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351.
We present a calculation of the electronic density of states in TiHx alloys (x=2.0, 1.7, and 1.5) with various degrees of long-range atomic order, η, in the subsystem of hydrogen and vacancies
in the nonstoichiometric hydrides. In comparing the calculated results with the features of the photoelectron spectrum of
TiH1.5 we find agreement for η=0.5. We determine the temperature range for the establishment of atomic vacancy order.
Siberian V. D. Kuznetsov Physicotechnical Institute, Tomsk University. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii,
Fizika, No. 10, pp. 7–14, October, 1998. 相似文献
352.
I. A. Nechaev A. Yu. Moskvichev V. S. Demidenko V. I. Simakov 《Russian Physics Journal》1998,41(6):600-606
Unified approximations are used to calculate the electronic structure of iron alloys with B, C, and N. Calculations are performed
for the lattice parameter of fcc iron and for the lattice parameter after relaxation in accordance with an empirical relation
for solid solutions. Laws are found that relate mutual perturbations of the states of the components to the position of the
interstitial elements in the periodic table.
V. D. Kuznetsov Siberian Physico-Technical Institute, Tomsk University. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii,
Fizika, No. 6, pp. 103–110, June, 1998. 相似文献
353.
A self-consistent analog of the Hubbard local-field factor accounting for a real band structure of the metal under investigation is proposed for the calculation of the exchange-correlation corrections to the randomphase approximation. The plasmon energy and the plasmon line width for potassium are calculated as a function of the wave vector. The calculations are performed within the random-phase approximation and with corrections for the local field. It is shown that the results of the calculations are in good agreement with the experimental data. This indicates that, first, the corrections to the random-phase approximation should be taken into account for metals with a low electron density and, second, the local-field factor approximation is an appropriate approach. 相似文献
354.
We study here a standard next-nearest-neighbor (NNN) model of ballistic growth on one-and two-dimensional substrates focusing
our analysis on the probability distribution function P(M,L) of the number M of maximal points (i.e., local “peaks”) of growing surfaces. Our analysis is based on two central results: (i) the proof
(presented here) of the fact that uniform one-dimensional ballistic growth process in the steady state can be mapped onto
“rise-and-descent” sequences in the ensemble of random permutation matrices; and (ii) the fact, established in Ref. [G. Oshanin
and R. Voituriez, J. Phys. A: Math. Gen. 37:6221 (2004)], that different characteristics of “rise-and-descent” patterns in random permutations can be interpreted in
terms of a certain continuous-space Hammersley-type process. For one-dimensional system we compute P(M,L) exactly and also present explicit results for the correlation function characterizing the enveloping surface. For surfaces
grown on 2d substrates, we pursue similar approach considering the ensemble of permutation matrices with long-ranged correlations.
Determining exactly the first three cumulants of the corresponding distribution function, we define it in the scaling limit
using an expansion in the Edgeworth series, and show that it converges to a Gaussian function as L → ∞. 相似文献
355.
356.
The composition, the structure, and the microhardness of the oxide coating formed during a combined plasma process on a VT16 titanium alloy are studied. The structure of plasma-sputtered aluminum oxide after microarc oxidation is found to change: the coating has a lower density and is melted. The phase composition of the aluminum oxide formed by electro-plasma sputtering and then subjected to microarc oxidation remains unchanged. 相似文献
357.
K. V. Berezin V. V. Nechaev M. K. Berezin N. F. Stepanov S. V. Krasnoshchekov 《Optics and Spectroscopy》2014,117(3):366-373
The anharmonic vibrational IR and Raman spectra of the bicyclo[1.1.0]butane molecule have been calculated in the range of up to 4000 cm?1 using a numerical and analytical realization of the van Vleck second-order operator perturbation theory. Cubic and quartic force constants in normal coordinates, as well as cubic surfaces of the dipole moment and polarizability, have been found by numerical differentiation of the corresponding first and second derivatives calculated by the MP2/cc-pVTZ quantum-mechanical method. In order to increase the prediction accuracy of vibrational transitions, corresponding harmonic frequencies have been obtained by the CCSD(T)/cc-pVTZ high-precision quantum mechanical method. The anharmonic intensities of the IR and Raman spectra have been calculated using canonical transformations of the operators of the dipole moment and polarizability expanded into a Taylor series around the equilibrium configuration. The assignment of experimental vibrational bands in the IR and Raman spectra has been analyzed. It has been shown that the anharmonic calculation based on the above-described procedure of combining more exact harmonic frequencies with the anharmonic force field obtained with a more economical method makes possible the reliable interpretation of the majority of spectral bands, including Fermi and Darling-Dennison resonances. 相似文献
358.
New potassium-conducting solid electrolytes based on potassium monogallate in the K2?2x Ga2?x V x O4 system are synthesized and studied. It is found that an introduction of V5+ ions leads to a considerable increase in the KGaO2 conductivity due to the formation of vacancies in the potassium sublattice. The conductivity for optimal compositions is approximately 10?3 S cm?1 at 400°C and above 10?2 S cm?1 at 700°C. The results are compared with early obtained data for potassium monogallate dopped with four-charged cations. 相似文献
359.
New solid electrolytes with a high conductivity by K+ ions in the K1 − 2x
Sr
x
GaO2 system are synthesized and studied. It is found that the introduction of Sr2+ ions into potassium monogallate leads to the formation of solid solutions with KGaO2 structure in a wide range of additive concentration. These solid solutions exhibit a high conductivity; the conductivity
increases monotonically with increasing concentration of strontium within the single-phase range. The electrical characteristics
are related to the electrolyte structure. The results are compared with the earlier data for the gallate solid electrolytes
with the additives of four-charged cations and the systems based on potassium monoferrite and monoaluminate. 相似文献
360.
V. M. Bystritsky G. N. Dudkin B. A. Nechaev V. N. Padalko F. M. Pen’kov Yu. Zh. Tuleushev M. Filipowicz A. V. Philippov 《JETP Letters》2018,107(11):665-670
The D(3He, p)4He reaction is first investigated in a solid target of deuterated zirconium (ZrD) in the 3He+ ion energy range EHe = 18–30 (E = 7.2?12.0keV keV in the center-of-mass system) with a step of 2 keV. The electron screening potential Ue = (617.8 ± 154.7) eV and the D(3He, p)4He reaction enhancement factors are experimentally determined in the given energy range. The measured electron screening potential is six times higher than in gaseous targets. This can be due to the ZrD lattice effects, which have not been studied either theoretically or experimentally so far. The D(3He, p)4He reaction has been investigated at the pulsed plasma Hall accelerator (Tomsk). 相似文献