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A solid phase microextraction fiber based on high temperature silicone glue coated on a stainless steel wire is presented for use in the extraction of amino acid derivatives. Amino acids were derivatizad using ethyl chloroformate. Effects of the extraction and desorption parameters including extraction and desorption time, desorption temperature and ionic strength on the extraction/desorption efficiency have been studied and quality parameters of the method were measured. A possibility to apply the proposed method for the identification of proteinaceous binders was demonstrated.  相似文献   
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iauliai Pedagogical Institute, P. Viinskio str. 25, 5419 iauliai, Lithuania. Translated from Lietuvos Matematikos Rinkinys, Vol. 33, No. 2, pp. 135–141, April–June, 1993.  相似文献   
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We obtain the asymptotics of the Gerber-Shiu discounted penalty function in the classical Lundberg model. We cosider claims from a class of subexponential distributions and find the asymptotics as the initial surplus x tends to infinity. The main term of the discounted penalty function ψ(x, δ) has different expressions in the cases where the interest rate δ > 0 and where δ = 0. Published in Lietuvos Matematikos Rinkinys, Vol. 46, No. 4, pp. 598–605, October–December, 2006.  相似文献   
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The art of light engineering unveils a world of possibilities through the meticulous manipulation of photonic properties such as intensity, phase, and polarization. Precision control over these properties finds application in a variety of fields spanning communications, light–matter interactions, laser direct writing, and imaging. Terahertz (THz) range, nestled between microwaves and infrared light, stands out for its remarkable ability to propagate with minimal losses in numerous dielectric materials and compounds, making THz imaging a powerful tool for noninvasive control and inspection. In this study, a rational framework for the design and optimal assembly of nonparaxial THz imaging systems is established. The research is centered on lensless photonic systems composed solely of high-resistivity silicon-based nonparaxial elements such as the Fresnel zone plate, the Fibonacci lens, the Bessel axicon, and the Airy zone plate, all fabricated using laser ablation technology. Through a comprehensive examination through illumination engineering and scattered light collection from raster-scanned samples in a single-pixel detector scheme, the imaging systems are evaluated via diverse metrics including contrast, resolution, depth of field, and focus. These findings chart an exciting course toward the development of compact and user-friendly THz imaging systems where sensors and optical elements seamlessly integrate into a single chip.  相似文献   
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The photoelectron emission spectra of BiSCl crystal and molecular clusters have been calculated by the Density Functional Theory (DFT) method. Molecular clusters consists from 2 to 20 molecules in one double chain along z(c) axis. Total and partial density of states of BiSCl crystal and clusters have been weighted with atomic photoemission emission cross-section. The molecular clusters have been investigated including all normal modes of vibration. Theoretical results of BiSCl crystal and molecular clusters have been compared with experimental X-ray photoelectron emission spectra (XPS) of BiSI crystal.  相似文献   
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