Nuclear Resonant Inelastic and Forward Scattering of Synchrotron Radiation by 40K

We achieved excitation of the first excited state of ⁴⁰K and confirmed both energy and lifetime. Furthermore, we observed nuclear resonant inelastic scattering by ⁴⁰K in a powdered KCl sample at room temperature using a high-resolution monochromator. The time spectrum of the nuclear resonant forward scattering was measured at 50 K. Our observations of nuclear resonant inelastic and forward scattering by ⁴⁰K make electronic and dynamic studies for potassium practical. The measurements of nuclear resonant scattering for the radioactive ⁴⁰K nuclide will enable and lead to further studies of other radioactive nuclides. This revised version was published online in August 2006 with corrections to the Cover Date.     

Spinor with Schrödinger symmetry and non-relativistic supersymmetry

We construct the d-dimensional “half” Schrödinger equation, which is a kind of the root of the Schrödinger equation, from the (d+1)-dimensional free Dirac equation. The solution of the “half” Schrödinger equation also satisfies the usual free Schrödinger equation. We also find that the explicit transformation laws of the Schrödinger and the half Schrödinger fields under the Schrödinger symmetry transformation are derived by starting from the Klein-Gordon equation and the Dirac equation in d+1 dimensions. We derive the 3- and 4-dimensional super-Schrödinger algebra from the superconformal algebra in 4 and 5 dimensions. The algebra is realized by introducing two complex scalar and one (complex) spinor fields and the explicit transformation properties have been found.     

Synthesis of novel mucic acid 1,4-lactone methyl ester 3-O-ferulate related to an extractive component isolated from the peels of Citrus sudachi

Synthesis of a new type of mucic acid 1,4-lactone methyl ester 3-O-ferulate related to an extractive component isolated from Citrus sudachi, and its diastereomer has been achieved by employing stereodivergent dihydroxylation as a key step. The structures of the final products are fully characterized by spectroscopic methods and compared with that of the natural product.     

A synthetic approach to diverse 3-acyltetramic acids via O- to C-acyl rearrangement and application to the total synthesis of penicillenol series

For the efficient approach to medicinally important α-branched 3-acyltetramic acids, the key reaction of O- to C- acyl rearrangement using α-amino-acid-derived 4-O-acyltetramic acids was extensively examined in the presence of various metal salts. Use of CaCl(2) or NaI dramatically changed the results in the reaction efficiency and rapidly brought about the desired α-branched 3-acyltetramic acids in markedly improved yields. We also discuss an epimerization at C5 stereocenter under the rearrangement conditions as well as the tolerance for structural variation at C3 and C5. In addition to the preceding success in the total synthesis of new cytotoxic tetramic acid, penicillenol A(1), this methodology could be also applied to the first total synthesis of penicillenol A(2).     

First Precision Spectroscopy of Pionic Atoms at RI Beam Factory

We conducted an inclusive missing-mass spectroscopy of ¹²²Sn (d, ³He) reaction near the π¯ emission threshold at an incident energy of T _d = 250 MeV/nucleon. The experiment sets its goals to the research and development of the high precision spectroscopy of pionic atoms at the RI beam factory (RIBF) of RIKEN, which precedes a new project, pionic atom factory project (piAF), to observe pionic atoms systematically. Here, we report the preliminary results of the pilot experiment.     

Formation of Deeply Bound Pionic Atoms in Sn Isotopes

We study the formation of deeply bound pionic atoms in the (d,³He) reaction theoretically. At different scattering angles, we find that the different subcomponents dominate the formation spectra because of the matching condition of the reaction. We also find that the pionic 1s state which is free from the residual interaction effects appears clearly in ¹¹⁷Sn(d, ³He) spectra. We conclude that the observation of the (d,³He) reaction for these new cases will provide more systematic and accurate information on the pionic bound states, and it will help to develop the study of the pion properties and the partial restoration of chiral symmetry in nuclei.     

Anharmonic oscillation of ions trapped in a rf trap with light buffer gas

The effect of a light buffer gas on the anharmonic oscillation of ions trapped in a rf trap is studied. The rf resonance absorption signals showed a change of the signal height and the hysteresis with the sweep direction of the dc voltage or the probing frequency due to the anharmonicity of the pseudopotential well of a rf trap. It was found that the signals changed drastically or even disappeared depending on the pressure of buffer gas, although almost the same number of ions were trapped. These effects indicate that the sensitivity of detection of the trapped ions can be improved by appropriately choosing the pressure of the buffer gas and the sweep direction. The trapped ions could be detected until 76 h 20 min and the storage time of 1.3×10⁵ s was determined when these parameters were optimized.     

Dianion of N-phenyl-2-(phenylsulfonylmethyl)propenamide: an efficient synthetic reagent for (E)-trisubstituted olefins and 5,6-dihydro-2H-pyrans

The dianion of N-phenyl-2-(phenylsulfonylmethyl)propenamide was found to be an efficient reagent for the synthesis of (E)-α,β-unsaturated amides and 5,6-dihydro-2H-pyrans.     

Contactless density measurement of high-temperature BiFeO<Subscript>3</Subscript> and BaTiO<Subscript>3</Subscript>

The density of liquid and undercooled BiFeO₃ and high-temperature solid, liquid, and undercooled BaTiO₃ was measured with an electrostatic levitation furnace. The density was obtained with an ultraviolet-based imaging technique that allowed excellent sample contrast throughout all phases of processing, including at elevated temperatures. Over the 1250- to 1490-K temperature range, the density of liquid BiFeO₃ can be expressed as _L(T)=6.70×10³–1.31(T-T_m)(kgm^-3) (±2 per cent) with T_m=1423 K, yielding a volume coefficient of thermal expansion _L(T)=1.9×10^-4 K^-1. For BaTiO₃, the density of the solid can be expressed as _S(T)=5.04×10³–0.21(T-T_m) (T_m=1893 K) over the 1220- to 1893-K range, yielding a volume coefficient of thermal expansion _S(T)=4.2×10^-5 K^-1, whereas that of the liquid can be expressed as _L(T)=4.04×10³-0.34(T-T_m) over the 1300- to 2025-K range with _L(T)=8.4×10^-5 K^-1. PACS 77.84.-s; 81.05.Je; 81.20.n     

Visualization of aerodynamic noise source around a rotating fan blade

The purpose of this study is to understand the aerodynamic noise source distribution around a rotating fan blade by measuring the noise signal and velocity field around the blade. The local noise-level distribution over the fan blade is measured by microphone arrays, and the flow field is visualized by smoke and phase-averaged PIV measurement. The noise source distribution is examined by cross-correlation analysis between noise signal and velocity fluctuation. It is found that the noise source is located near the rotating fan blade, especially around leading and trailing edges. The separation and reattachment of flow are observed near the leading edge, and the tip vortices and vortex shedding are found near the trailing edge. The cross-correlation distribution of the noise signal and the radial velocity fluctuation shows large magnitude in the correlated regions, which indicates the noise generation by the formation of vortex structure around the blade.