Precipitates originating from tungsten crucible parts in AlN bulk crystals grown by the PVT method

In order to evaluate the possible involvement of crucible materials in the growth of AlN bulk crystals grown by physical vapor transport, we applied growth conditions with a high vertical thermal gradient and hence high supersaturation of aluminum vapor. Under these conditions, precipitates formed causing diffuse grayish substructures at the initial growth interface and in the crystal body, decorating dislocations. Electron microscopy studies revealed that the precipitates are elongated, single‐phase particles with sizes of 50–500 nm of commensurate structure, oriented along the <110> direction. Chemical analysis of the precipitates showed tungsten as well as carbon and oxygen. The lattice parameters of the precipitates are in close agreement to hexagonal tungsten hemicarbide (W₂C). The possible transport from the tungsten parts and its conversion into tungsten hemicarbide precipitates is discussed. We thus conclude that the W₂C precipitates may contribute to the decoration of dislocations, even in growth with moderate thermal gradients.     

Zur Darstellung gasiger und w?ssriger Bromwasserstoffs?ure

Ohne Zusammenfassung     

Das Verhalten von Salzen in nicht w?ssrigen L?sungen

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Multiplicity structure of inclusive diffraction in À+ p andK + p interactions at 250 GeV/c

Results on the multiplicity structure of diffractively excited meson and proton systems in À⁺/K⁺ p interactions at 250 GeV/c are presented for diffractive masses up to about 9 GeV. The energy dependence of the average charge multiplicity and the shape of the multiplicity distribution in terms of KNO-scaling and negative binomial distribution are investigated. The diffractive systems are compared toe ⁺ e ^–,lh and non-diffractivehh final states as suggested by modern approaches of the Pomeron-hadron collision. Systematic differences are found between diffractive meson and proton systems but also between diffraction and the reactions compared to.     

A uniqueness theorem for weak solutions of the stationary semiconductor equations

In this paper we prove a uniqueness theorem for weak solutions of a mixed boundary-value problem for the stationary semiconductor equations (van Roosbroeck's system) under the assumption that the deviation of the carrier potentials from an equilibrium solution is sufficiently small.     

X-ray investigation of combined main-chain/side-chain liquid-crystalline polymers

Structural investigations on six combined liquid-crystalline polymers using the X-ray technique are described. The measurements have allowed a characterization of the liquid-crystalline phases and have led to our first ideas about the phase structures. All mesogenic groups are arranged parallel to each other, the shortest segment in the main-chain or in the side-chain determines the smectic layer spacing. A modified designation for liquid-crystalline phases of high polymers is proposed.