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111.
Navnath B. Khomane Rayala Naveen Kumar Prakash R. Mali Prashishkumar K. Shirsat H.M. Meshram 《Tetrahedron letters》2017,58(50):4687-4690
Formal synthesis of 14-membered unsymmetrical bis-macrolactone, (?)-colletodiol was accomplished from homopropargylic alcohol derivative. Building of the two different hydroxy acid fragments from the same intermediate of homoallylic alcohol was particularly advantageous. A Sharpless asymmetric dihydroxylation, homologation of carbon chain, a Pinnick oxidation, and a macrolactonization to assemble the 14-membered macrodiolide were the additional salient features of this convergent synthesis. 相似文献
112.
Polymer blended films of polyethylene oxide (PEO)?+?polyvinyl pyrrolidone (PVP):lithium perchlorate (LiClO4) embedded with silver (Ag) nanofiller in different concentrations have been synthesized by a solution casting method. The semi-crystalline nature of these polymer films has been confirmed from their X-ray diffraction (XRD) profiles. Fourier transform infrared spectroscopy (FTIR) and Raman analysis confirmed the complex formation of the polymer with dopant ions. Dispersed Ag nanofiller size evaluation study has been done using transmission electron microscopy (TEM) analysis. It was observed that the conductivity increases when increasing the Ag nanofiller concentration. On the addition of Ag nanofiller to the polyethylene oxide (PEO)?+?polyvinyl pyrrolidone (PVP):Li+ electrolyte system, it was found to result in the enhancement of ionic conductivity. The maximum ionic conductivity has been set up to be 1.14?×?10?5 S cm?1 at the optimized concentration of 4 wt% Ag nanofiller-embedded (45 wt%) polyethylene oxide (PEO)?+?(45 wt%) polyvinyl pyrrolidone (PVP):(10 wt%) Li+ polymer electrolyte nanocomposite at room temperature. Polyethylene oxide (PEO)?+?polyvinyl pyrrolidone (PVP):Li+ +Ag nanofiller (4 wt%) cell exhibited better performance in terms of cell parameters. This is ascribed to the presence of flexible matrix and high ionic conductivity. The applicability of the present 4 wt% Ag nanofiller-dispersed polyethylene oxide (PEO)?+?polyvinyl pyrrolidone (PVP):Li+ polymer electrolyte system could be suggested as a potential candidate for solid-state battery applications. Dielectric constants and dielectric loss behaviours have been studied. 相似文献
113.
114.
Mushfika Baishakhi Upama Matthew Wright Naveen Kumar Elumalai Md Arafat Mahmud Dian Wang Kah Howe Chan Cheng Xu Faiazul Haque Ashraf Uddin 《Optical and Quantum Electronics》2017,49(1):28
The optical properties of a novel semi-transparent organic solar cell were investigated both experimentally and by transfer matrix modelling to maximize photocurrent generation. The effect of multilayer anode thickness and illumination direction was studied. Bottom illumination was shown to provide enhanced exciton generation and increased photocurrent. Changing the multilayer anode thickness also influenced the device reflectance and photocurrent generation. 相似文献
115.
In this paper, we implement a fully phase-encrypted memory system using cascaded extended fractional Fourier transform (FRT). We encrypt and decrypt a two-dimensional image obtained from an amplitude image. The full phase image to be encrypted is fractional Fourier transformed three times and random phase masks are placed in the two intermediate planes. Performing the FRT three times increases the key size, at an added complexity of one more lens. The encrypted image is holographically recorded in a photorefractive crystal and is then decrypted by generating through phase conjugation, the conjugate of the encrypted image. A lithium niobate crystal has been used as a phase contrast filter to reconstruct the decrypted phase image, alleviating the need of alignment in the Fourier plane making the system rugged. 相似文献
116.
Though the predictions of the standard model (SM) are in excellent agreement with experiments, there are still several theoretical
problems associated with the Higgs sector of the SM, where it is widely believed that some new physics will take over at the
TeV scale. One beyond the SM theory which resolves these problems is the Little Higgs (LH) model. In this work we have investigated
the effects of the LH model on γγ → γγ scattering [1].
相似文献
117.
S. Rai Choudhury A. S. Cornell Naveen Gaur 《The European Physical Journal C - Particles and Fields》2008,58(2):251-259
Flavor changing neutral current (FCNC) decays of the B-meson are a very useful tool for studying possible physics scenarios beyond the standard model (SM), where of the many FCNC
modes radiative, purely leptonic and semi-leptonic decays of the B-meson are relatively clean tests. Within this context, the BELLE collaboration has measured the process B→K
*
γ and also searched for the B→K
1(1270)γ process. Theoretical analyses of these processes are yielding similar values of the relevant form factors. In this work we
have used this upper bound in studying the angular correlations for the related semi-leptonic decay mode B
−→K
1−(1270)(→ρ
0
K
−)ℓ
+
ℓ
−, where we have used the form factors that have already been estimated for the B→K
1(1270)γ mode. Note that the additional form factors that are required were calculated using large energy effective theory (LEET). 相似文献
118.
G.E. Barberis D. Davidov J.P. Donoso F.G. Gandra C. Rettori J.F. Suassuna 《Solid State Communications》1978,28(6):427-433
The resonance properties of the Γ6 ground state of Nd+3 in the type II Superconductors CeRu2, ThRu2 and LaRu2 are reported. A significant change of the g value and lineshape were observed for CeRu2:Nd upon going from the normal state to the superconducting state. The data in the superconducting state is discussed in terms of conduction electron's pairing mechanism and inhomogeneous field distribution mechanism in the superconducting state. A preliminary lineshape analysis is not completely consistent with previous theoretical predictions and experiments. 相似文献
119.
The conversion of oxime ethers into nitriles has been achieved under neutral conditions using Ru(CO)(PPh3)3H2 and the bidentate ligand Xantphos as the catalyst. 相似文献
120.
S. Viveka G. Vasantha Dinesha S. Naveen N. K. Lokanath 《Molecular Crystals and Liquid Crystals》2016,629(1):135-145
The present study describes the synthesis, spectroscopic, and single crystal X-ray structural analysis of ethyl 5-methyl-1-phenyl-1H-pyrazole-4-carboxylate. The pyrazole ester of formula [C13H14N2O2] was prepared from the three-component one-pot condensation reaction of ethyl acetoacetate, N,N-dimethyldimethoxymethanamine, and phenyl hydrazine. The product was crystallized by using ethanol as solvent. The structure of the compound was confirmed by elemental analysis, Fourier transforms infrared (IR), thermogravimetric analysis, UV-visible (UV-Vis), 1H NMR, and single-crystal X-ray diffraction studies. The gas-phase molecular geometry and the electronic structure-property of the molecule were calculated at the density functional theory. The frontier molecular orbitals, theoretical UV-Vis, and IR stretching vibrations were also reported. The compound crystallizes in the monoclinic system with the space group P21/c and Z = 4. The unit cell parameters are a = 12.141(3) Å, b = 13.934(4) Å, c = 7.2777(18) Å, and β = 97.816(14)0. The structure is stabilized by an intermolecular interaction of type C-H···O and the structure also involves C-H···π interactions. 相似文献