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71.
72.
Functionalized crosslinked polystyrene-co-divinylbenzene-co-chloromethylstyrene magnetic latex particles were prepared via emulsifier-free miniemulsion polymerization using 2, 2′ azobis (2-amidinopropane) dihydrochloride (V-50) as an initiator and in the presence of magnetite nanoparticles in the monomers. Transmission electron microscopy (TEM) proved the presence of magnetite nanoparticles in polymer particles. Differential scanning calorimetery (DSC) analysis of the product showed an exothermic signal due to crosslinking of chains through electrophilic aromatic substitution of phenyl groups with chloromethyl groups in the presence of the dispersed Fe3O4 as Lewis acid. This was proven by thermogravimetric analysis (TGA) via the loss of gaseous HCl. The results were also compared with those of magnetite-free miniemulsion polymerization using V-50. 相似文献
73.
Callaghan PL Fernández-Pacheco R Jasim N Lachaize S Marder TB Perutz RN Rivalta E Sabo-Etienne S 《Chemical communications (Cambridge, England)》2004,(2):242-243
Metal phosphine hydrides of type RuP(4)H(2) and RhP(3)H(3) react photochemically with HB(pin)(pin = pinacolate) to form metal boryl hydride complexes via 16-electron intermediates generated by H(2) loss; the second order rate constants for reaction of the intermediates with HB(pin) are even larger than those for reaction with Et(3)SiH. 相似文献
74.
Mahmoodi Nosrat O. Zeydi Masoud Mohammadi Mamaghani Manouchehr Montazeri Naser 《Research on Chemical Intermediates》2017,43(4):2641-2651
Research on Chemical Intermediates - A series of new thiocarbamoyl tris-pyrazoline (tripod pyrazoline with triazine core) compounds was obtained by tris-cyclization of chalcone with... 相似文献
75.
The Ramberg–Osgood equation has been approximately inverted. Four orders of approximations providing progressively more accurate inversions are considered. The second order inversion is used to develop closed-form relations for stress in terms of strain and for cyclic stress in terms of cyclic strain. Explicit relations between the cyclic-strength coefficient and the cyclic strain-hardening exponent and between the cyclic strain-hardening exponent and the elastic modulus are developed. Application to nine different engineering metals shows that the proposed approximate inversion provides a powerful tool for describing stress–strain relations. Examples of hysteresis loops for a number of strain time-histories are presented. Also, it is shown that augmenting the strain time-history with fictitious strain segments to close all the hysteresis loops yields the same stress–strain relation as that obtained through the rain-flow counting method. 相似文献
76.
Naser Foroughifar Akbar Mobinikhaledi Hassan Moghanian Reza Mozafari Hamid R. M. Esfahani 《合成通讯》2013,43(18):2663-2673
A one-pot, multicomponent reaction of aldehydes, dimedone, and β-naphthols is described for the preparation of 12-aryl- or 12-alkyl-8,9,10,12-tetrahydrobenzo[α]xanthen-11-one derivatives using ammonium chloride as a mild, inexpensive, and environmentally benign catalyst under solvent-free conditions. Different types of aldehyde and β-naphthol derivatives are used in the reaction, and in all cases the products were synthesized successfully.
77.
There is a high overvoltage in the oxidation of methanol in fuel cells, and so modified electrodes are used to decrease it. A modified electrode that used Ni(Ⅱ) loaded analcime zeolite to catalyze the electrooxidation of methanol in alkaline solution was proposed. Analcime zeolite was synthesized by hydrothermal synthesis, and Ni(Ⅱ) ions were incorporated into the analcime structure, which was then mixed with carbon paste to prepare modified electrode. The electrocatalytic oxidation of methanol on the surface of the modified electrode in alkaline solution was investigated by cyclic voltammetry and chronoamperometry. The effects of the scan rate of the potential, concentration of methanol, and amount of zeolite were investigated. The rate constant for the catalytic reaction of methanol was 6×103 cm3 mol-1 s-1 from measurements using chronoamperometry. The proposed electrode significantly improved the electron transfer rate and decreased the overpotential for methanol oxidation. 相似文献
78.
Oxidation of hydrogen cyanide with ozone on the singlet potential energy surface is carried out using the MP2 and CCSD(T)//MP2 theoretical approaches in connection with the 6-311++G(d,p) basis set. In this reaction, energy barrier of transition states are low, so the reaction of HCN with ozone can occur easily at atmospheric condition. With variety of pre-reactive complex, five types of products are obtained at the MP2 method which four types of them have enough thermodynamic stability at the standard condition. CO2 + HNO are final adducts in a process that is computed to be exothermic by ?132.605 kcal/mol in standard enthalpy and spontaneous by ?144.166 kcal/mol in Gibbs free energy of reaction. In kinetic viewpoint, the production of OCN + HO2 adducts path with one low level transition state is the most favored path. 相似文献
79.
Akbar Mobinikhaledi Naser Foroughifar Mohammad Ali Bodaghi Fard Hassan Moghanian Sattar Ebrahimi Mehdi Kalhor 《合成通讯》2013,43(7):1166-1174
An efficient Hantzsch four-component condensation reaction for the synthesis of polyhydroquinoline derivatives was reported under two conditions: solvent-free conventional heating and energy-saving microwave irradiation. The process is simple and environmentally benign, and the use of a heterogeneous and reusable catalyst, high yields, and short reaction times are the key features of this protocol. 相似文献
80.
Talha Achouri 《Numerical Methods for Partial Differential Equations》2019,35(1):200-221
In this article, two finite difference schemes for solving the semilinear wave equation are proposed. The unique solvability and the stability are discussed. The second‐order accuracy convergence in both time and space in the discrete H1‐norm for the two proposed difference schemes is proved. Numerical experiments are performed to support our theoretical results. 相似文献