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Five new open-framework zinc phosphates, encompassing the entire hierarchy of open-framework structures, have been synthesized hydrothermally in the presence of triethylenetetramine. The structures include one-dimensional ladders, two-dimensional layers, and three-dimensional structures as well as a zinc phosphate where the amine acts as a ligand. [C6N4H22]0.5[Zn(HPO4)2] (I): monoclinic, space group P2(1)/c (no. 14), a = 5.2677(1) A, b = 13.3025(1) A, c = 14.7833(1) A, beta = 96.049 degrees, Z = 4. [C6N4H22]0.5[Zn2(HPO4)3] (II): triclinic, space group P1 (no. 2), a = 7.515(1) A, b = 8.2553(1) A, c = 12.911(1) A, alpha = 98.654(1) degrees, beta = 101.274(1) degrees, gamma = 115.791(1) degrees, Z = 2. [C6N4H22]0.5[Zn2P2O8] (III): triclinic, space group P1 (no. 2), a = 8.064(1) A, b = 8.457(1) A, c = 9.023(1) A, alpha = 111.9(1) degrees, beta = 108.0(1) degrees, gamma = 103.6(1) degrees, Z = 2. [C6N4H22]0.5[Zn3(PO4)2(HPO4)] (IV): triclinic, space group P1 (no. 2), a = 5.218(1) A, b = 8.780(1) A, c = 16.081(1) A, alpha = 89.3(1) degrees, beta = 83.5(1) degrees, gamma = 74.3(1) degrees, Z = 2. [C6N4H20]0.5[Zn4P4O16] (V): monoclinic, space group P2(1)/c (no. 14), a = 9.219(1) A, b = 15.239(1) A, c = 10.227(1) A, beta = 105.2(1), Z = 4. The structure of I is composed of ZnO4 and HPO4 tetrahedra, which are edge-shared to form four-membered rings, which, in turn, form a one-dimensional chain (ladder). In II, these ladders are fused into a layer. The structures of III and IV comprise networks of ZnO4 and PO4 tetrahedra forming three-dimensional architectures. In V, the amine molecule coordinates to the Zn and acts as a pillar supporting the zinc phosphate layers, which possess infinite Zn-O-Zn linkages. The 16-membered one-dimensional channel in IV and the ZnO3N pillar, along with infinite Zn-O-Zn linkages in V, are novel features. The structure of the open-framework zinc phosphates is found to depend sensitively on the relative concentrations of the amine and phosphoric acid, with high concentrations of the latter favoring structures with lower dimensions. 相似文献
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Choudhury A Neeraj S Natarajan S Rao CN 《Angewandte Chemie (International ed. in English)》2000,39(17):3091-3093
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Raju N. Aiyer 《Physics letters. A》1983,93(8):368-370
The recursion operator for the infinitesimal transformations about solutions of the coupled KdV is obtained as a 2 × 2 matrix. 相似文献
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The variation in hyperfine field with long range order parameter is estimated both in FeCo and FeNi3 with the help of an emperical relation connecting field and magnetic moments. The agreement is good with the available experimental values. 相似文献
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Experiments have been carried out to determine heat transfer rates from a continuously moving belt to an air jet impinging normally. The parameters that were varied included the jet velocity (4 < VN < 40 m/s), the jet width (4.8 < B < 19 mm), the nozzle-to-plate distance (3 < H/2B < 11) and the belt speed (0. 15 < VB < 5. 5 m/s). An infrared thermometer was used for the measurement of temperature of the moving belt. The average heat transfer coefficients increase with belt speed steeply initially to a maximum value and then remain almost constant for all higher belt speeds. The maximum heat transfer coefficients are about 1.5 to 2.0 times higher than those predicted for the stationary surface. The present data on continuously surface in still air and in impinging jet flow are well compared with the data on rotating cylinders reported in the literature.
Nomenclature A Heat transfer area - B Width of the nozzle - D Diameter of the cylinder or equivalent diameter of the flat surface (D=L/) - k Thermal conductivity - Gr Grashof number - h Heat transfer coefficient - H Height of the nozzle from the surface - i Number of nozzles - L Heat transfer length of a flat surface - NuD Nusselt number hD/k - ReDB Belt Reynoldsnumber, DVB/ - ReDN Nozzle Reynolds number, DVN/ - ReSN Nozzle Reynolds number, SVN/ - S Hydraulic diameter of the nozzle, 2B - VB Belt velocity or circumferential velocity of a cylinder - VN Nozzle celocity - Kinematic viscosity 相似文献
Wärmeübergang zwischen einem senkrecht auftreffenden Strahl und einer bewegten Oberfläche
Zusammenfassung Experimentell bestimmte Wärmeübergangskoeffizienten für Düsengeschwindigkeiten zwischen 4 m/s und 40 m/s, sowie Düsenbreiten zwischen 4,8 mm und 19 mm lagen bei Bandgeschwindigkeiten zwischen 0, 15 m/s bis 5, 5 m/s ca. 50 % bis 100 % höher als bei unbewegtem Band. Die gemessenen Daten bei bewegtem wie bei unbewegtem Band schließen gut an bekannte Werte aus der Literatur an.
Nomenclature A Heat transfer area - B Width of the nozzle - D Diameter of the cylinder or equivalent diameter of the flat surface (D=L/) - k Thermal conductivity - Gr Grashof number - h Heat transfer coefficient - H Height of the nozzle from the surface - i Number of nozzles - L Heat transfer length of a flat surface - NuD Nusselt number hD/k - ReDB Belt Reynoldsnumber, DVB/ - ReDN Nozzle Reynolds number, DVN/ - ReSN Nozzle Reynolds number, SVN/ - S Hydraulic diameter of the nozzle, 2B - VB Belt velocity or circumferential velocity of a cylinder - VN Nozzle celocity - Kinematic viscosity 相似文献