Cooperative Lewis Pairs Based on Late Transition Metals: Activation of Small Molecules by Platinum(0) and B(C6F5)3

A Lewis basic platinum(0)–CO complex supported by a diphosphine ligand and B(C₆F₅)₃ act cooperatively, in a manner reminiscent of a frustrated Lewis pair, to activate small molecules such as hydrogen, CO₂, and ethene. This cooperative Lewis pair facilitates the coupling of CO and ethene in a new way.     

Displacement of hexanol by the hexanoic acid overoxidation product in alcohol oxidation on a model supported palladium nanoparticle catalyst

This work characterizes the adsorption, structure, and binding mechanism of oxygenated organic species from cyclohexane solution at the liquid/solid interface of optically flat alumina-supported palladium nanoparticle surfaces prepared by atomic layer deposition (ALD). The surface-specific nonlinear optical vibrational spectroscopy, sum-frequency generation (SFG), was used as a probe for adsorption and interfacial molecular structure. 1-Hexanoic acid is an overoxidation product and possible catalyst poison for the aerobic heterogeneous oxidation of 1-hexanol at the liquid/solid interface of Pd/Al(2)O(3) catalysts. Single component and competitive adsorption experiments show that 1-hexanoic acid adsorbs to both ALD-prepared alumina surfaces and alumina surfaces with palladium nanoparticles, that were also prepared by ALD, more strongly than does 1-hexanol. Furthermore, 1-hexanoic acid adsorbs with conformational order on ALD-prepared alumina surfaces, but on surfaces with palladium particles the adsorbates exhibit relative disorder at low surface coverage and become more ordered, on average, at higher surface coverage. Although significant differences in binding constant were not observed between surfaces with and without palladium nanoparticles, the palladium particles play an apparent role in controlling adsorbate structures. The disordered adsorption of 1-hexanoic acid most likely occurs on the alumina support, and probably results from modification of binding sites on the alumina, adjacent to the particles. In addition to providing insight on the possibility of catalyst poisoning by the overoxidation product and characterizing changes in its structure that result in only small adsorption energy changes, this work represents a step toward using surface science techniques that bridge the complexity gap between fundamental studies and realistic catalyst models.     

Organometallic reactivity: the role of metal-ligand bond energies from a computational perspective

The association and dissociation of ligands plays a vital role in determining the reactivity of organometallic catalysts. Computational studies with density functional theory often fail to reproduce experimental metal-ligand bond energies, but recently functionals which better capture dispersion effects have been developed. Here we explore their application and discuss future challenges for computational studies of organometallic catalysis.     

Introduction to Physics in Modern Medicine, 2nd edn., by Suzanne Amador Kane

The inexorable miniaturisation of technologies, the relentless drive to improve efficiency and the enticing prospect of boosting performance through quantum effects are all compelling reasons to investigate microscopic machines. Thermal absorption machines are a particularly interesting class of device that operate autonomously and use only heat flows to perform a useful task. In the quantum regime, this provides a natural setting in which to quantify the thermodynamic cost of various operations such as cooling, timekeeping or entanglement generation. This article presents a pedagogical introduction to the physics of quantum absorption machines, covering refrigerators, engines and clocks in detail.     

Aziridination Reactivity of a Manganese(II) Complex with a Bulky Chelating Bis(Alkoxide) Ligand

Treatment of Mn(N(SiMe₃)₂)₂(THF)₂ with bulky chelating bis(alkoxide) ligand [1,1′:4′,1′′-terphenyl]-2,2′′-diylbis(diphenylmethanol) (H₂[O-terphenyl-O]^Ph) formed a seesaw manganese(II) complex Mn[O-terphenyl-O]^Ph(THF)₂, characterized by structural, spectroscopic, magnetic, and analytical methods. The reactivity of Mn[O-terphenyl-O]^Ph(THF)₂ with various nitrene precursors was investigated. No reaction was observed between Mn[O-terphenyl-O]^Ph(THF)₂ and aryl azides. In contrast, the treatment of Mn[O-terphenyl-O]^Ph(THF)₂ with iminoiodinane PhINTs (Ts = p-toluenesulfonyl) was consistent with the formation of a metal-nitrene complex. In the presence of styrene, the reaction led to the formation of aziridine. Combining varying ratios of styrene and PhINTs in different solvents with 10 mol% of Mn[O-terphenyl-O]^Ph(THF)₂ at room temperature produced 2-phenylaziridine in up to a 79% yield. Exploration of the reactivity of Mn[O-terphenyl-O]^Ph(THF)₂ with various olefins revealed (1) moderate aziridination yields for p-substituted styrenes, irrespective of the electronic nature of the substituent; (2) moderate yield for 1,1′-disubstituted α-methylstyrene; (3) no aziridination for aliphatic α-olefins; (4) complex product mixtures for the β-substituted styrenes. DFT calculations suggest that iminoiodinane is oxidatively added upon binding to Mn, and the resulting formal imido intermediate has a high-spin Mn(III) center antiferromagnetically coupled to an imidyl radical. This imidyl radical reacts with styrene to form a sextet intermediate that readily reductively eliminates the formation of a sextet Mn(II) aziridine complex.     

Formation of rectangular packing and one-dimensional lines of C60 on 11-phenoxyundecanethiol self-assembled monolayers on Au(111)

The behavior of C(60) molecules deposited onto 11-phenoxyundecanethiol (phenoxy) self-assembled monolayers (SAMs) is studied using ultrahigh vacuum scanning tunneling microscopy (UHV-STM) and spectroscopy. We observe that after thermally annealing between 350 and 400 K in vacuum a combination of hexagonally close-packed islands, rectangularly packed islands, and isolated single lines of C(60) is observed when the C(60) is initially deposited on an unannealed phenoxy SAM. However, only rectangularly packed islands are found when they are deposited on a preannealed phenoxy SAM. We determine the rectangular packing to have a (2√3 × 4) rectangular unit cell with respect to the underlying Au(111) substrate. This type of C(60) structure has not been observed previously for multicomponent self-assemblies on a surface. We discuss the possible causes for the formation of this structure as well as the differences between starting on an unannealed SAM and an annealed one. This study demonstrates the capability of functionalized alkanethiol SAMs to control the growth and structure of C(60) islands during annealing depending on the structural changes of the SAM itself; by preannealing the SAM, the motion of the C(60) can be confined and unique structures resulting from interactions between the SAM molecules and C(60) can be produced.     

Adding value to crystallographically-derived knowledge bases

A protocol for the partially automated computational investigation of crystal structure geometries of transition-metal complexes with unusual/outlier structural features has been developed for application in an e-science context. This protocol not only is envisaged as a part of knowledge base software packages such as Mogul but can also be used to further analyze the results of database searches. The issues arising from automating the initial input generation and DFT optimization of complexes have been examined and a procedure for extracting additional knowledge "value" from the computational results is described. Potential problems/weaknesses arising from the choice of computational approach and from errors in the crystal structure refinement are discussed. A range of likely outcomes of applying this protocol to database mining results is illustrated, with representative examples identified for tetracoordinate transition-metal complexes and ligand fragments (terminal chloride, monodentate phosphorus(III), and primary amine ligands) with unusual metal-ligand bond lengths.