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51.
Benzothiazepine, a prominent “drug prejudice core”, is a heterocyclic moiety of immense importance due to its presence in a wide range of bioactive compounds. They act as a primary “biolinker” in diverse synthetic routes to obtain bioactive molecules and serve as important templates in synthetic and medicinal chemistry. They are known to possess a plethora of pharmacological activities, which include Ca2+ channel blockers, CNS acting agents, anti-HIV, ACE inhibitors, antimicrobial, antifungal, anticancer. Their promising behaviour as drug molecules led the scientific community to develop novel, mild, green, and highly efficient synthetic routes for their synthesis. The conventional synthesis generally involved the condensation of chalcones with 2-aminothiophenol in the presence of acid/base with high-temperature heating, mostly resulting in poor yields or mixtures. However, recent trends are replacing these conditions with mild and green conditions through organocatalysis or other methodologies. In this review, an attempt has been made by authors to summarize (a) Recent developments in the synthetic strategies of 1,5-benzoathiazepines and its derivatives (b) Conventional methods for the synthesis of 1,5-benzothiazepines including progress in the green chemistry routes (c) Applications of various metals and organocatalysts to achieve the enantioselective synthesis of title compounds. 相似文献
52.
Tripathi Jai Prakash Jana Debaldev Vyshnavi Devi N. S. N. V. K. Tiwari Vandana Abbas Syed 《Nonlinear dynamics》2020,102(1):511-535
Nonlinear Dynamics - In this present study, we systematically explore the periodicity (almost periodic nature) of a dynamical system in time-varying environment, which portrays a special case of... 相似文献
53.
在303 K恒温条件下,以NaCl为电解质保持离子强度为0.16 mol.L-1,用pH滴定法研究了M(Ⅱ)-Dopa(多巴)二元配合物在0~60%(V/V)的丙二醇(PG)-水体系中的生成平衡。在PG-水体系中,Ca(Ⅱ)和Mg(Ⅱ)的典型配合物为MLH,ML2,ML2H和ML2H2,而Zn髤的典型配合物为ML,MLH,ML2,ML2H和ML2H2。根据静电和非静电力解释了稳定常数随介质的介电常数而变化的倾向。还讨论了在不同组成的丙二醇(PG)-水体系中配合物物种随pH值变化的情况。 相似文献
54.
Cecilia Devi Wilfred 《合成通讯》2013,43(22):2859-2867
A tandem oxidation reaction has been utilized to prepare ethyl (E)‐4,5‐dioxo‐2‐hexadecenoate, the immediate precusor to the antiviral fungal metabolite podoscyphic acid. 相似文献
55.
Christian Fabiansen Charles W. Yaméogo Sarita Devi Henrik Friis Anura Kurpad Jonathan C. Wells 《Isotopes in environmental and health studies》2017,53(4):344-355
Childhood malnutrition is highly prevalent and associated with high mortality risk. In observational and interventional studies among malnourished children, body composition is increasingly recognised as a key outcome. The deuterium dilution technique has generated high-quality data on body composition in studies of infants and young children in several settings, but its feasibility and accuracy in children suffering from moderate acute malnutrition requires further study. Prior to a large nutritional intervention trial among children with moderate acute malnutrition, we conducted pilot work to develop and adapt the deuterium dilution technique. We refined procedures for administration of isotope doses and collection of saliva. Furthermore, we established that equilibration time in local context is 3?h. These findings and the resulting standard operating procedures are important to improve data quality when using the deuterium dilution technique in malnutrition studies in field conditions, and may encourage a wider use of isotope techniques. 相似文献
56.
Benzofuroxanes react with dienamines to give a novel class of quinoxaline NN'-dioxide enamines in good yields. 相似文献
57.
A modified combustion process, namely a mixed fuel process making use of a mixture of two fuels, such as citric acid and glycine
has been developed to prepare nanocrystalline ceria powders. The effect of the mixed fuel and the different fuel to oxidant
ratios on the decomposition characteristics of the gels were investigated by simultaneous thermal analysis experiments. It
was established from various characterization techniques that the ceria powder prepared through the mixed fuel process has
got the optimum powder characteristics, namely, a surface area of 33.33 m2/g and a crystallite size of 14 nm compared to the powders produced through the combustion process using a single fuel like
glycine or citric acid. Such powders when sintered at 1250°C resulted in pellets with densities in the range of 94–96% of
theoretical density. In this paper, we have carried out systematic studies on the sintering of ceria powders prepared by different
approaches. The sintered ceramic from mixed fuel batch, exhibited and retained relative density more than 95% up to 1250°C
and this data clearly underscores the ability of this process in developing ceria ceramics with increased stability against
reduction. 相似文献
58.
The Rayleigh–Taylor instability (RTI) of a ferrofluid has been the subject of recent research, because of its implications on the stability of stellar and planetary interiors. This paper analyzes the effects of rotation and magnetic field on nonlinear RTI of two superposed ferrofluids. It is considered that the system is subjected to uniform parallel rotation and normal magnetic field. Surface tension acts at the interface. The method of multiple scales is utilized to obtain the solutions and dispersion relations are obtained for the nonlinear problem of RTI of magnetic fluids. Finally the stability of the problem is discussed. 相似文献
59.
Rajendra N. Goyal Neena Jain Vibha Gurnani 《Monatshefte für Chemie / Chemical Monthly》2001,132(5):575-585
Summary. The electrochemical behaviour of chlorpromazine has been examined in phosphate buffers in aqueous as well as micellar media
at a pyrolytic graphite electrode surface. Two oxidation peaks were obtained in linear sweep voltammetry of chlorpromazine.
The first peak corresponds to the formation of the cationic free radical, which on further 1e−-oxidation gives a dication. The spectroscopic changes and kinetics of the cationic free radical and dication species generated
during electrooxidation of chlorpromazine were investigated in both media. The decay of the dication was studied chronoamperometrically
and was found to follow first-order kinetics with a half-life of ∼25 ms. Surfactants affect both E
p and i
p values. The anionic surfactant SDS has been found to catalyze the reaction of the free radical cation and the dication. 相似文献
60.