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排序方式: 共有498条查询结果,搜索用时 15 毫秒
491.
Majid Montazer Morteza Maali Amiri Reza Mohammad Ali Malek 《Photochemistry and photobiology》2013,89(5):1057-1063
This study has been carried out to synthesize nano ZnO on wool fabric and also to investigate influences of nano photo reactors on wool fabric characteristics. Zinc acetate has been used as a precursor and the synthesis process has been done in water and water/ethanol media. The treated wool fabrics were heated at 80°C for 10 h to dehydrate Zn(OH)2 obtaining ZnO. The fabric samples were then subjected to daylight for 7 days to examine the influence of nano ZnO photo reactor on the fabric properties. SEM images revealed the embedding of ZnO nanoparticles on the fabrics and X‐ray diffraction verified the nanoparticles composition. The Yellowness Index (YI) of the fabrics was measured with Color Eye XTH that has been reduced with increasing pH, Zn(CH3COO)2 concentration, ethanol and heating. The lower water contact angle and time of water absorption confirmed higher hydrophilic properties of the treated fabrics. Interestingly, a higher tensile strength obtained on the wool fabrics proved the interaction of ZnO with protein chains of wool, which was verified through lower alkali solubility of treated fabric with nano ZnO and confirmed more benefits of the in situ synthesis process. 相似文献
492.
Mohammad Anary-Abbasinejad Hamidreza Dehghanpour Farashah Hossein Anaraki-Ardakani Nasim Shams 《合成通讯》2013,43(13):1877-1884
A new and efficient one-pot synthesis of polysubstituted pyrrole derivatives by three-component reaction of dialkyl acetylenedicarboxylates, triphenylphosphine, 2-aminothiazole or 2-aminobenzothiazole in the presence of arylglyoxals is described. The reactions were performed in dichloromethane at room temperature and neutral conditions and afforded good yields of products. 相似文献
493.
Harmon AM Lash MH Tishbi N Lent D Mintzer EA Uhrich KE 《Langmuir : the ACS journal of surfaces and colloids》2011,27(15):9131-9138
Surfactant amphiphilic macromolecules (AMs) were complexed with a 1:1 ratio of 1,2-dioleoyl-3-trimethylammonium-propane (DOTAP) and 1,2-dioleoyl-sn-glycero-3-phosphoethanolamine (DOPE), either by a coevaporation (CE) or postaddition (PA) method, to form AM-lipid complexes with enhanced drug delivery applications. By characterizing the surfactant-lipid interactions, these heterogeneous drug delivery systems can be better controlled and engineered for optimal therapeutic outcomes. In this study, the physical interactions between DOPE:DOTAP liposomes and AM surfactants were investigated. Langmuir film balance and isothermal calorimetry studies showed cooperative intermolecular interactions between pure lipids and AM in monolayers and high thermostability of structure formed by the addition of AM micelles to DOTAP:DOPE vesicles in buffer solution respectively. Increasing the AM weight ratio in the complexes via the CE method led to complete vesicle solubilization--from lamellar aggregates, to a mixture of coexisting vesicles and micelles, to mixed micelles. Isothermal calorimetry evaluation of AM-lipid complexes shows that, at higher AM weight ratios, PA-produced complexes exhibit greater stability than complexes at lower AM weight ratios. Similar studies show that AM-lipid complexes produced by the CE methods display stronger interactions between AM-lipid components than complexes produced by the PA method. The results suggest that the PA method produces vesicles with AM molecules associated with its outer leaflet only (i.e., an AM-coated vesicle), while the CE method produces complexes ranging from mixed vesicles to mixed micelle in which the AM-lipid components are more intimately associated. These results will be helpful in the design of AM-lipid complexes as structurally defined, stable, and effective drug delivery systems. 相似文献
494.
Solvatochromic mixed-chelate copper(II) complexes, [Cu(Cl-acac)(diamine)]X (where Cl-acac = 3-chloroacetylacetonate ion, diamine = N,N′-dimethyl,N′-benzyl-1,2-diaminoethane and X = B(Ph)4−, PF6−, BF4− and ClO4−), have been prepared. The complexes were characterized on the basis of elemental analysis, molar conductance, UV-Vis and IR spectroscopies. Single crystals of [Cu(Cl-acac)(diamine)(H2O)]PF6, complex 2, were also characterized by X-ray diffraction. The influence of the solvent polarity and counter ions on the νmax values of the d-d bands of the complexes have been investigated by means of visible spectroscopy. All the complexes demonstrated negative solvatochromism. A multi-parametric equation has been utilized to explain the solvent effect on the d-d transition of the complexes using SPSS/PC software. The stepwise multiple linear regression (SMLR) method demonstrated that the donor power of the solvent plays the most important role in the solvatochromism of the compounds. The relative donor power of the anions X was determined by visible spectra in the solvent dichloromethane. 相似文献
495.
Seyed Hanif Mahboobi Ali Meghdari Nader Jalili Farshid Amiri 《Central European Journal of Physics》2011,9(2):454-465
Molecular dynamics simulations are carried out to investigate the manipulation of metallic clusters on stepped surfaces. Five
surface forms are considered in the simulations. The system parts are made of pure transition metals and Sutton-Chen many-body
potential is used as interatomic potential. The conditions which are subjected to change in the tests include: materials used
for particles and substrate, and surface step conditions. In addition to qualitative observations, two criteria which represent
the particle deformation and substrate abrasion are utilized as evaluation tools and are computed for each case. Simulation
results show the effect of the aforementioned working conditions on the particle behavior as well as changes in the pushing
forces. Obtaining this sort of knowledge is highly beneficial for further experiments in order to be able to plan the conditions
and routines which guarantee better success in the manipulation process. 相似文献
496.
Nasim Alem Rolf Erni Christian Kisielowski Marta D. Rossell Peter Hartel Bin Jiang Will Gannett A. Zettl 《固体物理学:研究快报》2011,5(8):295-297
Atomically thin hexagonal boron nitride (h‐BN) is investigated using aberration‐corrected ultra‐high resolution electron microscopy under 80 kV electron beam. This study focuses on the in situ formation, growth and migration of vacancies in h‐BN. This study also reveals interaction dynamics of edges and vacancies with adatoms and molecules under the electron beam. According to this investigation, boron monovacancies migrate through their second neighbor to reduce the surface energy of the membrane. (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
497.
为探究不同类型地震波作用下地下综合体结构的地震反应特征,本文以上海某地下综合体为工程背景,采用ABAQUS软件建立土-地下综合体结构相互作用体系三维有限元模型,利用Davidenkov模型模拟土的非线性,以不同类型的单向地震波和双向地震波(含水平向和竖向)作为输入,对软土场地中地下综合体结构进行了地震反应分析,比较了不同类型地震波作用下地下综合体结构地震反应的差异,探讨了地下综合体结构的竖向地震动效应问题.本文的算例结果表明:在长周期地震波作用下地下综合体结构的位移响应和内力响应峰值均明显大于普通地震波作用下的结果;考虑竖向地震动时地下综合体结构的柱轴力较单一水平向地震动作用情形有明显增大;在本文地下综合体结构算例中,地下三层柱底、四层柱顶、五层柱底、以及底板与侧墙连接处为受力较大部位. 相似文献
498.
Prof. Dr. Lena Keller Dr. Emilia Oueis Dr. Amninder Kaur Dr. Nasim Safaei Dr. Susanne H. Kirsch Dr. Antonia P. Gunesch Dr. Sibylle Haid Dr. Ulfert Rand Prof. Dr. Luka Čičin-Šain Dr. Chengzhang Fu PD Dr. Joachim Wink Prof. Dr. Thomas Pietschmann Prof. Dr. Rolf Müller 《Angewandte Chemie (International ed. in English)》2023,62(6):e202214595
A new family of highly unusual sesquarterpenoids (persicamidines A–E) exhibiting significant antiviral activity was isolated from a newly discovered actinobacterial strain, Kibdelosporangium persicum sp. nov., collected from a hot desert in Iran. Extensive NMR analysis unraveled a hexacyclic terpenoid molecule with a modified sugar moiety on one side and a highly unusual isourea moiety fused to the terpenoid structure. The structures of the five analogues differed only in the aminoalkyl side chain attached to the isourea moiety. Persicamidines A–E showed potent activity against hCoV-229E and SARS-CoV-2 viruses in the nanomolar range together with very good selectivity indices, making persicamidines promising as starting points for drug development. 相似文献