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V.M. Shanmugam K. Kulangiappar M. Ramaprakash D. Vasudevan R. Senthil Kumar D. Velayutham T. Raju 《Tetrahedron letters》2017,58(23):2294-2297
Electrochemical synthesis of quinones has been attempted from phenols, 1,4-dihydroxybenzenes, 1,4-dihydroxynaphthalenes and related compounds using biphasic media. Excellent yields of quinones (98%) or brominated diols have been achieved with good current efficiency. Reuse of the electrolyte without any modification and quantitative conversion of substrate with theoretical amount of current are the advantages of this method. 相似文献
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Madduluri Venkata Rao Katari Naresh Kumar Peddinti Nagaiah Velpula Venkataramana Kumar Burri David Raju Kamaraju Seetha Rama Rao Jonnalagadda Sreekantha B. 《Research on Chemical Intermediates》2018,44(12):7619-7639
Research on Chemical Intermediates - Excellent catalytic activity of activated redbrick clay (ARB) for dehydration and highly selective conversion of cyclohexanol to cyclohexene and 1-phenylethanol... 相似文献
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R. Nageswara Rao Ch. Gangu Naidu K. Guru Prasad Raju Padiya Sachin B. Agwane 《Biomedical chromatography : BMC》2012,26(12):1534-1542
A highly selective, sensitive and rapid hydrophilic liquid interaction chromatographic method was developed and validated for determination of gemifloxacin on dried blood spots. The chromatographic separation was achieved on a reversed‐phase zwitterionic hydrophilic interaction liquid chromatographic ZIC®HILIC‐C18 (4.6 × 100 mm; 5 µm) column using acetonitrile–10 mM ammonium acetate (pH 3.5; 80:20, v/v) as a mobile phase in an isocratic elution mode at a flow rate 0.6 mL/min at 27 °C. An on‐line fluorescence detector set at excitation and emission wavelengths of 269 and 393 nm, respectively was used for monitoring column eluents. Ciprofloxacin was used as an internal standard. The method was validated for accuracy, precision, linearity and selectivity by design of experiments following ICH guidelines. The assay exhibited a linear range of 25–5000 ng/mL for gemifloxacin on dried blood spots. The lower limit of detection was found to be 10 ng/mL. The intra‐ and inter‐assay coefficients of variation did not exceed 7.4% deviation of the nominal concentration. The recovery of GFX from dried blood spots was >95.0% and its stability was excellent with no evidence of degradation during sample processing for at least 3 months storage in a freezer at ?20 °C. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
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Gowravaram Sabitha Chintam Nagendra ReddyAtla Raju Jhillu Singh Yadav 《Tetrahedron: Asymmetry》2011,22(4):493-498
A highly stereoselective synthesis of the naturally occurring lactone (−)-spicigerolide has been achieved utilizing OsO4-catalyzed dihydroxylation, CBS, Lindlar’s reductions, Still-Gennari, and Grignard reactions as the key reaction steps. 相似文献
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DNA fastening and scission actions of Cu(II), Co(II), Ni(II) and Zn(II) complexes: synthesis,spectral characterization and cytotoxic study 下载免费PDF全文
A heterocyclic compound, 2‐(aminomethyl)benzimidazole dihydrohydrochloride, was treated with nitrobenzaldehyde to form a Schiff base that was made to react with divalent metals. A co‐ligand, either 1,10‐phenanthroline or 2,2′‐bipyridine, was added to this mixture to obtain metal chelators of type [ML(co‐L)2]Cl2. They were in 1:1:2 stoichiometry ratio, which was characterized by various spectroscopic techniques that suggested an octahedral geometry around the central metal ions. These complexes were investigated for their binding affinities with calf thymus (CT) DNA, using various techniques, such as UV–Vis, viscosity, cyclic voltammetry (CV), etc. The binding interaction studies revealed intercalation as the possible binding mode of the complexes with the CT DNA. In addition, these complexes were screened for their antimicrobial potential and DNA denaturing tendencies using gel electrophoretic assay. The antimicrobial screening investigation showed that the complexes behaved as better antimicrobial agents than the ligand, especially, complex 5 shows exceptional activity even in the electrophoretic assay along with the antimicrobial efficacy. Moreover, complex 5 was able to denature the plasmid DNA better than the other compounds. All the compounds were screened for cytotoxic efficacy, and the IC50 values suggest that the compounds possess cytotoxic activity to some extent that is almost the same as the activity of cisplatin. 相似文献
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