全文获取类型
收费全文 | 380篇 |
免费 | 4篇 |
国内免费 | 2篇 |
专业分类
化学 | 272篇 |
晶体学 | 1篇 |
力学 | 4篇 |
数学 | 22篇 |
物理学 | 87篇 |
出版年
2021年 | 6篇 |
2020年 | 2篇 |
2019年 | 13篇 |
2017年 | 2篇 |
2016年 | 5篇 |
2015年 | 7篇 |
2014年 | 6篇 |
2013年 | 16篇 |
2012年 | 12篇 |
2011年 | 26篇 |
2010年 | 18篇 |
2009年 | 13篇 |
2008年 | 21篇 |
2007年 | 24篇 |
2006年 | 34篇 |
2005年 | 15篇 |
2004年 | 13篇 |
2003年 | 13篇 |
2002年 | 14篇 |
2001年 | 12篇 |
2000年 | 8篇 |
1999年 | 6篇 |
1998年 | 4篇 |
1997年 | 7篇 |
1996年 | 9篇 |
1995年 | 2篇 |
1994年 | 1篇 |
1993年 | 4篇 |
1992年 | 5篇 |
1991年 | 5篇 |
1990年 | 3篇 |
1989年 | 4篇 |
1988年 | 2篇 |
1987年 | 2篇 |
1986年 | 2篇 |
1985年 | 8篇 |
1984年 | 6篇 |
1983年 | 2篇 |
1982年 | 1篇 |
1981年 | 5篇 |
1980年 | 8篇 |
1979年 | 1篇 |
1978年 | 4篇 |
1977年 | 6篇 |
1976年 | 2篇 |
1975年 | 2篇 |
1974年 | 2篇 |
1968年 | 3篇 |
排序方式: 共有386条查询结果,搜索用时 265 毫秒
31.
Yajima T Wakabayashi N Uchida H Watanabe M 《Chemical communications (Cambridge, England)》2003,(7):828-829
Adsorbed water molecules which promote the methanol oxidation reaction (MOR) at Pt-Ru alloy electrode are clearly detected by in-situ FTIR spectroscopy with the attenuated total reflection configuration, which directly supports the "bi-functional mechanism" for the MOR. 相似文献
32.
Masahiro Kihara Shin‐Ichiro Kohama Shota Umezono Kanji Wakabayashi Shinichi Yamazaki Kunio Kimura 《Journal of polymer science. Part A, Polymer chemistry》2011,49(5):1088-1096
Poly(p‐oxybenzoyl) (POB) crystals were prepared by reaction‐induced crystallization during direct polymerization of p‐hydroxybenzoic acid in the presence of boronic anhydrides. Polymerizations were carried out at 300 °C in dibenzyltoluene at a concentration of 1% with three kinds of anhydrides of boronic acid such as 3,4,5‐trifluorophenylboronic acid (TFB), 4‐methoxyphenylboronic acid (MPB) and 4‐biphenylboronic acid (BPB). The POB crystals were formed as precipitates in the solution and the morphology was considerably influenced by both the structure of the boronic anhydride and its concentration (cB). Needle‐like crystals were firmed in the presence of TFB anhydride (TFBA) at cBs of 5 and 10 mol % by the spiral growth of lamellae. Spherical aggregates of slab‐like crystals were formed at cBs from 50 to 100 mol %. The polymerization with MPB anhydride and BPB anhydride (BPBA) also yielded the needle‐like crystals at cBs of 50 and 5 mol %, respectively. The polymerization with TFBA at lower cB was favorable to prepare the needle‐like crystal. Molecular weight was also influenced by the structure of the boronic anhydride and cB. Mn increased generally with cB and BPBA gave the highest Mn of 14.7 × 103 at cB of 100 mol %. The loose packing of the molecules in the crystal caused by the bulkiness of the end‐groups made the polymerization in the crystals more efficiently. Morphology and molecular weight of the POB crystals could be controlled by the chemical structure and the content of boronic anhydride. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011. 相似文献
33.
34.
35.
36.
37.
38.
39.
40.
Kanyiva KS Kashihara N Nakao Y Hiyama T Ohashi M Ogoshi S 《Dalton transactions (Cambridge, England : 2003)》2010,39(43):10483-10494
A combination of Ni(cod)(2) and PCyp(3) is found to be an effective catalyst for chemoselective activation of the C-H bond of fluoroarenes over C-F bonds followed by insertion of alkynes to allow direct alkenylation of the electron-deficient arenes. The characteristics of the reactions are: a C-H bond ortho to a fluorine substituent is selectively activated; the reactivity of fluorobenzenes is roughly proportional to the number of fluorine atoms. The reaction conditions tolerate a broad range of both alkynes and fluoroarenes containing both electron-withdrawing and -donating groups, thus allowing efficient synthesis of a variety of substituted ethenes containing a fluoroaryl motif in high regio- and stereoselective manners. Mechanistic studies including both labeling experiments and stoichiometric reactions reveal that oxidative addition of C-H bonds in fluoroarenes to nickel(0) is kinetically highly facile whereas that of C-F bonds is thermodynamically favoured. 相似文献