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71.
Kuzmann E. Nath A. Chechersky V. Li S. Wei Y. Chen X. Li J. Homonnay Z. Gál M. Garg V. K. Klencsár Z. Vértes A. 《Hyperfine Interactions》2002,139(1-4):631-639
57Fe transmission Mössbauer spectroscopy and X-ray diffractometry were used to study - and -polymorphs of iron phthalocyanines (FePc) to get information about their oxygenation in connection with controlled pyrolysis of flat layered phthalocyanines initiated by radicals at relatively low temperatures, to form acicular carbide particles encaged in carbon. Mössbauer spectroscopy and XRD revealed that the oxygenation of both - and -polymorphs of FePc was successfully achieved. New Mössbauer spectral components (doublets) appeared upon the oxygenation in both and FePc. This can be attributed to iron microenvironments containing oxygen between the layers of iron phthalocyanines. 相似文献
72.
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75.
The composition of the precipitate formed when the Nessler's reagent is treated with ammonia, is assumed as NHn-1Hg2In, aq. and has been studied potentiometrically from iodine-hypoiodite-system. It has been observed that the value of n depends on the concentrations of [HgI4]-2 and OH- ions as well as on the amount of ammonia added and it may vary from 1 to 3. The colour of the precipitate deepens from brown to chocolate as the value of n increases. 相似文献
76.
We develop models for the propagation of intense pulses in solid state media which can have either saturated absorption or reverse absorption. We model subluminal propagation in ruby and superluminal propagation in alexandrite as three and four level systems, respectively, coupled to Maxwell's equations. We present results well beyond the traditional pump-probe approach and explain the experiments of Bigelow et al. [Phys. Rev. Lett. 90, 113903 (2003)]Science 301, 200 (2003)]] on solid state materials. 相似文献
77.
In this review article, we discuss a class of biosensors that exploit the change in the colorimetric properties of noble metal nanoparticles in response to biomolecular binding at their surface. Several sensor fabrication techniques as well as sensor configurations are discussed with an emphasis on their strengths and limitations. We conclude by presenting the future prospects and challenges for the successful transition of this technology from the laboratory to a commercial product. 相似文献
78.
A solution phase UV-irradiation technique has been exploited to produce an AuSe nanoalloy through fusion of preformed Au (photoproduced) and Se (chemically prepared) in a micellar (TX-100) medium. 相似文献
79.
The Bergman cyclization of simple diethynylporphyrinic-enediynes exhibits a double activation barrier to the formation of Bergman cyclized product. Addition of H-atom acceptor accelerates the formation of the picenoporphyrin, indicating that the second barrier is rate limiting. 相似文献
80.
Boltzmann-transport equation is analytically solved for two-component magnetoplasma using Chapman-Enskog analysis to include
collisional diffusion transport having anisotropies in both streaming velocity and temperature components. The modified collisional
integrals are analytically solved with flux integrals and perturbed kinetic equation to arrive at drift diffusion velocity
and resulting transport coefficients which are markedly affected by both streaming and temperature anisotropy. The early isotropic
results are recovered in the limit V
0 = 0 and T
‖ = T
⊥ which reduce to eqs (11.30) and (11.31) of [1] and eqs (2.7) and (2.13) of [2]. The electrical resistivity (η⊥) diminishes sharply in fusion temperature limit kT
⊥ = 1 keV. The shape of the curves for both electrical resistivity and thermal conductivity is rectangular hyperbolic. However,
for low thermal ratio (T
‖/T
⊥ < 1), the curves are raised up and for high thermal ratio (T
‖/T
⊥ > 1), they are lowered down the isotropic case (T
‖/T
⊥ > 1), showing comparatively diminished magnitudes of the quantities.
相似文献