chemistry》2008,34(3):233-235
Novel series of complexes of the type [M(TML)X2], where TML is a tetradentate macrocyclic ligand; M = Co(II), Ni(II), Cu(II), Zn(II); X = Cl−, NO3−, CH3COO−, have been synthesized by template condensation of isatin and ethylenediamine in the presence of divalent metal salts in
a methanolic medium. The complexes have been characterized with the help of elemental analyses, conductance measurements,
molecular weight determination, magnetic measurements, NMR, infrared and far infrared spectral studies. The low value of molar
conductance indicates them to be nonelectrolytes. All the complexes are supposed to have distorted octahedral geometry.
The text was submitted by the authors in English. 相似文献
235.
236.
Madhuri Grover Tapan Behl Aayush Sehgal Sukhbir Singh Neelam Sharma Tarun Virmani Mahesh Rachamalla Abdullah Farasani Sridevi Chigurupati Amal M. Alsubayiel Shatha Ghazi Felemban Mohit Sanduja Simona Bungau 《Molecules (Basel, Switzerland)》2021,26(24)
The Curcuma longa plant is endowed with multiple traditional and therapeutic utilities and is here explored for its phytochemical constituents and cytotoxic potential. Turmeric rhizomes were extracted from three different solvents and screened for the presence of different phytochemical constituents, observation of which indicated that the polar solvents favoured extraction of greater versatile phytochemical constituents. These extracts were investigated for their cytotoxic potential by MTT (3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide) assay on three different of cell lines including SCC-29B (oral cancer cell line), DU-145 (prostate cancer cell line) and the Vero cell line (healthy cell line/non-cancerous cell line). This assay was performed by taking three extracts from isolated curcuminoids and a pure bioactive compound bisdemethoxycurcumin (BD). Bisdemethoxycurcumin was isolated from curcuminoids and purified by column and thin-layer chromatography, and its structural characterisation was performed with different spectroscopic techniques such as FTIR, NMR (1H Proton and 13C Carbon-NMR) and LC-MS. Amongst the extracts, the ethanolic extracts exhibited stronger cytotoxic potential against the oral cancer cell line (SCC-29B) with an IC50value of 11.27 μg/mL, and that this was too low of a cytotoxicity against the Vero cell line. Although, curcuminoids have also shown a comparable cytotoxic potential against SCC-29B (IC50 value 16.79 μg/mL), it was not as potent against the ethanolic extract, and it was even found to be cytotoxic against healthy cell lines at a very low dose. While considering the isolated compound, bisdemethoxycurcumin, it also possessed a cytotoxic potential against the prostate cancer cell line (DU-145) (IC50 value of 93.28 μg/mL), but was quite safe for the healthy cell line in comparison to doxorubicin. 相似文献
237.
238.
Rajendra Prasad Nandi Dr. Pagidi Sudhakar Dr. Neena K. Kalluvettukuzhy Prof. Pakkirisamy Thilagar 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(69):16306-16317
Herein, the design, synthesis, optical properties, and mechanofluorochromism characteristics of a series of conjugates having covalently linked triarylborane (TAB) and anil/boranil units (TAB-anil: 1 a – 3 a and TAB-boranil: 1 – 3 ) are reported. The electronic interactions between TAB and anil/boranil in 1 a – 3 a and 1 – 3 were fine-tuned by changing the boryl moiety's position on the phenyl spacer connecting the BMes2 (Mes=mesityl) and anil/boranil units. A boryl moiety at the meta position ( 1 a ) of the phenyl spacer stabilizes the enolic form (E-OH), whereas a boryl moiety at the para position ( 2 a and 3 a ) stabilizes the keto form (Z-NH) in the solid state. However, in solution 1 a , 2 a , and 3 a exhibit keto–enol tautomerism in both ground and excited states. Compounds 1 a – 3 a and 1 – 3 show red-shifted absorption compared with 4 a and 4 , which are devoid of TAB moieties, which indicate effective participation of an empty p orbital on the boron center in 1 a – 3 a and 1 – 3 . Compounds 1 and 2 showed fluorescence variations in response to external stimuli such as mechanical grinding. Long phosphorescence lifetimes of 18–46 ms were observed for compounds 1 – 3 . The observed optical properties of 1 a – 3 a and 1 – 3 are rationalized in the context of quantum mechanical calculations. 相似文献
239.
240.
Neena S. John Dr. Sam M. Stevens Osamu Terasaki Prof. Michael W. Anderson Prof. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2010,16(7):2220-2230
This paper sets out to try to determine some of the nanoscopic details of template action in zeolites. The problem has been addressed by monitoring the effects of competitive templating using, in particular, atomic force microscopy and high‐resolution scanning electron microscopy. Using these techniques, it is possible to determine the subtle crystal growth changes that occur as a result of altering the concentration of these competitive templating agents. This work concerns the two important intergrowth systems MFI–MEL and FAU–EMT. It was found that some organic templating agents provide much greater structure‐directing specificity. So much so in the case of the MFI–MEL system that a 2 mol % doping with the highly specific tetrapropylammonium cation drastically changes the fundamental growth processes. Furthermore, the effect of template crowding is shown to reduce specificity. This work shows how extensive frustrated intergrowth structures can still be accommodated within a nominal zeolite single crystal. 相似文献